{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,3]],"date-time":"2026-04-03T11:17:58Z","timestamp":1775215078675,"version":"3.50.1"},"reference-count":58,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2016,4,14]],"date-time":"2016-04-14T00:00:00Z","timestamp":1460592000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2016,4,14]],"date-time":"2016-04-14T00:00:00Z","timestamp":1460592000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Sci Rep"],"abstract":"<jats:title>Abstract<\/jats:title><jats:p>High quality cadmium-free Zn-In-S:Ag doped-nanocrystals (d-NCs) were synthesized via a simple one-step noninjection route using silver nitrate, indium acetate, zinc acetate, oleylamine, S powder and 1-dodecanethiol as starting materials in an organic phase. The size and optical properties can be effectively tailored by controlling the reaction time, reaction temperature, Ag<jats:sup>+<\/jats:sup> dopant concentration and the molar ratio of In to Zn. The photoluminescence wavelength of as-prepared Zn-In-S:Ag NCs covered a broad visible range from 458\u2009nm to 603\u2009nm. After being passivated by protective ZnS shell, the photoluminescence quantum yield (PLQY) of Zn-In-S:Ag<jats:sup>+<\/jats:sup> \/ZnS was greatly improved to 43.5%. More importantly, the initial high PLQY of the obtained core\/shell d-NCs in organic media can be preserved when being transferred into the aqueous media via ligand exchange. Finally, high quality Zn-In-S:Ag<jats:sup>+<\/jats:sup> \/ZnS d-NCs in aqueous phase were applied as bio-imaging agents for identifying living KB cells.<\/jats:p>","DOI":"10.1038\/srep24459","type":"journal-article","created":{"date-parts":[[2016,4,14]],"date-time":"2016-04-14T12:16:58Z","timestamp":1460636218000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Facile Synthesis of Cadmium-Free Zn-In-S:Ag\/ZnS Nanocrystals for Bio-Imaging"],"prefix":"10.1038","volume":"6","author":[{"given":"Tong-Tong","family":"Xuan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jia-Qing","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cai-Yan","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rong-Jun","family":"Xie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hui-Li","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2016,4,14]]},"reference":[{"key":"BFsrep24459_CR1","doi-asserted-by":"publisher","first-page":"2246","DOI":"10.1021\/cm5028964","volume":"27","author":"J van Embden","year":"2015","unstructured":"van Embden, J., Chesman, A. S. R. & Jasieniak, J. J. The heat-up synthesis of colloidal nanocrystals. Chem. Mater. 27, 2246\u20132285 (2015).","journal-title":"Chem. Mater."},{"key":"BFsrep24459_CR2","doi-asserted-by":"publisher","first-page":"5489","DOI":"10.1039\/c3cs60017c","volume":"42","author":"P Wu","year":"2013","unstructured":"Wu, P. & Yan, X.-P. Doped quantum dots for chemo\/biosensing and bioimaging. Chem. Soc. Rev. 42, 5489\u20135521 (2013).","journal-title":"Chem. Soc. Rev."},{"key":"BFsrep24459_CR3","doi-asserted-by":"publisher","first-page":"1238","DOI":"10.1016\/j.biomaterials.2011.10.070","volume":"33","author":"N Chen","year":"2012","unstructured":"Chen, N. et al. The cytotoxicity of cadmium-based quantum dots. Biomaterials 33, 1238\u20131244 (2012).","journal-title":"Biomaterials"},{"key":"BFsrep24459_CR4","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1038\/nmeth1004-73","volume":"1","author":"JK Jaiswal","year":"2004","unstructured":"Jaiswal, J. K., Goldman, E. R., Mattoussi, H. & Simon, S. M. Use of quantum dots for live cell imaging. Nat. Methods 1, 73\u201378 (2004).","journal-title":"Nat. Methods"},{"key":"BFsrep24459_CR5","doi-asserted-by":"publisher","first-page":"538","DOI":"10.1126\/science.1104274","volume":"307","author":"X Michalet","year":"2005","unstructured":"Michalet, X. et al. Quantum dots for live cells, in vivo imaging and diagnostics. Science 307, 538\u2013544 (2005).","journal-title":"Science"},{"key":"BFsrep24459_CR6","doi-asserted-by":"publisher","first-page":"9045","DOI":"10.1039\/c3cc44601h","volume":"49","author":"T Xuan","year":"2013","unstructured":"Xuan, T. et al. Single-step noninjection synthesis of highly luminescent water soluble Cu+ doped CdS quantum dots: application as bio-imaging agents. Chem. Commun. 49, 9045\u20139047 (2013).","journal-title":"Chem. Commun."},{"key":"BFsrep24459_CR7","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1016\/j.jallcom.2013.01.054","volume":"558","author":"T Xuan","year":"2013","unstructured":"Xuan, T. et al. One-step microwave-assisted synthesis of water soluble CdSe quantum dots for white light-emitting diodes with excellent color rendering. J. Alloys Comp. 558, 105\u2013108 (2013).","journal-title":"J. Alloys Comp."},{"key":"BFsrep24459_CR8","doi-asserted-by":"publisher","first-page":"7673","DOI":"10.1039\/C4RA14982C","volume":"5","author":"T-T Xuan","year":"2015","unstructured":"Xuan, T.-T. et al. Microwave synthesis of high luminescent aqueous CdSe\/CdS\/ZnS quantum dots for crystalline silicon solar cells with enhanced photovoltaic performance. RSC Adv. 5, 7673\u20137678 (2015).","journal-title":"RSC Adv."},{"key":"BFsrep24459_CR9","doi-asserted-by":"publisher","first-page":"1187","DOI":"10.1021\/cm503770w","volume":"27","author":"T-T Xuan","year":"2015","unstructured":"Xuan, T.-T., Liu, J.-Q., Xie, R.-J., Li, H.-L. & Sun, Z. Microwave-assisted synthesis of CdS\/ZnS:Cu quantum dots for white light-emitting diodes with high color rendition. Chem. Mater. 27, 1187\u20131193 (2015).","journal-title":"Chem. Mater."},{"key":"BFsrep24459_CR10","doi-asserted-by":"publisher","first-page":"2343","DOI":"10.1021\/cr4001594","volume":"114","author":"S Gai","year":"2014","unstructured":"Gai, S., Li, C., Yang, P. & Lin, J. Recent progress in rare earth micro\/nanocrystals: soft chemical synthesis, luminescent properties and biomedical applications. Chem. Rev. 114, 2343\u20132389 (2014).","journal-title":"Chem. Rev."},{"key":"BFsrep24459_CR11","doi-asserted-by":"publisher","first-page":"751","DOI":"10.1039\/C2TC00107A","volume":"1","author":"Y Chen","year":"2013","unstructured":"Chen, Y., Huang, L., Li, S. & Pan, D. Aqueous synthesis of glutathione-capped Cu+ and Ag+ -doped ZnxCd1\u2212x S quantum dots with full color emission. J. Mater. Chem. C 1, 751\u2013756 (2013).","journal-title":"J. Mater. Chem. C"},{"key":"BFsrep24459_CR12","doi-asserted-by":"publisher","first-page":"2725","DOI":"10.1002\/ange.200705111","volume":"120","author":"SE Irvine","year":"2008","unstructured":"Irvine, S. E., Staudt, T., Rittweger, E., Engelhardt, J. & Hell, S. W. Direct light\u2010driven modulation of luminescence from Mn\u2010doped ZnSe quantum dots. Angew. Chem. 120, 2725\u20132728 (2008).","journal-title":"Angew. Chem."},{"key":"BFsrep24459_CR13","doi-asserted-by":"publisher","first-page":"3552","DOI":"10.1039\/C4CC10127H","volume":"51","author":"M Li","year":"2015","unstructured":"Li, M., Xu, C., Wu, L., Wu, P. & Hou, X. Dually enriched Cu:CdS@ZnS QDs with both polyvinylpyrrolidone twisting and SiO2 loading for improved cell imaging. Chem. Commun. 51, 3552\u20133555 (2015).","journal-title":"Chem. Commun."