{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T18:43:10Z","timestamp":1789497790628,"version":"build-2803163510"},"reference-count":47,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2022,10,8]],"date-time":"2022-10-08T00:00:00Z","timestamp":1665187200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2022,10,8]],"date-time":"2022-10-08T00:00:00Z","timestamp":1665187200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/501100004543","name":"China Scholarship Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004543","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002347","name":"Bundesministerium f\u00fcr Bildung und Forschung","doi-asserted-by":"publisher","award":["05K19WC1"],"award-info":[{"award-number":["05K19WC1"]}],"id":[{"id":"10.13039\/501100002347","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Commun Chem"],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Chemical stability of the alkali halides NaCl and KCl has allowed for their use as inert media in high-pressure high-temperature experiments. Here we demonstrate the unexpected reactivity of the halides with metals (Y, Dy, and Re) and iron oxide (FeO) in a laser-heated diamond anvil cell, thus providing a synthetic route for halogen-containing binary and ternary compounds. So far unknown chlorides, Y\n                    <jats:sub>2<\/jats:sub>\n                    Cl and DyCl, and chloride carbides, Y\n                    <jats:sub>2<\/jats:sub>\n                    ClC and Dy\n                    <jats:sub>2<\/jats:sub>\n                    ClC, were synthesized at ~40\u2009GPa and 2000 K and their structures were solved and refined using in situ single-crystal synchrotron X-ray diffraction. Also, FeCl\n                    <jats:sub>2<\/jats:sub>\n                    with the HP-PdF\n                    <jats:sub>2<\/jats:sub>\n                    -type structure, previously reported at 108\u2009GPa, was synthesized at ~160\u2009GPa and 2100\u2009K. The results of our ab initio calculations fully support experimental findings and reveal the electronic structure and chemical bonding in these compounds.\n                  <\/jats:p>","DOI":"10.1038\/s42004-022-00736-x","type":"journal-article","created":{"date-parts":[[2022,10,8]],"date-time":"2022-10-08T05:02:59Z","timestamp":1665205379000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Synthesis of rare-earth metal compounds through enhanced reactivity of alkali halides at high pressures"],"prefix":"10.1038","volume":"5","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8861-8443","authenticated-orcid":false,"given":"Yuqing","family":"Yin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fariia I.","family":"Akbar","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8652-024X","authenticated-orcid":false,"given":"Elena","family":"Bykova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4730-4197","authenticated-orcid":false,"given":"Alena","family":"Aslandukova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dominique","family":"Laniel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey","family":"Aslandukov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0248-1728","authenticated-orcid":false,"given":"Maxim","family":"Bykov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Hanfland","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4780-9520","authenticated-orcid":false,"given":"Gaston","family":"Garbarino","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhitai","family":"Jia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3717-7585","authenticated-orcid":false,"given":"Leonid","family":"Dubrovinsky","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8256-5675","authenticated-orcid":false,"given":"Natalia","family":"Dubrovinskaia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2022,10,8]]},"reference":[{"key":"736_CR1","doi-asserted-by":"publisher","first-page":"431","DOI":"10.1080\/08957950701659700","volume":"27","author":"PI Dorogokupets","year":"2007","unstructured":"Dorogokupets, P. I. & Dewaele, A. Equations of state of MgO, au, pt, NaCl-B1, and NaCl-B2: Internally consistent high-temperature pressure scales. High. Press. Res. 27, 431\u2013446 (2007).","journal-title":"High. Press. Res."