{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T17:56:50Z","timestamp":1778867810781,"version":"3.51.4"},"reference-count":47,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2025,4,30]],"date-time":"2025-04-30T00:00:00Z","timestamp":1745971200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2025,4,30]],"date-time":"2025-04-30T00:00:00Z","timestamp":1745971200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"funder":[{"DOI":"10.13039\/501100017516","name":"International Max Planck Research School for Chemistry and Physics of Quantum Materials","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100017516","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Commun Chem"],"abstract":"<jats:title>Abstract<\/jats:title>\n          <jats:p>The preparation of Zintl phases with pronounced spin-orbit coupling has received substantial scientific interest because of their distinctive electronic properties. In the context of superconductivity and topological phenomena related to band inversion, intermetallic compounds of bismuth have come into focus recently. While bismuth forms a rich variety of Zintl phases with the heavier alkaline-earth metals, there are significantly fewer magnesium compounds. Here we show that high-temperature high-pressure synthesis opens a convenient route for the preparation of Mg<jats:sub>5<\/jats:sub>Bi<jats:sub>3<\/jats:sub>H<jats:sub>x<\/jats:sub> already at moderate conditions. The compound (space group <jats:italic>Pnma, a<\/jats:italic>\u2009=\u200911.5399(3) \u00c5, <jats:italic>b<\/jats:italic>\u2009=\u20098.9503(2) \u00c5 and <jats:italic>c<\/jats:italic>\u2009=\u20097.8770(2) \u00c5) adopts a Ca<jats:sub>5<\/jats:sub>Sb<jats:sub>3<\/jats:sub>F crystal structure. The minute amounts of hydrogen could only be detected by thermal decomposition of the compound in combination with mass spectroscopy of the gas phase. Direct space analysis of the chemical bonding allowed for allocating the hydrogen position at a partially occupied interstitial site and reveals strongly polar Mg-Bi and Mg-H bonds in accordance with the Zintl concept. Calculated band structures exhibit substantial electronic reorganization upon hydrogen insertion. The combination of advanced analytical tools in concert with modern quantum chemical techniques provides an efficient approach to allocate trace amounts of interstitial atoms stabilizing intermetallic phases.<\/jats:p>","DOI":"10.1038\/s42004-025-01530-1","type":"journal-article","created":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T05:03:55Z","timestamp":1746075835000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Locating hydrogen in the Mg5Bi3Hx Zintl phase"],"prefix":"10.1038","volume":"8","author":[{"given":"Teuta","family":"Neziraj","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lev","family":"Akselrud","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marcus","family":"Schmidt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ulrich","family":"Burkhardt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuri","family":"Grin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7301-8629","authenticated-orcid":false,"given":"Ulrich","family":"Schwarz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2025,4,30]]},"reference":[{"key":"1530_CR1","first-page":"121","volume":"6","author":"NN Zhuravlev","year":"1961","unstructured":"Zhuravlev, N. N. & Melik Adamyan, V. R. Study of the crystal structure of the superconducting compounds SrBi3 and BaBi3. Sov. Phys. Crystallogr.6, 121\u2013124 (1961).","journal-title":"Sov. Phys. Crystallogr."},{"key":"1530_CR2","doi-asserted-by":"publisher","first-page":"10089","DOI":"10.1038\/srep10089","volume":"5","author":"A Iyo","year":"2015","unstructured":"Iyo, A. et al. Large enhancement of superconducting transition temperature of SrBi3 induced by Na substitution for. Sr. Sci. Rep. 5, 10089 (2015).","journal-title":"Sr. Sci. Rep."