{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T05:14:51Z","timestamp":1791954891014,"version":"4.3.4"},"reference-count":76,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T00:00:00Z","timestamp":1738108800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"},{"start":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T00:00:00Z","timestamp":1738108800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Sci Rep"],"DOI":"10.1038\/s41598-025-87564-w","type":"journal-article","created":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T07:46:11Z","timestamp":1738136771000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["Experimental and computational approach on the corrosion inhibition properties of two newly pyrazole derivatives on carbon steel in acid medium"],"prefix":"10.1038","volume":"15","author":[{"given":"Nawal","family":"Setti","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Asma","family":"Barrahi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohamed","family":"Maatallah","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yassine","family":"Kaddouri","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taibi Ben","family":"Hadda","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Halima","family":"Outada","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abhinay","family":"Thakur","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rachid","family":"Touzani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khalid","family":"Karrouchi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hatem A.","family":"Abuelizz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Burak","family":"Dikici","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5495-2125","authenticated-orcid":false,"given":"Abdelkader","family":"Zarrouk","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ali","family":"Dafali","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,1,29]]},"reference":[{"key":"87564_CR1","doi-asserted-by":"publisher","first-page":"105918","DOI":"10.1016\/j.jcsr.2019.105918","volume":"166","author":"F Fu","year":"2020","unstructured":"Fu, F. Fire induced progressive collapse potential assessment of steel framed buildings using machine learning. J. Constr. Steel Res. 166, 105918. https:\/\/doi.org\/10.1016\/j.jcsr.2019.105918 (2020).","journal-title":"J. Constr. Steel Res."},{"key":"87564_CR2","doi-asserted-by":"publisher","first-page":"100394","DOI":"10.1016\/j.cdc.2020.100394","volume":"27","author":"M Rbaa","year":"2020","unstructured":"Rbaa, M. et al. Synthesis of new epoxy glucose derivatives as a non-toxic corrosion inhibitors for carbon steel in molar HCl: experimental, DFT and MD simulation. Chem. Data Collect. 27, 100394. https:\/\/doi.org\/10.1016\/j.cdc.2020.100394 (2020).","journal-title":"Chem. Data Collect."},{"key":"87564_CR3","doi-asserted-by":"publisher","first-page":"3010","DOI":"10.1016\/S1452-3981(23)06515-X","volume":"10","author":"M Belayachi","year":"2015","unstructured":"Belayachi, M. et al. New pyrimidothiazine derivative as Corrosion Inhibitor for Carbon Steel in Acidic Media. Int. J. Electrochem. Sci. 10, 3010\u20133025. https:\/\/doi.org\/10.1016\/S1452-3981(23)06515-X (2015).","journal-title":"Int. J. Electrochem. Sci."},{"key":"87564_CR4","first-page":"636","volume":"8","author":"K Cherrak","year":"2017","unstructured":"Cherrak, K. et al. Two new benzothiazine derivatives as corrosion inhibitors for mild steel in hydrochloric acid medium. J. Mater. Environ. Sci. 8, 636\u2013647 (2017).","journal-title":"J. Mater. Environ. Sci."},{"key":"87564_CR5","doi-asserted-by":"publisher","first-page":"128499","DOI":"10.1016\/j.matchemphys.2023.128499","volume":"311","author":"H Jafari","year":"2024","unstructured":"Jafari, H., Ameri, E., Vakili, M. H. & Berisha, A. Novel Silicon-based schiff-base as corrosion inhibitor for anti-corrosion behavior of API 5L Grade B in 1\u00a0M HCl. Mater. Chem. Phys. 311, 128499. https:\/\/doi.org\/10.1016\/j.matchemphys.2023.128499 (2024).","journal-title":"Mater. Chem. Phys."},{"key":"87564_CR6","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1016\/j.jtice.2019.12.006","volume":"107","author":"A Sedik","year":"2020","unstructured":"Sedik, A. et al. Dardagan Fruit extract as eco-friendly corrosion inhibitor for mild steel in 1\u00a0M HCl: Electrochemical and surface morphological studies. J. Taiwan. Inst. Chem. Eng. 107, 189\u2013200. https:\/\/doi.org\/10.1016\/j.jtice.2019.12.006 (2020).","journal-title":"J. Taiwan. Inst. Chem. Eng."