},{"key":"BFsrep24459_CR14","doi-asserted-by":"publisher","first-page":"2528","DOI":"10.1021\/jz300978r","volume":"3","author":"G Manna","year":"2012","unstructured":"Manna, G., Jana, S., Bose, R. & Pradhan, N. Mn-doped multinary CIZS and AIZS nanocrystals. J. Phy. Chem. Lett. 3, 2528\u20132534 (2012).","journal-title":"J. Phy. Chem. Lett."},{"key":"BFsrep24459_CR15","doi-asserted-by":"publisher","first-page":"5473","DOI":"10.1039\/c2cc31000g","volume":"48","author":"Q Qu","year":"2012","unstructured":"Qu, Q., Zhu, A., Shao, X., Shi, G. & Tian, Y. Development of a carbon quantum dots-based fluorescent Cu2+ probe suitable for living cell imaging. Chem. Commun. 48, 5473\u20135475 (2012).","journal-title":"Chem. Commun."},{"key":"BFsrep24459_CR16","doi-asserted-by":"publisher","first-page":"704","DOI":"10.1002\/adom.201400570","volume":"3","author":"JC Bear","year":"2015","unstructured":"Bear, J. C. et al. Doping group IIB metal ions into quantum dot shells via the one-pot decomposition of metal-dithiocarbamates. Adv. Opt. Mater. 3, 704\u2013712 (2015).","journal-title":"Adv. Opt. Mater."},{"key":"BFsrep24459_CR17","doi-asserted-by":"publisher","first-page":"3654","DOI":"10.1021\/am405978a","volume":"6","author":"VK Sharma","year":"2014","unstructured":"Sharma, V. K., Guzelturk, B., Erdem, T., Kelestemur, Y. & Demir, H. V. Tunable white-light-emitting Mn-doped ZnSe nanocrystals. ACS Appl. Mater. Inter. 6, 3654\u20133660 (2014).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR18","doi-asserted-by":"publisher","first-page":"10645","DOI":"10.1021\/ja903558r","volume":"131","author":"R Xie","year":"2009","unstructured":"Xie, R. & Peng, X. Synthesis of Cu-doped InP nanocrystals (d-dots) with ZnSe diffusion barrier as efficient and color-tunable NIR emitters. J. Am. Chem. Soc. 131, 10645\u201310651 (2009).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep24459_CR19","doi-asserted-by":"publisher","first-page":"369","DOI":"10.1006\/jcis.1998.5591","volume":"204","author":"E Hao","year":"1998","unstructured":"Hao, E. et al. Synthesis and photophysical properties of ZnS colloidal particles doped with silver. J. Colloid. Interf. Sci. 204, 369\u2013373 (1998).","journal-title":"J. Colloid. Interf. Sci."},{"key":"BFsrep24459_CR20","doi-asserted-by":"publisher","first-page":"3830","DOI":"10.1021\/jp809666t","volume":"113","author":"C Corrado","year":"2009","unstructured":"Corrado, C. et al. Synthesis, structural and optical properties of stable ZnS:Cu, Cl nanocrystals. J. Phys. Chem. A 113, 3830\u20133839 (2009).","journal-title":"J. Phys. Chem. A"},{"key":"BFsrep24459_CR21","doi-asserted-by":"publisher","first-page":"20864","DOI":"10.1021\/jp2047272","volume":"115","author":"S Gul","year":"2011","unstructured":"Gul, S. et al. Synthesis, optical and structural properties and charge carrier dynamics of Cu-doped ZnSe nanocrystals. J. Phys. Chem. C 115, 20864\u201320875 (2011).","journal-title":"J. Phys. Chem. C"},{"key":"BFsrep24459_CR22","doi-asserted-by":"publisher","first-page":"14319","DOI":"10.1039\/C4NR04473H","volume":"6","author":"R Zhou","year":"2014","unstructured":"Zhou, R. et al. Low-toxic Mn-doped ZnSe@ZnS quantum dots conjugated with nano-hydroxyapatite for cell imaging. Nanoscale 6, 14319\u201314325 (2014).","journal-title":"Nanoscale"},{"key":"BFsrep24459_CR23","doi-asserted-by":"publisher","first-page":"7510","DOI":"10.1038\/srep07510","volume":"4","author":"S Cao","year":"2014","unstructured":"Cao, S. et al. Long-lived and well-resolved Mn2+ ion emissions in CuInS-ZnS quantum dots. Sci. Rep. 4, 7510 (2014).","journal-title":"Sci. Rep."