},{"key":"1530_CR3","doi-asserted-by":"publisher","first-page":"21737","DOI":"10.1039\/C6CP02856J","volume":"18","author":"MJ Winiarski","year":"2016","unstructured":"Winiarski, M. J. et al. Superconductivity in CaBi2. Phys. Chem. Chem. Phys. 18, 21737\u201321745 (2016).","journal-title":"Phys. Chem. Chem. Phys."},{"key":"1530_CR4","doi-asserted-by":"publisher","first-page":"438","DOI":"10.1038\/nphys1270","volume":"5","author":"H Zhang","year":"2009","unstructured":"Zhang, H. et al. Topological insulators in Bi2Se3, Bi2Te3 and Sb2Te3 with a single Dirac cone on the surface. Nat. Phys. 5, 438\u2013442 (2009).","journal-title":"Nat. Phys."},{"key":"1530_CR5","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.82.241306","volume":"82","author":"Z Ren","year":"2010","unstructured":"Ren, Z., Taskin, A. A., Sasaki, S., Segawa, K. & Ando, Y. Large bulk resistivity and surface quantum oscillations in the topological insulator Bi2Te2Se. Phys. Rev. B 82, 241306 (2010).","journal-title":"Phys. Rev. B"},{"key":"1530_CR6","doi-asserted-by":"publisher","first-page":"864","DOI":"10.1126\/science.1245085","volume":"343","author":"ZK Liu","year":"2014","unstructured":"Liu, Z. K. et al. Discovery of a three-dimensional topological Dirac semimetal, Na3Bi. Science 343, 864\u2013867 (2014).","journal-title":"Science"},{"key":"1530_CR7","doi-asserted-by":"publisher","first-page":"113","DOI":"10.1002\/zaac.19332110113","volume":"211","author":"E Zintl","year":"1933","unstructured":"Zintl, E. & Kaiser, H. \u00dcber die F\u00e4higkeit der Elemente zur Bildung negativer Ionen. Z. Anorg. Allg. Chem. 211, 113\u2013131 (1933).","journal-title":"Z. Anorg. Allg. Chem."},{"key":"1530_CR8","doi-asserted-by":"publisher","first-page":"138","DOI":"10.1515\/zpch-1933-2112","volume":"B 21","author":"E Zintl","year":"1933","unstructured":"Zintl, E. & Husemann, E. Bindungsart und Gitterbau bin\u00e4rer Magnesiumverbindungen. Z. Physikal. Ch. B 21, 138\u2013155 (1933).","journal-title":"Z. Physikal. Ch."},{"key":"1530_CR9","doi-asserted-by":"publisher","first-page":"693","DOI":"10.1002\/anie.197306941","volume":"12","author":"H Sch\u00e4fer","year":"1973","unstructured":"Sch\u00e4fer, H., Eisenmann, B. & M\u00fcller, W. Zintl phases: transitions between metallic and ionic bonding. Angew. Chem. Int. Ed. 12, 693\u2013712 (1973).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR10","first-page":"L467","volume":"6","author":"AC Barnes","year":"1994","unstructured":"Barnes, A. C., Guo, C. & Howells, W. S. Fast-ion conduction and the structure of \u03b2-Mg3Bi2. J. Phys.: Condens. Matter 6, L467\u2013L471 (1994).","journal-title":"J. Phys.: Condens. Matter"},{"key":"1530_CR11","doi-asserted-by":"publisher","first-page":"9853","DOI":"10.1002\/anie.201302397","volume":"52","author":"U Schwarz","year":"2013","unstructured":"Schwarz, U. et al. CoBi3: a binary cobalt\u2013bismuth compound and superconductor. Angew. Chem. Int. Ed. 52, 9853\u20139857 (2013).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR12","doi-asserted-by":"publisher","first-page":"3083","DOI":"10.1021\/acs.chemmater.9b00385","volume":"31","author":"JPS Walsh","year":"2019","unstructured":"Walsh, J. P. S. et al. MnBi2: a metastable high-pressure phase in the Mn\u2212Bi system. Chem. Mater. 31, 3083\u20133088 (2019).","journal-title":"Chem. Mater."},{"key":"1530_CR13","doi-asserted-by":"publisher","first-page":"867","DOI":"10.1021\/acscentsci.6b00287","volume":"2","author":"JPS Walsh","year":"2016","unstructured":"Walsh, J. P. S., Clarke, S. M., Meng, Y., Jacobsen, S. D. & Freedman, D. E. Discovery of FeBi2. ACS Cent. Sci. 2, 867\u2013871 (2016).","journal-title":"ACS Cent. Sci."},{"key":"1530_CR14","doi-asserted-by":"publisher","first-page":"13446","DOI":"10.1002\/anie.201605902","volume":"55","author":"SM Clarke","year":"2016","unstructured":"Clarke, S. M. et al. Discovery of a superconducting Cu\u2013Bi intermetallic compound by high-pressure synthesis. Angew. Chem. Int. Ed. 55, 13446\u201313449 (2016).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR15","doi-asserted-by":"publisher","first-page":"5620","DOI":"10.1002\/anie.201700712","volume":"56","author":"K Guo","year":"2017","unstructured":"Guo, K. et al. Weak interactions under pressure: hp-CuBi and its analogues. Angew. Chem. Int. Ed. 56, 5620\u20135624 (2017).