},{"key":"87564_CR7","doi-asserted-by":"publisher","unstructured":"Setti, N. et al. Experimental and computational investigation of novel triazole-pyrazole derivative as a synthetic corrosion inhibitor for M-steel in 1.0\u00a0M HCl. in BIO Web of Conferences. EDP Sciences. 109, 01021. (2024). https:\/\/doi.org\/10.1051\/bioconf\/202410901021","DOI":"10.1051\/bioconf\/202410901021"},{"key":"87564_CR8","doi-asserted-by":"publisher","first-page":"19301","DOI":"10.1039\/D3RA00357D","volume":"13","author":"I Arshad","year":"2023","unstructured":"Arshad, I. et al. Melamine\u2013isatin tris Schiff base as an efficient corrosion inhibitor for mild steel in 0.5 molar hydrochloric acid solution: weight loss, electrochemical and surface studies. RSC Adv. 13, 19301\u201319311. https:\/\/doi.org\/10.1039\/D3RA00357D (2023).","journal-title":"RSC Adv."},{"key":"87564_CR9","doi-asserted-by":"publisher","first-page":"2555","DOI":"10.1007\/s11814-023-1527-7","volume":"40","author":"I Arshad","year":"2023","unstructured":"Arshad, I. et al. Melamine-benzaldehyde tris-schiff base as an efficient corrosion inhibitor for mild steel in 0.5 molar hydrochloric acid solution: weight loss, electrochemical, theoretical and surface studies. Korean J. Chem. Eng. 40, 2555\u20132564. https:\/\/doi.org\/10.1007\/s11814-023-1527-7 (2023).","journal-title":"Korean J. Chem. Eng."},{"key":"87564_CR10","doi-asserted-by":"publisher","first-page":"159","DOI":"10.1007\/s40090-019-0181-8","volume":"10","author":"SK Ahmed","year":"2019","unstructured":"Ahmed, S. K., Ali, W. B. & Khadom, A. A. Synthesis and investigations of heterocyclic compounds as corrosion inhibitors for mild steel in hydrochloric acid. Int. J. Ind. Chem. 10, 159\u2013173. https:\/\/doi.org\/10.1007\/s40090-019-0181-8 (2019).","journal-title":"Int. J. Ind. Chem."},{"key":"87564_CR11","doi-asserted-by":"publisher","first-page":"100252","DOI":"10.1016\/j.cdc.2019.100252","volume":"22","author":"K Cherrak","year":"2019","unstructured":"Cherrak, K. et al. Corrosion inhibition of mild steel by new Benzothiazine derivative in a hydrochloric acid solution: experimental evaluation and theoretical calculations. Chem. Data Collect. 22, 100252. https:\/\/doi.org\/10.1016\/j.cdc.2019.100252 (2019).","journal-title":"Chem. Data Collect."},{"key":"87564_CR12","doi-asserted-by":"publisher","first-page":"7359","DOI":"10.1007\/s13369-022-07281-8","volume":"48","author":"H Jafari","year":"2023","unstructured":"Jafari, H. et al. 4,4\u2019-(((2,2-Dimethylpropane-1,3-Diyl) Bis (Azanediyl)Bis (Methylene) Bis(2-Methoxyphenol) as new reduced form of Schiff Base for protecting API 5L Grade B in 1\u00a0M HCl. Arab. J. Sci. Eng. 48, 7359\u20137372. https:\/\/doi.org\/10.1007\/s13369-022-07281-8 (2023).","journal-title":"Arab. J. Sci. Eng."},{"key":"87564_CR13","doi-asserted-by":"publisher","first-page":"107653","DOI":"10.1016\/j.elecom.2023.107653","volume":"159","author":"H Jafari","year":"2024","unstructured":"Jafari, H., Ameri, E., Vakili, M. H. & Berisha, A. Effect of OH position on adsorption behavior of Schiff-base derivatives in corrosion inhibition of carbon steel in 1\u00a0M HCl. Electrochem. Commun. 159, 107653. https:\/\/doi.org\/10.1016\/j.elecom.2023.107653 (2024).","journal-title":"Electrochem. Commun."},{"key":"87564_CR14","doi-asserted-by":"publisher","first-page":"1387","DOI":"10.1016\/j.arabjc.2014.11.018","volume":"12","author":"H Jafari","year":"2019","unstructured":"Jafari, H., Akbarzade, K. & Danaee, I. Corrosion inhibition of carbon steel immersed in a 1\u00a0M HCl solution using benzothiazole derivatives. Arab. J. Chem. 12, 1387\u20131394. https:\/\/doi.org\/10.1016\/j.arabjc.2014.11.018 (2019).","journal-title":"Arab. J. Chem."},{"key":"87564_CR15","doi-asserted-by":"publisher","first-page":"117507","DOI":"10.1016\/j.molliq.2021.117507","volume":"342","author":"K Cherrak","year":"2021","unstructured":"Cherrak, K. et al. Electrochemical and theoretical performance of new synthetized pyrazole derivatives as promising corrosion inhibitors for mild steel in acid environment: molecular structure effect on efficiency. J. Mol. Liq. 342, 117507. https:\/\/doi.org\/10.1016\/j.molliq.2021.117507 (2021).","journal-title":"J. Mol. Liq"},{"key":"87564_CR16","doi-asserted-by":"publisher","first-page":"740","DOI":"10.1016\/j.jcis.2020.07.073","volume":"580","author":"A Berrissoul","year":"2020","unstructured":"Berrissoul, A. et al. Anticorrosion effect of a green sustainable inhibitor on mild steel in hydrochloric acid. J. Colloid Interf Sci. 580, 740\u2013752. https:\/\/doi.org\/10.1016\/j.jcis.2020.07.073 (2020).","journal-title":"J. Colloid Interf Sci."