{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,25]],"date-time":"2026-04-25T11:35:27Z","timestamp":1777116927859,"version":"3.51.4"},"reference-count":28,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2025,12,24]],"date-time":"2025-12-24T00:00:00Z","timestamp":1766534400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"},{"start":{"date-parts":[[2025,12,24]],"date-time":"2025-12-24T00:00:00Z","timestamp":1766534400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Sci Rep"],"DOI":"10.1038\/s41598-025-28202-3","type":"journal-article","created":{"date-parts":[[2025,12,24]],"date-time":"2025-12-24T13:37:39Z","timestamp":1766583459000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Enhanced CO oxidation via synergistic interactions of Pd and phosphotungstic acid confined within MIL-101(Cr)"],"prefix":"10.1038","volume":"15","author":[{"given":"Fateme","family":"Abbasi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cyrus","family":"Ghotbi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2025,12,24]]},"reference":[{"key":"28202_CR1","doi-asserted-by":"publisher","first-page":"589","DOI":"10.1016\/j.jhazmat.2013.08.056","volume":"262","author":"SY Jia","year":"2013","unstructured":"Jia, S. Y. et al. Adsorptive removal of Dibenzothiophene from model fuels over one-pot synthesized PTA@ MIL-101 (Cr) hybrid material. J. Hazard. Mater. 262, 589\u2013597 (2013).","journal-title":"J. Hazard. Mater."},{"key":"28202_CR2","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1038\/srep02916","volume":"3","author":"Q Liu","year":"2013","unstructured":"Liu, Q. et al. Adsorption of carbon dioxide by MIL-101 (Cr): Regeneration conditions and influence of flue gas contaminants. Sci. Rep. 3, 1\u20136 (2013).","journal-title":"Sci. Rep."},{"key":"28202_CR3","doi-asserted-by":"publisher","first-page":"113479","DOI":"10.1016\/j.inoche.2024.113479","volume":"170","author":"X Yang","year":"2024","unstructured":"Yang, X., Ye, Q., Ge, F. & Zhou, M. Heteropolyacids promoted NiMo\/MOF catalyst for catalytic oxidation of lignin dimers in oxygen atmosphere. Inorg. Chem. Commun. 170, 113479 (2024).","journal-title":"Inorg. Chem. Commun."},{"key":"28202_CR4","doi-asserted-by":"publisher","first-page":"12822","DOI":"10.1016\/j.ijhydene.2021.01.237","volume":"46","author":"F Abbasi","year":"2021","unstructured":"Abbasi, F., Karimi-Sabet, J. & Ghotbi, C. Reactivity and characteristics of Pd\/MOF and Pd\/calcinated-MOF catalysts for CO oxidation reaction: effect of oxygen and hydrogen. Int. J. Hydrogen Energy. 46, 12822\u201312834 (2021).","journal-title":"Int. J. Hydrogen Energy"},{"key":"28202_CR5","doi-asserted-by":"publisher","first-page":"3727","DOI":"10.1038\/s41598-025-87642-z","volume":"15","author":"X Zhang","year":"2025","unstructured":"Zhang, X., Wang, Z. & Guo, X. Confinement-induced Ni-based MOF formed on Ti3C2Tx MXene support for enhanced capacitive Deionization of chromium (VI). Sci. Rep. 15, 3727 (2025).","journal-title":"Sci. Rep."},{"key":"28202_CR6","doi-asserted-by":"publisher","first-page":"4655","DOI":"10.1166\/jnn.2016.12602","volume":"16","author":"Z Pei","year":"2016","unstructured":"Pei, Z., Zheng, X. & Li, Z. Progress on synthesis and applications of Cr2O3 nanoparticles. J. Nanosci. Nanotechnol. 16, 4655\u20134671 (2016).","journal-title":"J. Nanosci. Nanotechnol"},{"key":"28202_CR7","doi-asserted-by":"publisher","first-page":"21450","DOI":"10.1016\/j.ijhydene.2020.05.223","volume":"45","author":"F Abbasi","year":"2020","unstructured":"Abbasi, F., Karimi-Sabet, J. & Ghotbi, C. Efficient CO oxidation over palladium supported on various mofs: Synthesis, amorphization, and space velocity of hydrogen stream. Int. J. Hydrogen Energy. 45, 21450\u201321463 (2020).","journal-title":"Int. J. Hydrogen Energy"},{"key":"28202_CR8","doi-asserted-by":"crossref","unstructured":"Abbasi, F. & Ghotbi, C. MOF-Derived oxide supported metal nanoparticle catalysts: A novel catalyst platform for synergistic N\u2082O decomposition and CO oxidation. J Environ. Chem. Eng 118757 (2025).","DOI":"10.1016\/j.jece.2025.118757"},{"key":"28202_CR9","doi-asserted-by":"publisher","first-page":"1664","DOI":"10.1021\/cm2034382","volume":"24","author":"L Bromberg","year":"2012","unstructured":"Bromberg, L., Diao, Y., Wu, H., Speakman, S. A. & Hatton, T. A. Chromium (III) terephthalate metal organic framework (MIL-101): HF-free synthesis, structure, polyoxometalate composites, and catalytic properties. Chem. Mater. 