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR16","doi-asserted-by":"publisher","first-page":"11241","DOI":"10.1039\/C7CC06471C","volume":"53","author":"KM Powderly","year":"2017","unstructured":"Powderly, K. M. et al. High-pressure discovery of \u03b2-NiBi. Chem. Commun. 53, 11241\u201311244 (2017).","journal-title":"Chem. Commun."},{"key":"1530_CR17","doi-asserted-by":"publisher","first-page":"214","DOI":"10.1021\/jacs.0c09419","volume":"143","author":"AB Altman","year":"2021","unstructured":"Altman, A. B. et al. Computationally directed discovery of MoBi2. J. Am. Chem. Soc. 143, 214\u2013222 (2021).","journal-title":"J. Am. Chem. Soc."},{"key":"1530_CR18","doi-asserted-by":"publisher","first-page":"59","DOI":"10.1016\/S0925-8388(02)01215-X","volume":"356\u2013357","author":"JD Corbett","year":"2003","unstructured":"Corbett, J. D. & Leon-Escamilla, E.-A. Role of hydrogen in stabilizing new hydride phases or altering old ones. J. Alloy. Compd. 356\u2013357, 59\u201364 (2003).","journal-title":"J. Alloy. Compd."},{"key":"1530_CR19","doi-asserted-by":"publisher","first-page":"311","DOI":"10.1021\/cm00003a008","volume":"1","author":"W-M Hurng","year":"1989","unstructured":"Hurng, W.-M. & Corbett, J. D. Alkaline-earth-metal antimonides and bismuthides with the A5Pn3 stoichiometry. Interstitial and other Zintl phases formed on their reactions with halogen or sulfur. Chem. Mater. 1, 311\u2013319 (1989).","journal-title":"Chem. Mater."},{"key":"1530_CR20","first-page":"143","volume":"40","author":"G Grube","year":"1934","unstructured":"Grube, G., Mohr, L. & Bornhak, R. Elektrische Leitf\u00e4higkeit und Zustandsdiagramm bei bin\u00e4ren Legierungen. Das System Magnesium-Wismut. Z. Elektrochem. 40, 143\u2013150 (1934).","journal-title":"Z. Elektrochem."},{"key":"1530_CR21","doi-asserted-by":"publisher","first-page":"239","DOI":"10.1515\/zpch-1962-21925","volume":"219","author":"M Wobst","year":"1962","unstructured":"Wobst, M. Das tern\u00e4re system Magnesium-Bismut-Zinn. Z. Phys. Chem. 219, 239\u2013265 (1962).","journal-title":"Z. Phys. Chem."},{"key":"1530_CR22","doi-asserted-by":"publisher","first-page":"181","DOI":"10.1016\/0364-5916(92)90006-J","volume":"16","author":"C-S Oh","year":"1992","unstructured":"Oh, C.-S., Kang, S.-Y. & Lee, D. N. Assessment of the Mg-Bi system. Calphad 16, 181\u2013191 (1992).","journal-title":"Calphad"},{"key":"1530_CR23","unstructured":"Parth\u00e9, E. Elements of Inorganic Structural Chemistry Vol. 38 (Petit-Lancy, Switzerland, 1996)."},{"key":"1530_CR24","doi-asserted-by":"publisher","first-page":"2808","DOI":"10.1107\/S0567740873007570","volume":"29","author":"E Parth\u00e9","year":"1973","unstructured":"Parth\u00e9, E. Valence-electron concentration rules and diagrams for diamagnetic, non-metallic iono-covalent compounds with tetrahedrally coordinated anions. Acta Crystallogr. B 29, 2808\u20132815 (1973).","journal-title":"Acta Crystallogr. B"},{"key":"1530_CR25","doi-asserted-by":"publisher","first-page":"378","DOI":"10.1021\/ic00105a057","volume":"34","author":"J-T Zhao","year":"1995","unstructured":"Zhao, J.-T. & Corbett, J. Square pyramidal clusters in La3ln5 and Y3In5. La3In5 as a metallic Zintl phase. Inorg. Chem. 34, 378\u2013383 (1995).","journal-title":"Inorg. Chem."},{"key":"1530_CR26","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/0079-6786(90)90006-2","volume":"20","author":"R Nesper","year":"1990","unstructured":"Nesper, R. Structure and chemical bonding in Zintl-phases containing lithium. Prog. Solid St. Chem. 20, 1\u201345 (1990).","journal-title":"Prog. Solid St. Chem."},{"key":"1530_CR27","doi-asserted-by":"publisher","first-page":"789","DOI":"10.1002\/anie.199107891","volume":"30","author":"R Nesper","year":"1991","unstructured":"Nesper, R. Bonding patterns in intermetallic compounds. Angew. Chem. Int. Ed. 30, 789\u2013817 (1991).