{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,31]],"date-time":"2026-10-31T07:30:32Z","timestamp":1793431832900,"version":"4.5.0"},"reference-count":25,"publisher":"Springer Science and Business Media LLC","issue":"8137","license":[{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"},{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springernature.com\/gp\/researchers\/text-and-data-mining"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Nature"],"published-print":{"date-parts":[[2026,10,22]]},"DOI":"10.1038\/s41586-026-11136-9","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T04:43:27Z","timestamp":1792039407000},"page":"936-942","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rh3+ stabilized in KRh@MFI catalyses regioselective hydroformylation"],"prefix":"10.1038","volume":"658","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-2198-1570","authenticated-orcid":false,"given":"Minjie","family":"Zhao","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4489-5411","authenticated-orcid":false,"given":"Reisel","family":"Mill\u00e1n","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9844-0220","authenticated-orcid":false,"given":"Alina","family":"Skorynina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5331-0633","authenticated-orcid":false,"given":"Laura","family":"Simonelli","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2560-8015","authenticated-orcid":false,"given":"Miguel Lopez","family":"Haro","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jos\u00e9 Juan","family":"Calvino","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2058-3103","authenticated-orcid":false,"given":"Patricia","family":"Concepci\u00f3n","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2232-3527","authenticated-orcid":false,"given":"Avelino","family":"Corma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2026,10,14]]},"reference":[{"key":"11136_CR1","doi-asserted-by":"publisher","first-page":"2144","DOI":"10.1002\/anie.199421441","volume":"33","author":"B Cornils","year":"1994","unstructured":"Cornils, B., Herrmann, W. A. & Rasch, M. Otto Roelen, pioneer in industrial homogeneous catalysis. Angew. Chem. Int. Ed. Engl. 33, 2144\u20132163 (1994).","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"11136_CR2","doi-asserted-by":"publisher","first-page":"5675","DOI":"10.1021\/cr3001803","volume":"112","author":"R Franke","year":"2012","unstructured":"Franke, R., Selent, D. & B\u00f6rner, A. Applied hydroformylation. Chem. Rev. 112, 5675\u20135732 (2012).","journal-title":"Chem. Rev."},{"key":"11136_CR3","doi-asserted-by":"publisher","first-page":"2630","DOI":"10.1016\/j.chempr.2022.07.020","volume":"8","author":"B Liu","year":"2022","unstructured":"Liu, B. et al. Heterogeneous hydroformylation of alkenes by Rh-based catalysts. Chem. 8, 2630\u20132658 (2022).","journal-title":"Chem"},{"key":"11136_CR4","doi-asserted-by":"publisher","first-page":"287","DOI":"10.1038\/s41586-022-05075-4","volume":"609","author":"I Ro","year":"2022","unstructured":"Ro, I. et al. Bifunctional hydroformylation on heterogeneous Rh-WOx pair site catalysts. Nature 609, 287\u2013292 (2022).","journal-title":"Nature"},{"key":"11136_CR5","doi-asserted-by":"publisher","first-page":"597","DOI":"10.1038\/s41586-024-07342-y","volume":"629","author":"X Zhang","year":"2024","unstructured":"Zhang, X. et al. Regioselective hydroformylation of propene catalysed by rhodium-zeolite. Nature 629, 597\u2013602 (2024).","journal-title":"Nature"},{"key":"11136_CR6","doi-asserted-by":"publisher","first-page":"112390","DOI":"10.1016\/j.micromeso.2022.112390","volume":"358","author":"R Zhao","year":"2023","unstructured":"Zhao, R., Haller, G. L. & Lercher, J. A. Alkene adsorption and cracking on acidic zeolites \u2013 a gradual process of understanding. Microporous Mesoporous Mater. 358, 112390 (2023).","journal-title":"Microporous Mesoporous Mater."},{"key":"11136_CR7","doi-asserted-by":"publisher","first-page":"6112","DOI":"10.1002\/anie.201601231","volume":"55","author":"A Corma","year":"2016","unstructured":"Corma, A. Heterogeneous catalysis: understanding for designing, and designing for applications. Angew. Chem. Int. Ed. 55, 6112\u20136113 (2016).","journal-title":"Angew. Chem. Int. Ed."