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In this context, we presented the electrochemical behavior of these nanocomposites as an electrode for supercapacitors and as a catalyst in the oxidation process of methanol\/ethanol. Our engineered samples were characterized by X-ray diffraction pattern and scanning electron microscopy. As a result, MoO<jats:sub>3<\/jats:sub>\/WO<jats:sub>3<\/jats:sub> and MoO<jats:sub>3<\/jats:sub>\/WO<jats:sub>3<\/jats:sub>\/rGO indicated specific capacitances of 452 and 583 F\/g and stability of 88.9% and 92.6% after 2000 consecutive GCD cycles, respectively. Also, MoO<jats:sub>3<\/jats:sub>\/WO<jats:sub>3<\/jats:sub> and MoO<jats:sub>3<\/jats:sub>\/WO<jats:sub>3<\/jats:sub>\/rGO nanocatalysts showed oxidation current densities of 117 and 170 mA\/cm<jats:sup>2<\/jats:sup> at scan rate of 50 mV\/s, and stability of 71 and 89%, respectively in chronoamperometry analysis, in the MOR process. Interestingly, in the ethanol oxidation process, corresponding oxidation current densities of 42 and 106 mA\/cm<jats:sup>2<\/jats:sup> and stability values of 70 and 82% were achieved. 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