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR28","doi-asserted-by":"publisher","first-page":"6457","DOI":"10.1002\/anie.202014284","volume":"60","author":"R Freccero","year":"2021","unstructured":"Freccero, R. et al. Excess\u201d electrons in LuGe. Angew. Chem. Int. Ed. 60, 6457\u20136461 (2021).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR29","doi-asserted-by":"publisher","first-page":"527","DOI":"10.1524\/zkri.2007.222.10.527","volume":"222","author":"A Baranov","year":"2007","unstructured":"Baranov, A., Kohout, M., Wagner, F. R., Grin, Y. & Bronger, W. Spatial chemistry of the aluminum-platinum compounds: a quantum chemical approach. Z. Kristallogr. 222, 527\u2013531 (2007).","journal-title":"Z. Kristallogr."},{"key":"1530_CR30","doi-asserted-by":"publisher","first-page":"99","DOI":"10.3390\/cryst8020099","volume":"8","author":"A Yu. Grin","year":"2018","unstructured":"Yu. Grin, A., Fedorchuk, R. J. & Wagner, F. R. Atomic charges and chemical bonding in Y-Ga compounds. Crystals 8, 99 (2018).","journal-title":"Crystals"},{"key":"1530_CR31","doi-asserted-by":"crossref","unstructured":"Agnarelli, L. et al. Charge transfer in Be-Ru compounds. Chem. Eur. J. 29, e202302301 (2023).","DOI":"10.1002\/chem.202302301"},{"key":"1530_CR32","doi-asserted-by":"publisher","first-page":"6600","DOI":"10.1002\/chem.201900510","volume":"25","author":"R Freccero","year":"2019","unstructured":"Freccero, R. et al. Polar-covalent bonding beyond the Zintl picture in intermetallic rare-earth germanides. Chem. Eur. J. 25, 6600\u20136612 (2019).","journal-title":"Chem. Eur. J."},{"key":"1530_CR33","doi-asserted-by":"publisher","first-page":"5724","DOI":"10.1002\/chem.200700013","volume":"13","author":"FR Wagner","year":"2007","unstructured":"Wagner, F. R., Bezugly, V., Kohout, M. & Grin, Y. Charge decomposition analysis of the electron localizability indicator: a bridge between the orbital and direct space representation of the chemical bond. Chem. Eur. J. 13, 5724\u20135741 (2007).","journal-title":"Chem. Eur. J."},{"key":"1530_CR34","doi-asserted-by":"publisher","first-page":"1808","DOI":"10.1002\/anie.199718081","volume":"36","author":"A Savin","year":"1997","unstructured":"Savin, A., Nesper, R., Wengert, S. & F\u00e4ssler, T. F. ELF: the electron localization function. Angew. Chem. Int. Ed. 36, 1808\u20131832 (1997).","journal-title":"Angew. Chem. Int. Ed."},{"key":"1530_CR35","doi-asserted-by":"publisher","first-page":"17523","DOI":"10.1021\/ja107436n","volume":"132","author":"DA Lang","year":"2010","unstructured":"Lang, D. A. & Zaikina, J. V. Ca2LiC3H: a new complex carbide hydride phase grown in metal flux. J. Am. Chem. Soc. 132, 17523\u201317530 (2010).","journal-title":"J. Am. Chem. Soc."},{"key":"1530_CR36","doi-asserted-by":"publisher","first-page":"192","DOI":"10.1016\/j.progsolidstchem.2008.07.001","volume":"36","author":"AF Al Alam","year":"2008","unstructured":"Al Alam, A. F. & Matar, S. F. Hydrogen insertion effects on the magnetic properties and chemical bonding within C14 Laves phases. Prog. Solid State Chem. 36, 192\u2013212 (2008).","journal-title":"Prog. Solid State Chem."},{"key":"1530_CR37","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.progsolidstchem.2010.08.003","volume":"38","author":"SF Matar","year":"2010","unstructured":"Matar, S. F. Intermetallic hydrides: a review with ab initio aspects. Prog. Solid State Chem. 38, 1\u201337 (2010).","journal-title":"Prog. Solid State Chem."},{"key":"1530_CR38","doi-asserted-by":"publisher","first-page":"14471","DOI":"10.1002\/chem.201501236","volume":"21","author":"X-J Feng","year":"2015","unstructured":"Feng, X.-J. et al. Zintl-Phase Sr3LiAs2H: crystal structure and chemical bonding analysis by the electron localizability approach. Chem. Eur. J. 21, 14471\u20131477 (2015).","journal-title":"Chem. Eur. J."},{"key":"1530_CR39","first-page":"1020","volume":"75","author":"D Walker","year":"1990","unstructured":"Walker, D., Carpenter, M. A. & Hitch, C. M. Some simplifications to multianvil devices for high pressure experiments. Am. Mineral. 75, 1020\u20131028 (1990).","journal-title":"Am. Mineral."