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The Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>@YS-Ph-PMO\/Pd was prepared through cetyltrimethylammonium bromide (CTAB) directed condensation of 1,4-bis(triethoxysilyl)benzene (BTEB) around Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>@silica nanoparticles followed by treatment with palladium acetate. This nanocatalyst was characterized by using Fourier transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), low-angle and wide-angle powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM) analyses. These analyses showed a magnetic nanomaterial with high chemical and thermal stability for the designed composite. The Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>@YS-Ph-PMO\/Pd nanocomposite was employed as a powerful and highly recoverable catalyst in the green reduction of nitroarenes in H<jats:sub>2<\/jats:sub>O at room temperature. A variety of nitroarene derivatives were applied as substrate in the presence of 0.9\u00a0mol% of Fe<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>@YS-Ph-PMO\/Pd catalyst. All nitroarenes were selectively converted to their corresponding amines with high to excellent yields (92\u201396%) within short reaction times (10\u201318\u00a0min). This catalyst was recovered and reused at least 11 times without significant decrease in efficiency and stability.<\/jats:p>","DOI":"10.1038\/s41598-024-66883-4","type":"journal-article","created":{"date-parts":[[2024,7,15]],"date-time":"2024-07-15T12:01:58Z","timestamp":1721044918000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Magnetic yolk-shell structured periodic mesoporous organosilica supported palladium as a powerful and highly recoverable nanocatalyst for the reduction of nitrobenzenes"],"prefix":"10.1038","volume":"14","author":[{"given":"Meysam","family":"Norouzi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dawood","family":"Elhamifar","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiva","family":"Kargar","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,7,15]]},"reference":[{"key":"66883_CR1","doi-asserted-by":"publisher","first-page":"3621","DOI":"10.1002\/adma.200803645","volume":"21","author":"Y Zhao","year":"2009","unstructured":"Zhao, Y. & Jiang, L. 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