},{"key":"87564_CR17","doi-asserted-by":"publisher","first-page":"874","DOI":"10.1016\/j.molliq.2015.12.093","volume":"216","author":"M Belghiti","year":"2016","unstructured":"Belghiti, M. et al. Anti-corrosive properties of 4-amino-3, 5-bis (disubstituted)-1, 2, 4-triazole derivatives on mild steel corrosion in 2\u00a0M H3PO4 solution: experimental and theoretical studies. J. Mol. Liq. 216, 874\u2013886. https:\/\/doi.org\/10.1016\/j.molliq.2015.12.093 (2016).","journal-title":"J. Mol. Liq"},{"key":"87564_CR18","doi-asserted-by":"publisher","first-page":"1436","DOI":"10.1016\/j.cjche.2020.03.002","volume":"28","author":"F Benhiba","year":"2020","unstructured":"Benhiba, F. et al. Combined electronic\/atomic level computational, surface (SEM\/EDS), chemical and electrochemical studies of the mild steel surface by quinoxalines derivatives anti-corrosion properties in 1 mol\u22c5 L-1 HCl solution. J. Chem. Eng. 28, 1436\u20131458. https:\/\/doi.org\/10.1016\/j.cjche.2020.03.002 (2020).","journal-title":"J. Chem. Eng."},{"issue":"8","key":"87564_CR19","first-page":"265","volume":"7","author":"Y ELouadi","year":"2015","unstructured":"ELouadi, Y. et al. Corrosion inhibition of mild steel by new N-heterocyclic compound in 1\u00a0M HCl: experimental and computational study. Der Pharma Chem. 7(8), 265\u2013275 (2015).","journal-title":"Der Pharma Chem."},{"key":"87564_CR20","doi-asserted-by":"publisher","first-page":"110645","DOI":"10.1016\/j.jpcs.2022.110645","volume":"164","author":"H Jafari","year":"2022","unstructured":"Jafari, H., Ameri, E., Rezaeivala, M., Berisha, A. & Halili, J. Anti-corrosion behavior of two N2O4 Schiff-base ligands: experimental and theoretical studies. J. Phys. Chem. Solids. 164, 110645. https:\/\/doi.org\/10.1016\/j.jpcs.2022.110645 (2022).","journal-title":"J. Phys. Chem. Solids"},{"key":"87564_CR21","doi-asserted-by":"publisher","first-page":"503","DOI":"10.1016\/j.molliq.2018.12.015","volume":"276","author":"AA Fadhil","year":"2019","unstructured":"Fadhil, A. A. et al. (S)\u20136\u2013Phenyl\u20132, 3, 5, 6\u2013tetrahydroimidazo [2, 1\u2013b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation. J. Mol. Liq. 276, 503\u2013518. https:\/\/doi.org\/10.1016\/j.molliq.2018.12.015 (2019).","journal-title":"J. Mol. Liq"},{"key":"87564_CR22","doi-asserted-by":"publisher","first-page":"110","DOI":"10.1016\/j.corsci.2016.05.002","volume":"111","author":"N Yilmaz","year":"2016","unstructured":"Yilmaz, N., Fitoz, A. & Emreg\u00fcl, K. C. A combined electrochemical and theoretical study into the effect of 2-((thiazole-2-ylimino) methyl) phenol as a corrosion inhibitor for mild steel in a highly acidic environment. Corros. Sci. 111, 110\u2013120. https:\/\/doi.org\/10.1016\/j.corsci.2016.05.002 (2016).","journal-title":"Corros. Sci."},{"key":"87564_CR23","doi-asserted-by":"publisher","first-page":"132925","DOI":"10.1016\/j.molstruc.2022.132925","volume":"1261","author":"K Cherrak","year":"2022","unstructured":"Cherrak, K. et al. Performance evaluation of newly synthetized bi-pyrazole derivatives as corrosion inhibitors for mild steel in acid environment. J. Mol. Struct. 1261, 132925. https:\/\/doi.org\/10.1016\/j.molstruc.2022.132925 (2022).","journal-title":"J. Mol. Struct."},{"key":"87564_CR24","doi-asserted-by":"publisher","first-page":"125744","DOI":"10.1016\/j.colsurfa.2020.125744","volume":"610","author":"M Chafiq","year":"2021","unstructured":"Chafiq, M., Chaouiki, A., Al-Hadeethi, M. R., Salghi, R. & Chung, I. M. A joint experimental and theoretical investigation of the corrosion inhibition behavior and mechanism of hydrazone derivatives for mild steel in HCl solution. Colloids Surf. 610, 125744. https:\/\/doi.org\/10.1016\/j.colsurfa.2020.125744 (2021).","journal-title":"Colloids Surf."},{"key":"87564_CR25","doi-asserted-by":"publisher","first-page":"796","DOI":"10.1016\/j.matchemphys.2010.09.056","volume":"125","author":"R Solmaz","year":"2011","unstructured":"Solmaz, R., Altunba\u015f, E. & Karda\u015f, G. Adsorption and corrosion inhibition effect of 2-((5-mercapto-1, 3, 4-thiadiazol-2-ylimino) methyl) phenol Schiff base on mild steel. Mater. Chem. Phys. 125, 796\u2013801. https:\/\/doi.org\/10.1016\/j.matchemphys.2010.09.056 (2011).","journal-title":"Mater. Chem. Phys."