},{"key":"736_CR2","doi-asserted-by":"publisher","first-page":"157","DOI":"10.1063\/1.1713864","volume":"36","author":"DL Decker","year":"1965","unstructured":"Decker, D. L. Equation of state of NaCl and its use as a pressure gauge in high\u2010pressure research. J. Appl. Phys. 36, 157\u2013161 (1965).","journal-title":"J. Appl. Phys."},{"key":"736_CR3","doi-asserted-by":"publisher","first-page":"10479","DOI":"10.1088\/0953-8984\/14\/44\/318","volume":"14","author":"JZ Hu","year":"2002","unstructured":"Hu, J. Z. et al. X-ray diffraction and laser heating: application of a moissanite anvil cell. J. Phys. -Condens. Matter 14, 10479\u201310481 (2002).","journal-title":"J. Phys. -Condens. Matter"},{"key":"736_CR4","doi-asserted-by":"publisher","first-page":"n\/a","DOI":"10.1029\/2011GL046949","volume":"38","author":"M Armentrout","year":"2011","unstructured":"Armentrout, M. & Kavner, A. High pressure, high temperature equation of state for Fe2SiO4ringwoodite and implications for the Earth\u2019s transition zone. Geophys. Res. Lett. 38, n\/a\u2013n\/a (2011).","journal-title":"Geophys. Res. Lett."},{"key":"736_CR5","doi-asserted-by":"publisher","first-page":"15724","DOI":"10.1021\/acs.jpcc.9b02915","volume":"123","author":"B Langerome","year":"2019","unstructured":"Langerome, B. et al. Probing NaCl at high pressure through optical studies and Ab initio calculations. J. Phys. Chem. C 123, 15724\u201315728 (2019).","journal-title":"J. Phys. Chem. C"},{"key":"736_CR6","doi-asserted-by":"publisher","first-page":"12958","DOI":"10.1039\/C7CC08290H","volume":"53","author":"FA Redeker","year":"2017","unstructured":"Redeker, F. A., Beckers, H. & Riedel, S. Matrix-isolation and comparative far-IR investigation of free linear [Cl3](-) and a series of alkali trichlorides. Chem. Commun. (Camb.) 53, 12958\u201312961 (2017).","journal-title":"Chem. Commun. (Camb.)"},{"key":"736_CR7","doi-asserted-by":"publisher","DOI":"10.1038\/srep26265","volume":"6","author":"W Zhang","year":"2016","unstructured":"Zhang, W. et al. Stability of numerous novel potassium chlorides at high pressure. Sci. Rep. 6, 26265 (2016).","journal-title":"Sci. Rep."},{"key":"736_CR8","doi-asserted-by":"publisher","first-page":"1502","DOI":"10.1126\/science.1244989","volume":"342","author":"W Zhang","year":"2013","unstructured":"Zhang, W. et al. Unexpected stable stoichiometries of sodium chlorides. Science 342, 1502\u20131505 (2013).","journal-title":"Science"},{"key":"736_CR9","doi-asserted-by":"publisher","first-page":"313","DOI":"10.2138\/am-2022-8283","volume":"107","author":"HS Yuan","year":"2022","unstructured":"Yuan, H. S. et al. HP-PdF2-type FeCl2 as a potential Cl-carrier in the deep Earth. Am. Mineral. 107, 313\u2013317 (2022).","journal-title":"Am. Mineral."},{"key":"736_CR10","doi-asserted-by":"publisher","unstructured":"Koemets, E. et al. Interaction Between FeOOH and NaCl at Extreme Conditions: Synthesis of Novel Na2FeCl4OHx Compound. Minerals https:\/\/doi.org\/10.3390\/min10010051 (2020).","DOI":"10.3390\/min10010051"},{"key":"736_CR11","doi-asserted-by":"publisher","first-page":"125102","DOI":"10.1063\/1.4768541","volume":"83","author":"I Kantor","year":"2012","unstructured":"Kantor, I. et al. BX90: a new diamond anvil cell design for X-ray diffraction and optical measurements. Rev. Sci. Instrum. 83, 125102 (2012).","journal-title":"Rev. Sci. Instrum."},{"key":"736_CR12","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-12530-w","volume":"10","author":"D Laniel","year":"2019","unstructured":"Laniel, D. et al. Synthesis of magnesium-nitrogen salts of polynitrogen anions. Nat. Commun. 10, 4515 (2019).","journal-title":"Nat. Commun."},{"key":"736_CR13","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07265-z","volume":"9","author":"E Bykova","year":"2018","unstructured":"Bykova, E. et al. Metastable silica high pressure polymorphs as structural proxies of deep Earth silicate melts. Nat. Commun. 9, 4789 (2018).","journal-title":"Nat. Commun."