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The advantages of the synthesized fluorescent probe (compound <jats:bold>1<\/jats:bold>) were the low detection limit (4\u2009\u00d7\u200910<jats:sup>\u22126<\/jats:sup> mol\u0387L<jats:sup>\u22121<\/jats:sup>), good selectivity and high sensitivity which had been demonstrated through UV-vis, fluorescent titration experiments. Besides cytotoxicity test of compounds (<jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold>) was studied and the results indicated that compounds (<jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold>) showed almost no cytotoxicityat at a concentration of 150\u2009\u03bcg\u00b7mL<jats:sup>\u22121<\/jats:sup>. The interacted mechanism was the thiolysis reaction of dinitrophenyl ether which had been confirmed by fluorescence and HRMS titration experiment. 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