},{"key":"87564_CR26","doi-asserted-by":"publisher","first-page":"1337","DOI":"10.3390\/molecules21101337","volume":"21","author":"YA Elshaier","year":"2016","unstructured":"Elshaier, Y. A., Barakat, A., Al-Qahtany, B. M., Al-Majid, A. M. & Al-Agamy, M. H. Synthesis of pyrazole-thiobarbituric acid derivatives: antimicrobial activity and docking studies. Molecules 21, 1337. https:\/\/doi.org\/10.3390\/molecules21101337 (2016).","journal-title":"Molecules"},{"key":"87564_CR27","doi-asserted-by":"publisher","first-page":"3730","DOI":"10.1016\/j.bmcl.2015.06.025","volume":"25","author":"JJ Shah","year":"2015","unstructured":"Shah, J. J., Khedkar, V., Coutinho, E. C. & Mohanraj, K. Design, synthesis and evaluation of benzotriazole derivatives as novel antifungal agents. Bioorg. Med. Chem. Lett. 25, 3730\u20133737. https:\/\/doi.org\/10.1016\/j.bmcl.2015.06.025 (2015).","journal-title":"Med. Chem. Lett."},{"key":"87564_CR28","doi-asserted-by":"publisher","first-page":"104696","DOI":"10.1016\/j.bioorg.2021.104696","volume":"110","author":"Y Kaddouri","year":"2021","unstructured":"Kaddouri, Y. et al. Synthesis, characterization, reaction mechanism prediction and biological study of mono, bis and tetrakis pyrazole derivatives against Fusarium oxysporum f. sp. Albedinis with conceptual DFT and ligand-protein docking studies. Bioorg. Chem. 110, 104696. https:\/\/doi.org\/10.1016\/j.bioorg.2021.104696 (2021).","journal-title":"Bioorg. Chem."},{"key":"87564_CR29","doi-asserted-by":"publisher","first-page":"6663245","DOI":"10.1155\/2021\/6663245","volume":"2021","author":"Y Kaddouri","year":"2021","unstructured":"Kaddouri, Y. et al. ADME-Tox predictions, and antimicrobial evaluation of novel mono\u2010and tetra\u2010alkylated pyrazole and triazole ligands. J. Chem. 2021, 6663245. https:\/\/doi.org\/10.1155\/2021\/6663245 (2021).","journal-title":"J. Chem."},{"key":"87564_CR30","doi-asserted-by":"publisher","first-page":"3123","DOI":"10.1016\/j.tet.2006.01.034","volume":"62","author":"M Daoudi","year":"2006","unstructured":"Daoudi, M. et al. Synthesis of N,N\u2032-bis and N,N,N\u2032,N\u2032-tetra-[(3, 5-di-substituted-1-pyrazolyl) methyl] para-phenylenediamines: new candidate ligands for metal complex wires. Tetrahedron 62, 3123\u20133127. https:\/\/doi.org\/10.1016\/j.tet.2006.01.034 (2006).","journal-title":"Tetrahedron"},{"key":"87564_CR31","doi-asserted-by":"publisher","first-page":"269","DOI":"10.3390\/80200269","volume":"8","author":"M Daoudi","year":"2003","unstructured":"Daoudi, M. et al. Crystal structure of N, N, N\u2019, N\u2019-tetra-[(3, 5-dimethyl-1-pyrazolyl) methyl]-para-phenylenediamine. Molecules 8, 269\u2013274. https:\/\/doi.org\/10.3390\/80200269 (2003).","journal-title":"Molecules"},{"key":"87564_CR32","unstructured":"A.S.f. Testing, Materials, ASTM G1-03: standard practice for preparing, cleaning, and evaluating corrosion test specimens, ASTM, (2004)."},{"key":"87564_CR33","unstructured":"Frisch, M. gaussian 09, Revision d. 01, Gaussian. 201 (2009)."},{"key":"87564_CR34","doi-asserted-by":"publisher","first-page":"100578","DOI":"10.1016\/j.surfin.2020.100578","volume":"20","author":"K Cherrak","year":"2020","unstructured":"Cherrak, K. et al. Pyrazole carbohydrazide as corrosion inhibitor for mild steel in HCl medium: experimental and theoretical investigations. Surf. Interfaces. 20, 100578. https:\/\/doi.org\/10.1016\/j.surfin.2020.100578 (2020).","journal-title":"Surf. Interfaces"},{"key":"87564_CR35","unstructured":"BIOVIA, D. S. BIOVIA materials studio. 92121 (2016)."},{"key":"87564_CR36","doi-asserted-by":"publisher","first-page":"7338","DOI":"10.1021\/jp980939v","volume":"102","author":"H Sun","year":"1998","unstructured":"Sun, H. COMPASS: an ab initio force-field optimized for condensed-phase applications overview with details on alkane and benzene compounds. J. Phys. Chem. 102, 7338\u20137364. https:\/\/doi.org\/10.1021\/jp980939v (1998).","journal-title":"J. Phys. Chem."},{"key":"87564_CR37","doi-asserted-by":"publisher","first-page":"707","DOI":"10.1016\/j.apsusc.2019.04.125","volume":"491","author":"M Belghiti","year":"2019","unstructured":"Belghiti, M. et al. Computational simulation and statistical analysis on the relationship between corrosion inhibition efficiency and molecular structure of some hydrazine derivatives in phosphoric acid on mild steel surface. Appl. Surf. Sci. 491, 707\u2013722. https:\/\/doi.org\/10.1016\/j.apsusc.2019.04.125 (2019).","journal-title":"Appl. Surf. Sci."},{"key":"87564_CR38","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1016\/j.corsci.2013.05.023","volume":"75","author":"M Tourabi","year":"2013","unstructured":"Tourabi, M., Nohair, K., Traisnel, M., Jama, C. & Bentiss, F. Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3, 5-bis (2-thienylmethyl)-4-amino-1, 2, 4-triazole. Corros. Sci. 75, 123\u2013133. https:\/\/doi.org\/10.1016\/j.corsci.2013.05.023 (2013).","journal-title":"Corros. Sci."