},{"key":"736_CR14","doi-asserted-by":"publisher","first-page":"175501","DOI":"10.1103\/PhysRevLett.126.175501","volume":"126","author":"M Bykov","year":"2021","unstructured":"Bykov, M. et al. High-pressure synthesis of dirac materials: layered van der waals bonded BeN_{4} polymorph. Phys. Rev. Lett. 126, 175501 (2021).","journal-title":"Phys. Rev. Lett."},{"key":"736_CR15","doi-asserted-by":"publisher","first-page":"9003","DOI":"10.1002\/anie.202100283","volume":"60","author":"M Bykov","year":"2021","unstructured":"Bykov, M. et al. Stabilization of polynitrogen anions in tantalum-nitrogen compounds at high pressure. Angew. Chem. Int. Ed. Engl. 60, 9003\u20139008 (2021).","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"736_CR16","doi-asserted-by":"publisher","first-page":"9048","DOI":"10.1002\/anie.201805152","volume":"57","author":"M Bykov","year":"2018","unstructured":"Bykov, M. et al. High-pressure synthesis of a nitrogen-rich inclusion compound ReN8 x N2 with conjugated polymeric nitrogen chains. Angew. Chem. Int. Ed. Engl. 57, 9048\u20139053 (2018).","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"736_CR17","doi-asserted-by":"publisher","first-page":"1383","DOI":"10.1107\/S1600576722008081","volume":"55","author":"A Aslandukov","year":"2022","unstructured":"Aslandukov, A., Aslandukov, M., Dubrovinskaia, N. & Dubrovinsky, L. Domain Auto Finder (DAFi) program: the analysis of single-crystal X-ray diffraction data from polycrystalline samples. J. Appl. Crystallogr. 55, 1383\u20131391 (2022).","journal-title":"J. Appl. Crystallogr"},{"key":"736_CR18","doi-asserted-by":"publisher","unstructured":"Aliakbari, A. & Amiri, P. Structural, elastic, electronic, thermal, and phononic properties of yttrium carbide: first-principles calculations. Mater. Chem. Phys. https:\/\/doi.org\/10.1016\/j.matchemphys.2021.124744 (2021).","DOI":"10.1016\/j.matchemphys.2021.124744"},{"key":"736_CR19","doi-asserted-by":"publisher","first-page":"4120","DOI":"10.1021\/ic00218a030","volume":"24","author":"JE Ford","year":"2002","unstructured":"Ford, J. E. & Corbett, J. D. Alkali-metal intercalates of layered yttrium chloride oxide and their hydration reactions. Inorg. Chem. 24, 4120\u20134128 (2002).","journal-title":"Inorg. Chem."},{"key":"736_CR20","doi-asserted-by":"publisher","first-page":"2094","DOI":"10.1021\/ic00182a022","volume":"23","author":"JE Ford","year":"2002","unstructured":"Ford, J. E., Meyer, G. & Corbett, J. D. Lithium intercalation compounds of yttrium and gadolinium monochloride: synthesis and structure. Inorg. Chem. 23, 2094\u20132098 (2002).","journal-title":"Inorg. Chem."},{"key":"736_CR21","doi-asserted-by":"publisher","first-page":"2128","DOI":"10.1021\/ic50209a057","volume":"19","author":"H Mattausch","year":"2002","unstructured":"Mattausch, H., Hendricks, J. B., Eger, R., Corbett, J. D. & Simon, A. Reduced halides of yttrium with strong metal-metal bonding: yttrium monochloride, monobromide, sesquichloride, and sesquibromide. Inorg. Chem. 19, 2128\u20132132 (2002).","journal-title":"Inorg. Chem."},{"key":"736_CR22","doi-asserted-by":"publisher","first-page":"940","DOI":"10.1021\/j150521a002","volume":"58","author":"DH Templeton","year":"2002","unstructured":"Templeton, D. H. & Carter, G. F. The crystal structures of yttrium trichloride and similar compounds. J. Phys. Chem. 58, 940\u2013944 (2002).","journal-title":"J. Phys. Chem."},{"key":"736_CR23","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1038\/s41524-018-0136-1","volume":"4","author":"B Wan","year":"2018","unstructured":"Wan, B. et al. Identifying quasi-2D and 1D electrides in yttrium and scandium chlorides via geometrical identification. Npj Comput. Mater. 4, 77 (2018).","journal-title":"Npj Comput. Mater."},{"key":"736_CR24","unstructured":"Pearson, W. B. The Crystal Chemistry and Physics of Metals and Alloys. Vol. 135 (Wiley-Inter-science, 1972)."},{"key":"736_CR25","doi-asserted-by":"publisher","first-page":"215401","DOI":"10.1088\/1361-648X\/abe607","volume":"33","author":"H Yu","year":"2021","unstructured":"Yu, H. & Chen, Y. Pressure-induced electrides and metallic phases in the Y-Cl system. J. Phys.