24, 1664\u20131675 (2012).","journal-title":"Chem. Mater."},{"key":"28202_CR10","doi-asserted-by":"publisher","first-page":"14759","DOI":"10.1021\/acsami.9b00415","volume":"11","author":"R Abazari","year":"2019","unstructured":"Abazari, R., Sanati, S., Morsali, A., Slawin, A. & Carpenter-Warren, L. Dual-purpose 3D pillared metal\u2013organic framework with excellent properties for catalysis of oxidative desulfurization and energy storage in asymmetric supercapacitor. ACS Appl. Mater. Interfaces. 11, 14759\u201314773 (2019).","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"28202_CR11","doi-asserted-by":"publisher","first-page":"281","DOI":"10.1002\/ijch.201000082","volume":"51","author":"NV Maksimchuk","year":"2011","unstructured":"Maksimchuk, N. V., Kholdeeva, O. A., Kovalenko, K. A. & Fedin, V. P. MIL-101 supported polyoxometalates: Synthesis, Characterization, and catalytic applications in selective Liquid\u2010Phase oxidation. Isr. J. Chem. 51, 281\u2013289 (2011).","journal-title":"Isr. J. Chem."},{"key":"28202_CR12","doi-asserted-by":"publisher","first-page":"59","DOI":"10.1002\/cssc.201000284","volume":"4","author":"Y Zhang","year":"2011","unstructured":"Zhang, Y., Degirmenci, V., Li, C. & Hensen, E. J. M. Phosphotungstic acid encapsulated in metal\u2013organic framework as catalysts for carbohydrate dehydration to 5-hydroxymethylfurfural. ChemSusChem 4, 59\u201364 (2011).","journal-title":"ChemSusChem"},{"key":"28202_CR13","doi-asserted-by":"publisher","first-page":"4756","DOI":"10.1021\/am201246d","volume":"3","author":"L Bromberg","year":"2011","unstructured":"Bromberg, L. & Hatton, T. A. Aldehyde-alcohol reactions catalyzed under mild conditions by chromium (III) terephthalate metal organic framework (MIL-101) and phosphotungstic acid composites. ACS Appl. Mater. Interfaces. 3, 4756\u20134764 (2011).","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"28202_CR14","doi-asserted-by":"publisher","first-page":"8459","DOI":"10.1002\/ange.201602801","volume":"128","author":"B Zhang","year":"2016","unstructured":"Zhang, B. et al. Stabilizing a platinum1 single-atom catalyst on supported phosphomolybdic acid without compromising hydrogenation activity. Angew Chemie. 128, 8459\u20138463 (2016).","journal-title":"Angew Chemie"},{"key":"28202_CR15","doi-asserted-by":"publisher","first-page":"1545","DOI":"10.1002\/cssc.201200914","volume":"6","author":"J Chen","year":"2013","unstructured":"Chen, J. et al. Conversion of cellulose and cellobiose into sorbitol catalyzed by ruthenium supported on a polyoxometalate\/metal\u2013organic framework hybrid. ChemSusChem 6, 1545\u20131555 (2013).","journal-title":"ChemSusChem"},{"key":"28202_CR16","doi-asserted-by":"publisher","first-page":"128","DOI":"10.1016\/j.inoche.2015.09.004","volume":"61","author":"ZD Tan","year":"2015","unstructured":"Tan, Z. D. et al. Metal-organic framework MIL-53(Al)-supported copper catalyst for CO catalytic oxidation reaction. Inorg. Chem. Commun. 61, 128\u2013131 (2015).","journal-title":"Inorg. Chem. Commun."},{"key":"28202_CR17","doi-asserted-by":"publisher","first-page":"2167","DOI":"10.1039\/c0cc04944a","volume":"47","author":"J Ye","year":"2011","unstructured":"Ye, J. & Liu, C. Cu 3 (BTC) 2: CO oxidation over MOF based catalysts. Chem. Commun. 47, 2167\u20132169 (2011).","journal-title":"Chem. Commun."},{"key":"28202_CR18","doi-asserted-by":"crossref","unstructured":"Zhang, X., Zhan, Z., Li, Z. & Di, L. Thermal activation of CuBTC MOF for CO oxidation: the effect of activation atmosphere. Catalysts 7, (2017).","DOI":"10.3390\/catal7040106"},{"key":"28202_CR19","doi-asserted-by":"publisher","first-page":"11302","DOI":"10.1021\/ja9047653","volume":"131","author":"HL Jiang","year":"2009","unstructured":"Jiang, H. L. et al. Au@ZIF-8: CO oxidation over gold nanoparticles deposited to metal-organic framework. J. Am. Chem. Soc. 131, 11302\u201311303 (2009).","journal-title":"J. Am. Chem. Soc."