},{"key":"87564_CR39","doi-asserted-by":"publisher","first-page":"118102","DOI":"10.1016\/j.molliq.2021.118102","volume":"349","author":"A Berrissoul","year":"2022","unstructured":"Berrissoul, A. et al. Exploitation of a new green inhibitor against mild steel corrosion in HCl: experimental, DFT and MD simulation approach. J. Mol. Liq. 349, 118102. https:\/\/doi.org\/10.1016\/j.molliq.2021.118102 (2022).","journal-title":"J. Mol. Liq"},{"key":"87564_CR40","doi-asserted-by":"publisher","first-page":"150","DOI":"10.1016\/j.porgcoat.2018.10.001","volume":"126","author":"W Gong","year":"2019","unstructured":"Gong, W., Yin, X., Liu, Y., Chen, Y. & Yang, W. 2-Amino-4-(4-methoxyphenyl)-thiazole as a novel corrosion inhibitor for mild steel in acidic medium. Prog Org. Coat. 126, 150\u2013161. https:\/\/doi.org\/10.1016\/j.porgcoat.2018.10.001 (2019).","journal-title":"Prog Org. Coat."},{"key":"87564_CR41","doi-asserted-by":"publisher","first-page":"125320","DOI":"10.1016\/j.colsurfa.2020.125320","volume":"604","author":"A Attou","year":"2020","unstructured":"Attou, A. et al. Experimental studies and computational exploration on the 2-amino-5-(2-methoxyphenyl)-1, 3, 4-thiadiazole as novel corrosion inhibitor for mild steel in acidic environment. Colloids Surf. 604, 125320. https:\/\/doi.org\/10.1016\/j.colsurfa.2020.125320 (2020).","journal-title":"Colloids Surf."},{"key":"87564_CR42","doi-asserted-by":"publisher","first-page":"1770","DOI":"10.1016\/j.corsci.2011.01.055","volume":"53","author":"A Popova","year":"2011","unstructured":"Popova, A., Christov, M. & Vasilev, A. Mono-and dicationic benzothiazolic quaternary ammonium bromides as mild steel corrosion inhibitors. Part II: Electrochemical impedance and polarisation resistance results. Corros. Sci. 53, 1770\u20131777. https:\/\/doi.org\/10.1016\/j.corsci.2011.01.055 (2011).","journal-title":"Corros. Sci."},{"key":"87564_CR43","doi-asserted-by":"publisher","first-page":"113874","DOI":"10.1016\/j.molliq.2020.113874","volume":"316","author":"C Verma","year":"2020","unstructured":"Verma, C., Ebenso, E. E. & Quraishi, M. Molecular structural aspects of organic corrosion inhibitors: influence of\u2013CN and\u2013NO2 substituents on designing of potential corrosion inhibitors for aqueous media. J. Mol. Liq. 316, 113874. https:\/\/doi.org\/10.1016\/j.molliq.2020.113874 (2020).","journal-title":"J. Mol. Liq"},{"key":"87564_CR44","doi-asserted-by":"publisher","first-page":"2310","DOI":"10.1149\/1.2097847","volume":"136","author":"F Growcock","year":"1989","unstructured":"Growcock, F. & Jasinski, R. Time-resolved impedance spectroscopy of mild steel in concentrated hydrochloric acid. J. Electrochem. Soc. 136, 2310. https:\/\/doi.org\/10.1149\/1.2097847 (1989).","journal-title":"J. Electrochem. Soc."},{"key":"87564_CR45","doi-asserted-by":"publisher","first-page":"302","DOI":"10.1016\/j.molliq.2017.09.057","volume":"246","author":"Y Kharbach","year":"2017","unstructured":"Kharbach, Y. et al. Anticorrosion performance of three newly synthesized isatin derivatives on carbon steel in hydrochloric acid pickling environment: electrochemical, surface and theoretical studies. J. Mol. Liq. 246, 302\u2013316. https:\/\/doi.org\/10.1016\/j.molliq.2017.09.057 (2017).","journal-title":"J. Mol. Liq"},{"key":"87564_CR46","doi-asserted-by":"publisher","first-page":"115310","DOI":"10.1016\/j.indcrop.2022.115310","volume":"187","author":"A Berrissoul","year":"2022","unstructured":"Berrissoul, A. et al. Assessment of corrosion inhibition performance of origanum compactum extract for mild steel in 1\u00a0M HCl: weight loss, electrochemical, SEM\/EDX, XPS, DFT and molecular dynamic simulation. Ind. Crops Prod. 187, 115310. https:\/\/doi.org\/10.1016\/j.indcrop.2022.115310 (2022).","journal-title":"Ind. Crops Prod."},{"key":"87564_CR47","doi-asserted-by":"publisher","first-page":"952","DOI":"10.1016\/j.apsusc.2016.07.115","volume":"389","author":"M Bouanis","year":"2016","unstructured":"Bouanis, M. et al. Corrosion inhibition performance of 2, 5-bis (4-dimethylaminophenyl)-1, 3, 4-oxadiazole for carbon steel in HCl solution: Gravimetric, electrochemical and XPS studies. Appl. Surf. Sci. 389, 952\u2013966. https:\/\/doi.org\/10.1016\/j.apsusc.2016.07.115 (2016).","journal-title":"Appl. Surf. Sci."},{"key":"87564_CR48","doi-asserted-by":"publisher","first-page":"100710","DOI":"10.1016\/j.scp.2022.100710","volume":"27","author":"Q Wang","year":"2022","unstructured":"Wang, Q. et al. Insight into the anti\u2013corrosion performance of Artemisia argyi leaves extract as eco\u2013friendly corrosion inhibitor for carbon steel in HCl medium. Sustainable Chem. Pharm. 