},{"key":"11136_CR8","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42938-4","volume":"14","author":"M Zhao","year":"2023","unstructured":"Zhao, M. et al. Low-temperature hydroformylation of ethylene by phosphorous stabilized Rh sites in a one-pot synthesized Rh-(O)-P-MFI zeolite. Nat. Commun. 14, 7174 (2023).","journal-title":"Nat. Commun."},{"key":"11136_CR9","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-09188-9","volume":"10","author":"MJ H\u00fclsey","year":"2019","unstructured":"H\u00fclsey, M. J. et al. In situ spectroscopy-guided engineering of rhodium single-atom catalysts for CO oxidation. Nat. Commun. 10, 1330 (2019).","journal-title":"Nat. Commun."},{"key":"11136_CR10","doi-asserted-by":"publisher","first-page":"307","DOI":"10.1016\/S0360-0564(02)47008-3","volume":"47","author":"KI Hadjiivanov","year":"2002","unstructured":"Hadjiivanov, K. I. & Vayssilov, G. N. Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule. Adv. Catal. 47, 307\u2013511 (2002).","journal-title":"Adv. Catal."},{"key":"11136_CR11","doi-asserted-by":"publisher","first-page":"3104","DOI":"10.1021\/ic50201a030","volume":"18","author":"AK Smith","year":"1979","unstructured":"Smith, A. K. et al. Surface-supported metal cluster carbonyls. Chemisorption decomposition and reactivity of hexadecacarbonylhexarhodium supported on alumina, silica-alumina, and magnesia. Inorg. Chem. 18, 3104\u20133112 (1979).","journal-title":"Inorg. Chem."},{"key":"11136_CR12","doi-asserted-by":"publisher","first-page":"6487","DOI":"10.1063\/1.440987","volume":"74","author":"CA Rice","year":"1981","unstructured":"Rice, C. A., Worley, S. D., Curtis, C. W., Guin, J. A. & Tarrer, A. R. The oxidation state of dispersed Rh on Al2O3. J. Chem. Phys. 74, 6487\u20136497 (1981).","journal-title":"J. Chem. Phys."},{"key":"11136_CR13","doi-asserted-by":"publisher","first-page":"257","DOI":"10.1016\/S0167-2991(09)61162-9","volume":"18","author":"F Lefebvre","year":"1984","unstructured":"Lefebvre, F., Gelin, P., Elleuch, B., Diab, Y. & Taarit, Y. Metal carbonyl compounds entrapped within zeolite cavities. Preparation, characterization and catalytic properties. Stud. Surf. Sci. Catal. 18, 257\u2013272 (1984).","journal-title":"Stud. Surf. Sci. Catal."},{"key":"11136_CR14","doi-asserted-by":"publisher","first-page":"335","DOI":"10.1006\/jcat.1994.1352","volume":"150","author":"S Trautmann","year":"1994","unstructured":"Trautmann, S. & Baerns, M. Infrared spectroscopic studies of CO adsorption on rhodium supported by SiO2, Al2O3, and TiO2. J. Catal. 150, 335\u2013344 (1994).","journal-title":"J. Catal."},{"key":"11136_CR15","doi-asserted-by":"publisher","first-page":"374","DOI":"10.1006\/jcat.1997.1807","volume":"171","author":"A Guerrero-Ruiz","year":"1997","unstructured":"Guerrero-Ruiz, A., Bachiller-Baeza, B., Ferreira-Aparicio, P. & Rodr\u0131\u0301guez-Ramos, I. Preparation, characterization, and activity for n-hexane reactions of alumina-supported rhodium-copper catalysts. J. Catal. 171, 374\u2013382 (1997).","journal-title":"J. Catal."},{"key":"11136_CR16","doi-asserted-by":"publisher","first-page":"605","DOI":"10.1038\/nature24640","volume":"551","author":"J Shan","year":"2017","unstructured":"Shan, J., Li, M., Allard, L. F., Lee, S. & Flytzani-Stephanopoulos, M. Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts. Nature 551, 605\u2013608 (2017).","journal-title":"Nature"},{"key":"11136_CR17","doi-asserted-by":"publisher","first-page":"459","DOI":"10.1016\/j.molstruc.2003.09.007","volume":"661\u2013662","author":"K Hadjiivanov","year":"2003","unstructured":"Hadjiivanov, K., Ivanova, E., Dimitrov, L. & Kn\u00f6zinger, H. FTIR spectroscopic study of CO adsorption on Rh\u2013ZSM-5: detection of Rh+-CO species. J. Mol. Struct. 661\u2013662, 459\u2013463 (2003).","journal-title":"J. Mol. Struct."},{"key":"11136_CR18","doi-asserted-by":"publisher","first-page":"3049","DOI":"10.1002\/cphc.201402122","volume":"15","author":"AB Kroner","year":"2014","unstructured":"Kroner, A. B. et al. Time-resolved, in situ DRIFTS\/EDE\/MS studies on alumina-supported rhodium catalysts: effects of ceriation and zirconiation on rhodium-CO interactions. ChemPhysChem. 