},{"key":"BFsrep24459_CR24","doi-asserted-by":"publisher","first-page":"379","DOI":"10.1016\/j.jcis.2011.02.030","volume":"357","author":"S Sahai","year":"2011","unstructured":"Sahai, S., Husain, M., Shanker, V., Singh, N. & Haranath, D. Facile synthesis and step by step enhancement of blue photoluminescence from Ag-doped ZnS quantum dots. J. Colloid. Interf. Sci. 357, 379\u2013383 (2011).","journal-title":"J. Colloid. Interf. Sci."},{"key":"BFsrep24459_CR25","doi-asserted-by":"publisher","first-page":"8193","DOI":"10.1021\/nn202839w","volume":"5","author":"GJ Stasiuk","year":"2011","unstructured":"Stasiuk, G. J. et al. Cell-permeable Ln (III) chelate-functionalized InP quantum dots as multimodal imaging agents. ACS Nano 5, 8193\u20138201 (2011).","journal-title":"ACS Nano"},{"key":"BFsrep24459_CR26","doi-asserted-by":"publisher","first-page":"4180","DOI":"10.1002\/adma.201104990","volume":"24","author":"X Yang","year":"2012","unstructured":"Yang, X. et al. Full visible range covering InP\/ZnS nanocrystals with high photometric performance and their application to white quantum dot light\u2010emitting Diodes. Adv. Mater. 24, 4180\u20134185 (2012).","journal-title":"Adv. Mater."},{"key":"BFsrep24459_CR27","doi-asserted-by":"publisher","first-page":"3076","DOI":"10.1039\/c3nj00407d","volume":"37","author":"B Lin","year":"2013","unstructured":"Lin, B. et al. Multifunctional manganese-doped core-shell quantum dots for magnetic resonance and fluorescence imaging of cancer cells. New J. Chem. 37, 3076\u20133083 (2013).","journal-title":"New J. Chem."},{"key":"BFsrep24459_CR28","doi-asserted-by":"publisher","first-page":"670","DOI":"10.1002\/adom.201400066","volume":"2","author":"E Song","year":"2014","unstructured":"Song, E. et al. Anomalous NIR luminescence in Mn2+ -doped fluoride perovskite nanocrystals. Adv. Opt. Mater. 2, 670\u2013678 (2014).","journal-title":"Adv. Opt. Mater."},{"key":"BFsrep24459_CR29","doi-asserted-by":"publisher","first-page":"14817","DOI":"10.1038\/srep14817","volume":"5","author":"Z Hu","year":"2015","unstructured":"Hu, Z. et al. Co-doping of Ag into Mn:ZnSe quantum dots: giving optical filtering effect with improved monochromaticity. Sci. Rep. 5, 14817 (2015).","journal-title":"Sci. Rep."},{"key":"BFsrep24459_CR30","doi-asserted-by":"publisher","first-page":"96","DOI":"10.1007\/s11671-009-9449-9","volume":"5","author":"R Sethi","year":"2010","unstructured":"Sethi, R., Kumar, L., Sharma, P. K. & Pandey, A. Tunable visible emission of Ag-doped CdZnS alloy quantum dots. Nanoscale Res. Lett. 5, 96\u2013102 (2010).","journal-title":"Nanoscale Res. Lett."},{"key":"BFsrep24459_CR31","doi-asserted-by":"publisher","first-page":"1204","DOI":"10.1021\/cm403584a","volume":"26","author":"W Zhang","year":"2013","unstructured":"Zhang, W., Lou, Q., Ji, W., Zhao, J. & Zhong, X. Color-tunable highly bright photoluminescence of cadmium-free Cu-doped Zn\u2013In\u2013S nanocrystals and electroluminescence. Chem. Mater. 26, 1204\u20131212 (2013).","journal-title":"Chem. Mater."},{"key":"BFsrep24459_CR32","doi-asserted-by":"publisher","first-page":"1405","DOI":"10.1021\/cm5047269","volume":"27","author":"Z Zhang","year":"2015","unstructured":"Zhang, Z. et al. Dual emissive Cu:InP\/ZnS\/InP\/ZnS nanocrystals: single-source \u201cgreener\u201d emitters with flexibly tunable emission from visible to near-infrared and their application in white light-emitting diodes. Chem. Mater. 27, 1405\u20131411 (2015).","journal-title":"Chem. Mater."},{"key":"BFsrep24459_CR33","doi-asserted-by":"publisher","first-page":"10858","DOI":"10.1021\/am403050s","volume":"5","author":"D Deng","year":"2013","unstructured":"Deng, D., Qu, L., Zhang, J., Ma, Y. & Gu, