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Fluorescent detection of H\n                    <jats:sub>2<\/jats:sub>\n                    S in living cells is very important to human health because it has been found that the abnormal levels of H\n                    <jats:sub>2<\/jats:sub>\n                    S in human body can cause Alzheimer\u2019s disease, cancers and diabetes. Herein, we develop a cyclodextrin-based metal-organic nanotube,\n                    <jats:bold>CD-MONT-2<\/jats:bold>\n                    , possessing a {Pb\n                    <jats:sub>14<\/jats:sub>\n                    } metallamacrocycle for efficient detection of H\n                    <jats:sub>2<\/jats:sub>\n                    S.\n                    <jats:bold>CD-MONT-2\u2032<\/jats:bold>\n                    (the guest-free form of\n                    <jats:bold>CD-MONT-2<\/jats:bold>\n                    ) exhibits\n                    <jats:italic>turn-on<\/jats:italic>\n                    detection of H\n                    <jats:sub>2<\/jats:sub>\n                    S with high selectivity and moderate sensitivity when the material was dissolved in DMSO solution. Significantly,\n                    <jats:bold>CD-MONT-2\u2032<\/jats:bold>\n                    can act as a fluorescent\n                    <jats:italic>turn-on<\/jats:italic>\n                    probe for highly selective detection of H\n                    <jats:sub>2<\/jats:sub>\n                    S in living cells. The sensing mechanism in the present work is based on the coordination of H\n                    <jats:sub>2<\/jats:sub>\n                    S as the auxochromic group to the central Pb(II) ion to enhance the fluorescence intensity, which is studied for the first time.\n                  <\/jats:p>","DOI":"10.1038\/srep21951","type":"journal-article","created":{"date-parts":[[2016,2,25]],"date-time":"2016-02-25T05:05:26Z","timestamp":1456376726000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Cyclodextrin-Based Metal-Organic Nanotube as Fluorescent Probe for Selective Turn-On Detection of Hydrogen Sulfide in Living Cells Based on H2S-Involved Coordination Mechanism"],"prefix":"10.1038","volume":"6","author":[{"given":"Xuelian","family":"Xin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingxin","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanfang","family":"Gong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hai","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rongming","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shijie","family":"Ji","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanxiao","family":"Dong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingguo","family":"Meng","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liangliang","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangna","family":"Dai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daofeng","family":"Sun","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2016,2,25]]},"reference":[{"key":"BFsrep21951_CR1","doi-asserted-by":"crossref","first-page":"18003","DOI":"10.1021\/ja207851s","volume":"133","author":"K Sasakura","year":"2011","unstructured":"Sasakura, K. et al. 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