15, 3049\u20133059 (2014).","journal-title":"ChemPhysChem"},{"key":"11136_CR19","doi-asserted-by":"publisher","first-page":"17166","DOI":"10.1021\/acs.jpcc.5b03969","volume":"119","author":"K Khivantsev","year":"2015","unstructured":"Khivantsev, K. et al. Effect of Si\/Al ratio and Rh precursor used on the synthesis of HY zeolite-supported rhodium carbonyl hydride complexes. J. Phys. Chem. C 119, 17166\u201317181 (2015).","journal-title":"J. Phys. Chem. C"},{"key":"11136_CR20","doi-asserted-by":"publisher","first-page":"75","DOI":"10.1007\/s11743-016-1886-8","volume":"20","author":"MG Alam","year":"2017","unstructured":"Alam, M. G., Tshabalala, T. A. & Ojwach, S. O. Metal-catalyzed alkene functionalization reactions towards production of detergent and surfactant feedstocks. J. Surfactants Deterg. 20, 75\u201381 (2017).","journal-title":"J. Surfactants Deterg."},{"key":"11136_CR21","doi-asserted-by":"publisher","first-page":"1231987","DOI":"10.1080\/23311940.2016.1231987","volume":"3","author":"L Simonelli","year":"2016","unstructured":"Simonelli, L. et al. CL\u00c6SS: the hard X-ray absorption beamline of the ALBA CELLS synchrotron. Cogent Phys. 3, 1231987 (2016).","journal-title":"Cogent Phys."},{"key":"11136_CR22","doi-asserted-by":"publisher","first-page":"537","DOI":"10.1107\/S0909049505012719","volume":"12","author":"B Ravel","year":"2005","unstructured":"Ravel, B. & Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 12, 537\u2013541 (2005).","journal-title":"J. Synchrotron Radiat."},{"key":"11136_CR23","doi-asserted-by":"publisher","first-page":"96","DOI":"10.1107\/S0909049500016290","volume":"8","author":"M Newville","year":"2001","unstructured":"Newville, M. EXAFS analysis using FEFF and FEFFIT. J. Synchrotron Radiat. 8, 96\u2013100 (2001).","journal-title":"J. Synchrotron Radiat."},{"key":"11136_CR24","doi-asserted-by":"publisher","first-page":"621","DOI":"10.1103\/RevModPhys.72.621","volume":"72","author":"JJ Rehr","year":"2000","unstructured":"Rehr, J. J. & Albers, R. C. Theoretical approaches to x-ray absorption fine structure. Rev. Mod. Phys. 72, 621\u2013654 (2000).","journal-title":"Rev. Mod. Phys."},{"key":"11136_CR25","doi-asserted-by":"publisher","first-page":"012007","DOI":"10.1088\/1742-6596\/430\/1\/012007","volume":"430","author":"M Newville","year":"2013","unstructured":"Newville, M. Larch: an analysis package for XAFS and related spectroscopies. J. Phys. Conf. Ser. 430, 012007 (2013).","journal-title":"J. Phys. Conf. Ser."}],"updated-by":[{"DOI":"10.1038\/s41586-026-11337-2","type":"correction","label":"Correction","source":"publisher","updated":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T00:00:00Z","timestamp":1793318400000}}],"container-title":["Nature"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41586-026-11136-9.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41586-026-11136-9","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41586-026-11136-9.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,31]],"date-time":"2026-10-31T06:38:12Z","timestamp":1793428692000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41586-026-11136-9"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,14]]},"references-count":25,"journal-issue":{"issue":"8137","published-print":{"date-parts":[[2026,10,22]]}},"alternative-id":["11136"],"URL":"https:\/\/doi.org\/10.1038\/s41586-026-11136-9","relation":{},"ISSN":["0028-0836","1476-4687"],"issn-type":[{"value":"0028-0836","type":"print"},{"value":"1476-4687","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,14]]},"assertion":[{"value":"2 February 2026","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"8 September 2026","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"14 October 2026","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"30 October 2026","order":5,"name":"change_date","label":"Change Date","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"Correction","order":6,"name":"change_type","label":"Change Type","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"A Correction to this paper has been published:","order":7,"name":"change_details","label":"Change Details","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"https:\/\/doi.org\/10.1038\/s41586-026-11337-2","URL":"https:\/\/doi.org\/10.1038\/s41586-026-11337-2","order":8,"name":"change_details","label":"Change Details","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interests.","order":1,"name":"Ethics","label":"Competing interests","group":{"name":"EthicsHeading","label":"Ethics"}}]}}