27, 100710. https:\/\/doi.org\/10.1016\/j.scp.2022.100710 (2022).","journal-title":"Sustainable Chem. Pharm."},{"key":"87564_CR49","doi-asserted-by":"publisher","first-page":"3579","DOI":"10.1007\/s11164-015-2233-9","volume":"42","author":"SM Tawfik","year":"2016","unstructured":"Tawfik, S. M. & Negm, N. A. Vanillin-derived non-ionic surfactants as green corrosion inhibitors for carbon steel in acidic environments. Res. Chem. Intermed. 42, 3579\u20133607. https:\/\/doi.org\/10.1007\/s11164-015-2233-9 (2016).","journal-title":"Res. Chem. Intermed"},{"key":"87564_CR50","doi-asserted-by":"publisher","first-page":"10338","DOI":"10.1016\/S1452-3981(23)16281-X","volume":"7","author":"H Zarrok","year":"2012","unstructured":"Zarrok, H. et al. Gravimetric and Electrochemical evaluation of 1-allyl-1Hindole-2,3-dione of Carbon Steel Corrosion in Hydrochloric Acid. Int. J. Electrochem. Sci. 7, 10338\u201310357. https:\/\/doi.org\/10.1016\/S1452-3981(23)16281-X (2012).","journal-title":"Int. J. Electrochem. Sci."},{"key":"87564_CR51","doi-asserted-by":"publisher","first-page":"470","DOI":"10.1016\/j.molliq.2017.12.087","volume":"251","author":"A Biswas","year":"2018","unstructured":"Biswas, A., Mourya, P., Mondal, D., Pal, S. & Udayabhanu, G. Grafting effect of gum acacia on mild steel corrosion in acidic medium: Gravimetric and electrochemical study. J. Mol. Liq. 251, 470\u2013479. https:\/\/doi.org\/10.1016\/j.molliq.2017.12.087 (2018).","journal-title":"J. Mol. Liq"},{"key":"87564_CR52","doi-asserted-by":"publisher","first-page":"544","DOI":"10.1016\/j.corsci.2014.10.047","volume":"90","author":"R Y\u0131ld\u0131z","year":"2015","unstructured":"Y\u0131ld\u0131z, R. An electrochemical and theoretical evaluation of 4, 6-diamino-2-pyrimidinethiol as a corrosion inhibitor for mild steel in HCl solutions. Corros. Sci. 90, 544\u2013553. https:\/\/doi.org\/10.1016\/j.corsci.2014.10.047 (2015).","journal-title":"Corros. Sci."},{"key":"87564_CR53","doi-asserted-by":"publisher","first-page":"209","DOI":"10.1016\/j.molliq.2015.09.009","volume":"212","author":"C Verma","year":"2015","unstructured":"Verma, C., Ebenso, E., Bahadur, I., Obot, I. & Quraishi, M. 5-(Phenylthio)-3H-pyrrole-4-carbonitriles as effective corrosion inhibitors for mild steel in 1\u00a0M HCl: experimental and theoretical investigation. J. Mol. Liq. 212, 209\u2013218. https:\/\/doi.org\/10.1016\/j.molliq.2015.09.009 (2015).","journal-title":"J. Mol. Liq"},{"key":"87564_CR54","doi-asserted-by":"publisher","first-page":"109801","DOI":"10.1016\/j.inoche.2022.109801","volume":"143","author":"HE Hassouni","year":"2022","unstructured":"Hassouni, H. E. et al. Corrosion inhibition, surface adsorption and computational studies of new sustainable and green inhibitor for mild steel in acidic medium. Inorg. Chem. 143, 109801. https:\/\/doi.org\/10.1016\/j.inoche.2022.109801 (2022).","journal-title":"Inorg. Chem."},{"key":"87564_CR55","doi-asserted-by":"publisher","first-page":"102439","DOI":"10.1016\/j.mtcomm.2021.102439","volume":"27","author":"A Mohanty","year":"2021","unstructured":"Mohanty, A., Kumar, S. & Tiwari, S. Assessment of N-(4H-1, 2, 4-triazol-4-yl) octanamide as hydrochloric acid corrosion inhibitor for mild steel. Mater. Today Commun. 27, 102439. https:\/\/doi.org\/10.1016\/j.mtcomm.2021.102439 (2021).","journal-title":"Mater. Today Commun."},{"key":"87564_CR56","doi-asserted-by":"publisher","first-page":"129","DOI":"10.1016\/j.aej.2012.11.001","volume":"52","author":"AS Yaro","year":"2013","unstructured":"Yaro, A. S., Khadom, A. A. & Wael, R. K. Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid. Alexandria Eng. J. 52, 129\u2013135. https:\/\/doi.org\/10.1016\/j.aej.2012.11.001 (2013).","journal-title":"Alexandria Eng. J."},{"issue":"6","key":"87564_CR57","first-page":"20","volume":"6","author":"H Tayebi","year":"2014","unstructured":"Tayebi, H. et al. An electrochemical and theoretical evaluation of new quinoline derivative as a corrosion inhibitor for carbon steel in HCl solutions. Der Pharmacia Lett. 6(6), 20\u201334 (2014).","journal-title":"Der Pharmacia Lett."},{"key":"87564_CR58","doi-asserted-by":"publisher","first-page":"116520","DOI":"10.1016\/j.molliq.2021.116520","volume":"334","author":"M Oubaaqa","year":"2021","unstructured":"Oubaaqa, M. et al. Insight into the corrosion inhibition of new amino-acids as efficient inhibitors for mild steel in HCl solution: experimental studies and theoretical calculations. J. Mol. Liq. 334, 116520. https:\/\/doi.org\/10.1016\/j.molliq.2021.116520 (2021).","journal-title":"J. Mol. Liq"},{"key":"87564_CR59","doi-asserted-by":"publisher","first-page":"788","DOI":"10.1016\/j.molliq.2019.03.126","volume":"283","author":"A Singh","year":"2019","unstructured":"Singh, A. et al. Solvent-free microwave assisted synthesis and corrosion inhibition study of a series of hydrazones derived from thiophene derivatives: experimental, surface and theoretical study. J. Mol. Liq. 283, 788\u2013803. https:\/\/doi.org\/10.1016\/j.molliq.2019.03.126 (2019).","journal-title":"J. Mol. Liq"},{"key":"87564_CR60","doi-asserted-by":"publisher","first-page":"2752","DOI":"10.1016\/j.corsci.2009.07.011","volume":"51","author":"AK Singh","year":"2009","unstructured":"Singh, A. K. & Quraishi, M. Effect of 2, 2\u2032 benzothiazolyl disulfide on the corrosion of mild steel in acid media. Corros. Sci. 51, 2752\u20132760. https:\/\/doi.org\/10.1016\/j.corsci.2009.07.011 (2009).","journal-title":"Corros. Sci."},{"key":"87564_CR61","doi-asserted-by":"publisher","first-page":"7529","DOI":"10.1021\/acs.joc.7b01225","volume":"82","author":"MA Mostafa","year":"2017","unstructured":"Mostafa, M. A., Bowley, R. M., Racys, D. T., Henry, M. C. & Sutherland, A. Iron (III)-catalyzed chlorination of activated arenes. J. Inorg. Chem. 82, 7529\u20137537. https:\/\/doi.org\/10.1021\/acs.joc.7b01225 (2017).","journal-title":"J. Inorg. Chem."},{"key":"87564_CR62","doi-asserted-by":"publisher","first-page":"113493","DOI":"10.1016\/j.molliq.2020.113493","volume":"313","author":"A Berrissoul","year":"2020","unstructured":"Berrissoul, A. et al. Evaluation of Lavandula Mairei extract as green inhibitor for mild steel corrosion in 1\u00a0M HCl solution. Experimental and theoretical approach. J. Mol. Liq. 313, 113493. https:\/\/doi.org\/10.1016\/j.molliq.2020.113493 (2020).","journal-title":"J. Mol. Liq"},{"key":"87564_CR63","doi-asserted-by":"publisher","first-page":"115553","DOI":"10.1016\/j.molliq.2021.115553","volume":"329","author":"FH Zaidon","year":"2021","unstructured":"Zaidon, F. H., Kassim, K., Zaki, H. M., Embong, Z. & Hashim, N. Z. N. Adsorption and corrosion inhibition accomplishment for thiosemicarbazone derivatives for mild steel in 1.0\u00a0M HCl medium: electrochemical, XPS and DFT studies. J. Mol. Liq. 329, 115553. https:\/\/doi.org\/10.1016\/j.molliq.2021.115553 (2021).","journal-title":"J. Mol. Liq"},{"key":"87564_CR64","doi-asserted-by":"publisher","first-page":"861","DOI":"10.1016\/j.apsusc.2019.01.149","volume":"476","author":"NZN Hashim","year":"2019","unstructured":"Hashim, N. Z. N., Kassim, K., Zaki, H. M., Alharthi, A. I. & Embong, Z. XPS and DFT investigations of corrosion inhibition of substituted benzylidene Schiff bases on mild steel in hydrochloric acid. Appl. Surf. Sci. 476, 861\u2013877. https:\/\/doi.org\/10.1016\/j.apsusc.2019.01.149 (2019).","journal-title":"Appl. Surf. Sci."},{"key":"87564_CR65","doi-asserted-by":"publisher","first-page":"243","DOI":"10.1016\/j.corsci.2012.07.018","volume":"64","author":"H Zarrok","year":"2012","unstructured":"Zarrok, H. et al. Corrosion control of carbon steel in phosphoric acid by purpald\u2013weight loss, electrochemical and XPS studies. Corros. Sci. 64, 243\u2013252. https:\/\/doi.org\/10.1016\/j.corsci.2012.07.018 (2012).","journal-title":"Corros. Sci."},{"key":"87564_CR66","doi-asserted-by":"publisher","first-page":"1628","DOI":"10.1016\/j.corsci.2009.04.009","volume":"51","author":"F Bentiss","year":"2009","unstructured":"Bentiss, F. et al. Corrosion control of mild steel using 3, 5-bis (4-methoxyphenyl)-4-amino-1, 2, 4-triazole in normal hydrochloric acid medium. Corros. Sci. 51, 1628\u20131635. https:\/\/doi.org\/10.1016\/j.corsci.2009.04.009 (2009).","journal-title":"Corros. Sci."},{"key":"87564_CR67","doi-asserted-by":"publisher","first-page":"119470","DOI":"10.1016\/j.molliq.2022.119470","volume":"360","author":"M Abouchane","year":"2022","unstructured":"Abouchane, M. et al. Insight into the corrosion inhibition performance of two quinoline-3-carboxylate derivatives as highly efficient inhibitors for mild steel in acidic medium: experimental and theoretical evaluations. J. Mol. Liq. 360, 119470. https:\/\/doi.org\/10.1016\/j.molliq.2022.119470 (2022).","journal-title":"J. Mol. Liq"},{"key":"87564_CR68","doi-asserted-by":"publisher","first-page":"114549","DOI":"10.1016\/j.molliq.2020.114549","volume":"322","author":"M Rbaa","year":"2021","unstructured":"Rbaa, M. et al. Green synthesis of novel carbohydrate polymer chitosan oligosaccharide grafted on d-glucose derivative as bio-based corrosion inhibitor. J. Mol. Liq. 322, 114549. https:\/\/doi.org\/10.1016\/j.molliq.2020.114549 (2021).","journal-title":"J. Mol. Liq"},{"key":"87564_CR69","doi-asserted-by":"publisher","first-page":"125465","DOI":"10.1016\/j.colsurfa.2020.125465","volume":"607","author":"A Singh","year":"2020","unstructured":"Singh, A., Ansari, K. & Quraishi, M. Chondroitin sulfate as a green corrosion inhibitor for zinc in 26% ammonium chloride solution: Electrochemical and surface morphological analysis. Colloids Surf. 607, 125465. https:\/\/doi.org\/10.1016\/j.colsurfa.2020.125465 (2020).","journal-title":"Colloids Surf."