},{"key":"1530_CR40","doi-asserted-by":"crossref","unstructured":"Young, D. A. Phase Diagrams of the Elements (University of California Press, Berkeley, 1991).","DOI":"10.1525\/9780520911482"},{"key":"1530_CR41","doi-asserted-by":"publisher","first-page":"803","DOI":"10.1107\/S1600576714001058","volume":"47","author":"L Akselrud","year":"2014","unstructured":"Akselrud, L. & Grin, Y. WinCSD: software package for crystallographic calculations (Version 4). J. Appl. Crystallogr. 47, 803\u2013805 (2014).","journal-title":"J. Appl. Crystallogr."},{"key":"1530_CR42","doi-asserted-by":"crossref","unstructured":"Koepernik, K. & Eschrig, H. Full-potential nonorthogonal local-orbital minimum-basis band-structure scheme. Phys. Rev. B 59, 1743\u20131757 (1999).","DOI":"10.1103\/PhysRevB.59.1743"},{"key":"1530_CR43","doi-asserted-by":"crossref","unstructured":"Perdew, J. P. & Wang, Y. Accurate and simple analytic representation of the electron-gas correlation energy. Phys. Rev. B 45, 13244\u201313249 (1992).","DOI":"10.1103\/PhysRevB.45.13244"},{"key":"1530_CR44","doi-asserted-by":"publisher","first-page":"1100","DOI":"10.1021\/jp054727r","volume":"110","author":"A Ormeci","year":"2006","unstructured":"Ormeci, A., Rosner, H., Wagner, F. R., Kohout, M. & Grin, Y. Electron Localization Function in Full-Potential Representation for Crystalline Materials. J. Phys. Chem. A 110, 1100\u20131105 (2006).","journal-title":"J. Phys. Chem. A"},{"key":"1530_CR45","unstructured":"Kohout, M. DGrid Versions 4.6\u22125.0 (Dresden, Germany, 2018\u22122021)."},{"key":"1530_CR46","doi-asserted-by":"crossref","unstructured":"Bader, R. F. W. Atoms in Molecules-A Quantum Theory 3rd edn. 222\u2013237 (Oxford University Press, New York, 1990).","DOI":"10.1093\/oso\/9780198551683.001.0001"},{"key":"1530_CR47","doi-asserted-by":"crossref","unstructured":"Wagner, F. R. & Grin, Y. Chemical bonding analysis in position space. In Comprehensive Inorganic Chemistry III (eds. Reedijk, J. & Poeppelmeier, K. R.) 222\u2013237 (Elsevier, 2023).","DOI":"10.1016\/B978-0-12-823144-9.00189-8"}],"updated-by":[{"DOI":"10.1038\/s42004-025-01616-w","type":"correction","label":"Correction","source":"publisher","updated":{"date-parts":[[2025,7,28]],"date-time":"2025-07-28T00:00:00Z","timestamp":1753660800000}}],"container-title":["Communications Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s42004-025-01530-1.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s42004-025-01530-1","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s42004-025-01530-1.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,9,6]],"date-time":"2025-09-06T13:18:12Z","timestamp":1757164692000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s42004-025-01530-1"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,30]]},"references-count":47,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2025,12]]}},"alternative-id":["1530"],"URL":"https:\/\/doi.org\/10.1038\/s42004-025-01530-1","relation":{"correction":[{"id-type":"doi","id":"10.1038\/s42004-025-01616-w","asserted-by":"object"}]},"ISSN":["2399-3669"],"issn-type":[{"value":"2399-3669","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,30]]},"assertion":[{"value":"26 November 2024","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"17 April 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"30 April 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"28 July 2025","order":4,"name":"change_date","label":"Change Date","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"Correction","order":5,"name":"change_type","label":"Change Type","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"A Correction to this paper has been published:","order":6,"name":"change_details","label":"Change Details","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"https:\/\/doi.org\/10.1038\/s42004-025-01616-w","URL":"https:\/\/doi.org\/10.1038\/s42004-025-01616-w","order":7,"name":"change_details","label":"Change Details","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"132"}}