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Although various technologies have been deployed to degrade PFASs with a focus on non-polymeric functionalized compounds (perfluorooctanoic acid and perfluorooctanesulfonic acid)\n                    <jats:sup>2\u20134<\/jats:sup>\n                    , a general PFAS destruction method coupled with fluorine recovery for upcycling is highly desirable. Here we disclose a protocol that converts multiple classes of PFAS, including the fluoroplastics polytetrafluoroethylene and polyvinylidene fluoride, into high-value fluorochemicals. To achieve this, PFASs were reacted with potassium phosphate salts under solvent-free mechanochemical conditions, a mineralization process enabling fluorine recovery as KF and K\n                    <jats:sub>2<\/jats:sub>\n                    PO\n                    <jats:sub>3<\/jats:sub>\n                    F for fluorination chemistry. The phosphate salts can be recovered for reuse, implying no detrimental impact on the phosphorus cycle. Therefore, PFASs are not only destructible but can now contribute to a sustainable circular fluorine economy.\n                  <\/jats:p>","DOI":"10.1038\/s41586-025-08698-5","type":"journal-article","created":{"date-parts":[[2025,3,26]],"date-time":"2025-03-26T14:09:17Z","timestamp":1742998157000},"page":"100-106","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":140,"title":["Phosphate-enabled mechanochemical PFAS destruction for fluoride reuse"],"prefix":"10.1038","volume":"640","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0220-3250","authenticated-orcid":false,"given":"Long","family":"Yang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zijun","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5834-8371","authenticated-orcid":false,"given":"Christopher A.","family":"Goult","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5034-0968","authenticated-orcid":false,"given":"Thomas","family":"Schlatzer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0104-4166","authenticated-orcid":false,"given":"Robert S.","family":"Paton","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8638-5308","authenticated-orcid":false,"given":"V\u00e9ronique","family":"Gouverneur","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,3,26]]},"reference":[{"key":"8698_CR1","doi-asserted-by":"publisher","first-page":"166764","DOI":"10.1016\/j.scitotenv.2023.166764","volume":"905","author":"SCE Leung","year":"2023","unstructured":"Leung, S. 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