-Condens Matter 33, 215401 (2021).","journal-title":"J. Phys.-Condens Matter"},{"key":"736_CR26","doi-asserted-by":"publisher","first-page":"094104","DOI":"10.1103\/PhysRevB.102.094104","volume":"102","author":"EJ Pace","year":"2020","unstructured":"Pace, E. J. et al. Structural phase transitions in yttrium up to 183 GPa. Phys. Rev. B 102, 094104 (2020).","journal-title":"Phys. Rev. B"},{"key":"736_CR27","doi-asserted-by":"publisher","first-page":"624","DOI":"10.1002\/anie.197606242","volume":"15","author":"A Simon","year":"1976","unstructured":"Simon, A., Mattausch, H. & Holzer, N. Monochlorides of the Lanthanoids: GdCl and TbCl. Angew. Chem. Int. Ed. 15, 624\u2013625 (1976).","journal-title":"Angew. Chem. Int. Ed."},{"key":"736_CR28","doi-asserted-by":"publisher","first-page":"3082","DOI":"10.1021\/ic50223a064","volume":"20","author":"RE Araujo","year":"2002","unstructured":"Araujo, R. E. & Corbett, J. D. Lanthanum monochloride and lanthanum sesquichloride. Inorg. Chem. 20, 3082\u20133086 (2002).","journal-title":"Inorg. Chem."},{"key":"736_CR29","doi-asserted-by":"publisher","first-page":"645","DOI":"10.1038\/nphys3372","volume":"11","author":"C Shekhar","year":"2015","unstructured":"Shekhar, C. et al. Extremely large magnetoresistance and ultrahigh mobility in the topological Weyl semimetal candidate NbP. Nat. Phys. 11, 645 (2015).","journal-title":"Nat. Phys."},{"key":"736_CR30","doi-asserted-by":"publisher","first-page":"2987","DOI":"10.1088\/0022-3719\/9\/16\/008","volume":"9","author":"A Pasternak","year":"1976","unstructured":"Pasternak, A. Lattice dynamics of FeCl2. J. Phys. C. Solid State Phys. 9, 2987\u20132995 (1976).","journal-title":"J. Phys. C. Solid State Phys."},{"key":"736_CR31","doi-asserted-by":"publisher","unstructured":"Rozenberg, G. K. et al. Pressure-induced structural, electronic, and magnetic phase transitions inFeCl2studied by x-ray diffraction and resistivity measurements. Phys. Rev. B https:\/\/doi.org\/10.1103\/PhysRevB.79.214105 (2009).","DOI":"10.1103\/PhysRevB.79.214105"},{"key":"736_CR32","doi-asserted-by":"publisher","first-page":"2186","DOI":"10.1002\/ejic.202000252","volume":"2020","author":"S Khandarkhaeva","year":"2020","unstructured":"Khandarkhaeva, S. et al. Novel rhenium carbides at 200 GPa. Eur. J. Inorg. Chem. 2020, 2186\u20132190 (2020).","journal-title":"Eur. J. Inorg. Chem."},{"key":"736_CR33","doi-asserted-by":"publisher","first-page":"134106","DOI":"10.1103\/PhysRevB.78.134106","volume":"78","author":"A Togo","year":"2008","unstructured":"Togo, A., Oba, F. & Tanaka, I. First-principles calculations of the ferroelastic transition between rutile-type and CaCl2-type SiO2 at high pressures. Phys. Rev. B 78, 134106 (2008).","journal-title":"Phys. Rev. B"},{"key":"736_CR34","doi-asserted-by":"publisher","first-page":"053803","DOI":"10.1103\/PhysRevMaterials.3.053803","volume":"3","author":"D Ohmer","year":"2019","unstructured":"Ohmer, D., Qiang, G., Opahle, I., Singh, H. K. & Zhang, H. High-throughput design of 211\u2212M2AX compounds. Phys. Rev. Mater. 3, 053803 (2019).","journal-title":"Phys. Rev. Mater."},{"key":"736_CR35","doi-asserted-by":"publisher","first-page":"814","DOI":"10.1038\/nmat4896","volume":"16","author":"H Fashandi","year":"2017","unstructured":"Fashandi, H. et al. Synthesis of Ti3AuC2, Ti3Au2C2 and Ti3IrC2 by noble metal substitution reaction in Ti3SiC2 for high-temperature-stable Ohmic contacts to SiC. Nat. Mater. 16, 814\u2013818 (2017).","journal-title":"Nat. Mater."},{"key":"736_CR36","doi-asserted-by":"publisher","first-page":"210","DOI":"10.1016\/j.trechm.2019.02.016","volume":"1","author":"M Sokol","year":"2019","unstructured":"Sokol, M., Natu, V., Kota, S. & Barsoum, M. W. On the chemical diversity of the MAX phases. Trends Chem. 1, 210\u2013223 (2019).","journal-title":"Trends Chem."},{"key":"736_CR37","doi-asserted-by":"publisher","first-page":"1809","DOI":"10.1002\/anie.199718081","volume":"36","author":"A Savin","year":"1997","unstructured":"Savin, A., Nesper, R., Wengert, S. & Fassler, T. F. ELF: the electron localization function. Angew. Chem. Int. Ed. 36, 1809\u20131832 (1997).","journal-title":"Angew. Chem. Int. Ed."