},{"key":"87564_CR70","doi-asserted-by":"publisher","first-page":"2869","DOI":"10.1039\/C1GC15148G","volume":"13","author":"C Gabler","year":"2011","unstructured":"Gabler, C. et al. Corrosion properties of ammonium based ionic liquids evaluated by SEM-EDX, XPS and ICP-OES. Green. Chem. 13, 2869\u20132877. https:\/\/doi.org\/10.1039\/C1GC15148G (2011).","journal-title":"Green. Chem."},{"key":"87564_CR71","doi-asserted-by":"publisher","first-page":"125231","DOI":"10.1016\/j.colsurfa.2020.125231","volume":"603","author":"J Saranya","year":"2020","unstructured":"Saranya, J. et al. Experimental and computational approaches on the pyran derivatives for acid corrosion. Colloids Surf. 603, 125231. https:\/\/doi.org\/10.1016\/j.colsurfa.2020.125231 (2020).","journal-title":"Colloids Surf."},{"key":"87564_CR72","unstructured":"MarvinSketch & Software Version: 18.22, ChemAxon Ltd. (2018)."},{"key":"87564_CR73","doi-asserted-by":"publisher","first-page":"130934","DOI":"10.1016\/j.molstruc.2021.130934","volume":"1244","author":"M Rbaa","year":"2021","unstructured":"Rbaa, M. et al. Synthesis, bioinformatics and biological evaluation of novel pyridine based on 8-hydroxyquinoline derivatives as antibacterial agents: DFT, molecular docking and ADME\/T studies. J. Mol. Struct. 1244, 130934. https:\/\/doi.org\/10.1016\/j.molstruc.2021.130934 (2021).","journal-title":"J. Mol. Struct."},{"key":"87564_CR74","doi-asserted-by":"publisher","first-page":"23","DOI":"10.1108\/acmm-11-2015-1594","volume":"64","author":"ME Belghiti","year":"2017","unstructured":"Belghiti, M. E. et al. Inhibition effect of E and Z conformations of 2-pyridinealdazine on mild steel corrosion in phosphoric acid. Anti-Corros Methods Mater. 64, 23\u201335. https:\/\/doi.org\/10.1108\/acmm-11-2015-1594 (2017).","journal-title":"Anti-Corros Methods Mater."},{"key":"87564_CR75","doi-asserted-by":"publisher","first-page":"2130","DOI":"10.1103\/physreva.7.2130","volume":"7","author":"JL Yarnell","year":"1973","unstructured":"Yarnell, J. L., Katz, M., Wenzel, R. G. & Koenig, S. Structure factor and radial distribution function for liquid argon at 85 K. Phys. Rev. 7, 2130. https:\/\/doi.org\/10.1103\/physreva.7.2130 (1973).","journal-title":"Phys. Rev."},{"key":"87564_CR76","doi-asserted-by":"publisher","first-page":"21","DOI":"10.1016\/j.corsci.2015.01.025","volume":"94","author":"D Daoud","year":"2015","unstructured":"Daoud, D., Douadi, T., Hamani, H., Chafaa, S. & Al-Noaimi, M. Corrosion inhibition of mild steel by two new S-heterocyclic compounds in 1\u00a0M HCl: experimental and computational study. Corros. Sci. 94, 21\u201337. https:\/\/doi.org\/10.1016\/j.corsci.2015.01.025 (2015).","journal-title":"Corros. Sci."}],"container-title":["Scientific Reports"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-87564-w.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-87564-w","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-87564-w.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T07:46:16Z","timestamp":1738136776000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41598-025-87564-w"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,29]]},"references-count":76,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2025,12]]}},"alternative-id":["87564"],"URL":"https:\/\/doi.org\/10.1038\/s41598-025-87564-w","relation":{},"ISSN":["2045-2322"],"issn-type":[{"value":"2045-2322","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,29]]},"assertion":[{"value":"11 May 2024","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"20 January 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"29 January 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Declarations"}},{"value":"The authors declare no competing interests.","order":2,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}},{"value":"Not applicable.","order":3,"name":"Ethics","group":{"name":"EthicsHeading","label":"Ethical approval"}},{"value":"Not applicable.","order":4,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent to participate"}},{"value":"Not applicable.","order":5,"name":"Ethics","group":{"name":"EthicsHeading","label":"Consent for publication"}}],"article-number":"3631"}}