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The MOFs were characterized by techniques such as FT-IR, PXRD, FE-SEM, and EDX. Through systematic optimization of key parameters (catalyst amount, time, temperature, solvent), MIP-202(Zr) achieved 99% styrene oxide conversion in 25\u00a0min with methanol at room temperature using 5\u00a0mg catalyst. In contrast, UiO-66-(CO\n                    <jats:sub>2<\/jats:sub>\n                    H)\n                    <jats:sub>2<\/jats:sub>\n                    required drastically harsher conditions of 120\u00a0min, 60\u00a0\u00b0C, and four times the catalyst loading to reach 98% conversion. A similar trend was observed for ring-opening with aniline \u2013MIP-202(Zr) gave 93% conversion in one hour at room temperature, while UiO-66-(CO\n                    <jats:sub>2<\/jats:sub>\n                    H)\n                    <jats:sub>2<\/jats:sub>\n                    needed two hours at 60\u00a0\u00b0C for 95% conversion. The superior performance of MIP-202(Zr) likely stems from cooperative Br\u00f8nsted\/Lewis acid sites and higher proton conductivity enabling more efficient epoxide activation. Remarkably, MIP-202(Zr) maintained consistent activity over five recycles in the ring-opening of styrene oxide by methanol and over three recycles in the ring-opening of styrene oxide by aniline. Testing various epoxide substrates and nucleophiles revealed trends in reactivity governed by electronic and steric effects. The results provide useful insights into tuning Zr-MOF-based catalysts and highlight the promise of the cost-effective and sustainable MIP-202(Zr) for diverse epoxide ring-opening reactions on an industrial scale.\n                  <\/jats:p>","DOI":"10.1038\/s41598-024-68497-2","type":"journal-article","created":{"date-parts":[[2024,7,31]],"date-time":"2024-07-31T16:04:53Z","timestamp":1722441893000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Superior and efficient performance of cost-effective MIP-202 catalyst over UiO-66-(CO2H)2 in epoxide ring opening reactions"],"prefix":"10.1038","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3009-3693","authenticated-orcid":false,"given":"Mojtaba","family":"Bagherzadeh","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-7318-7544","authenticated-orcid":false,"given":"Mohsen","family":"Chegeni","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3818-7539","authenticated-orcid":false,"given":"Arshad","family":"Bayrami","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6509-5942","authenticated-orcid":false,"given":"Mojtaba","family":"Amini","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2024,7,31]]},"reference":[{"key":"68497_CR1","doi-asserted-by":"publisher","first-page":"175","DOI":"10.1016\/B978-0-12-821632-3.00014-2","volume":"2002","author":"H Fa\u0142tynowicz","year":"2022","unstructured":"Fa\u0142tynowicz, H., Ku\u0142a\u017cynski, M. & Goodman, S. 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