},{"key":"736_CR38","doi-asserted-by":"publisher","first-page":"043516","DOI":"10.1063\/1.2335683","volume":"100","author":"Y Akahama","year":"2006","unstructured":"Akahama, Y. & Kawamura, H. Pressure calibration of diamond anvil Raman gauge to 310GPa. J. Appl. Phys. 100, 043516 (2006).","journal-title":"J. Appl. Phys."},{"key":"736_CR39","doi-asserted-by":"publisher","first-page":"072201","DOI":"10.1063\/1.4926895","volume":"86","author":"Y Meng","year":"2015","unstructured":"Meng, Y., Hrubiak, R., Rod, E., Boehler, R. & Shen, G. New developments in laser-heated diamond anvil cell with in situ synchrotron x-ray diffraction at High Pressure Collaborative Access Team. Rev. Sci. Instrum. 86, 072201 (2015).","journal-title":"Rev. Sci. Instrum."},{"key":"736_CR40","unstructured":"Rigaku Oxford Diffraction Ltd. Rigaku OD and CryAlis PRO (2018)."},{"key":"736_CR41","doi-asserted-by":"publisher","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"OV Dolomanov","year":"2009","unstructured":"Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 42, 339\u2013341 (2009).","journal-title":"J. Appl. Crystallogr."},{"key":"736_CR42","doi-asserted-by":"publisher","first-page":"345","DOI":"10.1515\/zkri-2014-1737","volume":"229","author":"V Pet\u0159\u00ed\u010dek","year":"2014","unstructured":"Pet\u0159\u00ed\u010dek, V., Du\u0161ek, M. & Palatinus, L. Crystallographic computing system JANA2006: general features. Z. Kristallogr.-Cryst. Mater. 229, 345\u2013352 (2014).","journal-title":"Z. Kristallogr.-Cryst. Mater."},{"key":"736_CR43","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","volume":"6","author":"G Kresse","year":"1996","unstructured":"Kresse, G. & Furthmuller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15\u201350 (1996).","journal-title":"Comput. Mater. Sci."},{"key":"736_CR44","doi-asserted-by":"publisher","first-page":"17953","DOI":"10.1103\/PhysRevB.50.17953","volume":"50","author":"PE Blochl","year":"1994","unstructured":"Blochl, P. E. Projector augmented-wave method. Phys. Rev. B Condens. Matter 50, 17953\u201317979 (1994).","journal-title":"Phys. Rev. B Condens. Matter"},{"key":"736_CR45","doi-asserted-by":"publisher","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","volume":"59","author":"G Kresse","year":"1999","unstructured":"Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59, 1758\u20131775 (1999).","journal-title":"Phys. Rev. B"},{"key":"736_CR46","doi-asserted-by":"publisher","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"JP Perdew","year":"1996","unstructured":"Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865\u20133868 (1996).","journal-title":"Phys. Rev. Lett."},{"key":"736_CR47","doi-asserted-by":"publisher","first-page":"653","DOI":"10.1107\/S0021889808012016","volume":"41","author":"K Momma","year":"2008","unstructured":"Momma, K. & Izumi, F. VESTA: a three-dimensional visualization system for electronic and structural analysis. J. Appl. Crystallogr. 41, 653\u2013658 (2008).","journal-title":"J. Appl. Crystallogr."}],"container-title":["Communications Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s42004-022-00736-x.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s42004-022-00736-x","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s42004-022-00736-x.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,10,8]],"date-time":"2022-10-08T17:02:25Z","timestamp":1665248545000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s42004-022-00736-x"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,10,8]]},"references-count":47,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2022,12]]}},"alternative-id":["736"],"URL":"https:\/\/doi.org\/10.1038\/s42004-022-00736-x","relation":{},"ISSN":["2399-3669"],"issn-type":[{"value":"2399-3669","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,10,8]]},"assertion":[{"value":"22 July 2022","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"19 September 2022","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"8 October 2022","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"122"}}