},{"key":"28202_CR20","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1016\/j.tca.2009.11.004","volume":"499","author":"W Kleist","year":"2010","unstructured":"Kleist, W., Maciejewski, M. & Baiker, A. MOF-5 based mixed-linker metal\u2013organic frameworks: Synthesis, thermal stability and catalytic application. Thermochim Acta. 499, 71\u201378 (2010).","journal-title":"Thermochim Acta"},{"key":"28202_CR21","doi-asserted-by":"publisher","first-page":"2040","DOI":"10.1126\/science.1116275","volume":"309","author":"G F\u00e9rey","year":"2005","unstructured":"F\u00e9rey, G. et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Sci. (80-). 309, 2040\u20132042 (2005).","journal-title":"Sci. (80-)"},{"key":"28202_CR22","doi-asserted-by":"publisher","first-page":"153295","DOI":"10.1016\/j.cej.2024.153295","volume":"495","author":"X Zhou","year":"2024","unstructured":"Zhou, X. et al. CuO nano-island anchored Pt catalyst for CO Preferential oxidation in H2-rich stream. Chem. Eng. J. 495, 153295 (2024).","journal-title":"Chem. Eng. J."},{"key":"28202_CR23","doi-asserted-by":"publisher","first-page":"3824","DOI":"10.1038\/s41467-019-11871-w","volume":"10","author":"S Zhao","year":"2019","unstructured":"Zhao, S. et al. Remarkable active-site dependent H2O promoting effect in CO oxidation. Nat. Commun. 10, 3824 (2019).","journal-title":"Nat. Commun."},{"key":"28202_CR24","doi-asserted-by":"crossref","unstructured":"Abbasi, F. & Ghotbi, C. Enhanced CO oxidation over Pd\/MIL catalysts promoted by co-impregnated alkali and alkaline Earth metals. Inorg Chem. Commun 115338 (2025).","DOI":"10.1016\/j.inoche.2025.115338"},{"key":"28202_CR25","doi-asserted-by":"publisher","first-page":"1604","DOI":"10.1021\/cs200351p","volume":"1","author":"H Li","year":"2011","unstructured":"Li, H. et al. Palladium nanoparticles confined in the cages of MIL-101: an efficient catalyst for the one-pot Indole synthesis in water. ACS Catal. 1, 1604\u20131612 (2011).","journal-title":"ACS Catal."},{"key":"28202_CR26","doi-asserted-by":"publisher","first-page":"8071","DOI":"10.1002\/chem.201101004","volume":"17","author":"J Hermannsd\u00f6rfer","year":"2011","unstructured":"Hermannsd\u00f6rfer, J. & Kempe, R. Selective Palladium-Loaded MIL\u2010101 catalysts. Chem. Eur. J. 17, 8071\u20138077 (2011).","journal-title":"Chem. Eur. J."},{"key":"28202_CR27","doi-asserted-by":"crossref","unstructured":"Abbasi, F., Karimi-Sabet, J., Abbasi, Z. & Ghotbi, C. Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework. Front Chem. Sci. Eng 1\u201310 (2021).","DOI":"10.1007\/s11705-021-2111-5"},{"key":"28202_CR28","doi-asserted-by":"crossref","unstructured":"Abbasi, F., Karimi-Sabet, J., Abbasi, Z. & Ghotbi, C. Improved method for increasing accessible pores of MIL-101 (Cr) by encapsulation and removal of phosphotungstic acid (PTA): Pd\/PTA-MIL-101 (Cr) as an effective catalyst for CO oxidation. J Clean. Prod 131168 (2022).","DOI":"10.1016\/j.jclepro.2022.131168"}],"container-title":["Scientific Reports"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-28202-3.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-28202-3","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-28202-3.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,25]],"date-time":"2026-04-25T10:45:34Z","timestamp":1777113934000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-28202-3"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,24]]},"references-count":28,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2025,12]]}},"alternative-id":["28202"],"URL":"https:\/\/doi.org\/10.1038\/s41598-025-28202-3","relation":{"has-preprint":[{"id-type":"doi","id":"10.21203\/rs.3.rs-6437540\/v1","asserted-by":"object"}]},"ISSN":["2045-2322"],"issn-type":[{"value":"2045-2322","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,24]]},"assertion":[{"value":"13 April 2025","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"10 November 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"24 December 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"The authors declare no competing interests.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"44602"}}