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The physical and chemical characteristics of samples were evaluated with different analyses. The obtained results demonstrated higher surface area for PTL\/Ar and negligible change in crystal structure, compared to NL. It was found that the synergistic effect between ozone and PTL\/Ar nanocatalyst was led to highest PhP degradation efficiency. The kinetic study confirmed the pseudo-first-order reaction for the PhP degradation processes included adsorption, peroxone and ozonation, catalytic ozonation with NL and PTL\/Ar. Long term application (6 cycles) confirmed the high stability of the PTL\/Ar. Moreover, different organic and inorganic salts as well as the dissolved ozone concentration demonstrated the predominant role of hydroxyl\u00a0radicals and superoxide radicals in PhP degradation by catalytic Ozonation using PTL\/Ar. The main produced intermediates during PhP oxidation by PTL\/Ar catalytic ozonation were identified using LC\u2013(+ESI)\u2013MS technique. Finally, the negligible iron leaching, higher mineralization rate, lower electrical energy consumption and excellent catalytic activity of PTL\/Ar samples demonstrate the superior application of non-thermal plasma for treatment of NL.<\/jats:p>","DOI":"10.1038\/s41598-020-80200-9","type":"journal-article","created":{"date-parts":[[2021,1,13]],"date-time":"2021-01-13T11:26:43Z","timestamp":1610537203000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["High performance ozone based advanced oxidation processes catalyzed with novel argon plasma treated iron oxyhydroxide hydrate for phenazopyridine degradation"],"prefix":"10.1038","volume":"11","author":[{"given":"Rasool","family":"Pelalak","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zahra","family":"Heidari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mojtaba","family":"Forouzesh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eslam","family":"Ghareshabani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reza","family":"Alizadeh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Azam","family":"Marjani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saeed","family":"Shirazian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2021,1,13]]},"reference":[{"key":"80200_CR1","doi-asserted-by":"publisher","first-page":"12","DOI":"10.1016\/j.cej.2016.01.022","volume":"290","author":"O Gimeno","year":"2016","unstructured":"Gimeno, O., Garc\u00eda-Araya, J. 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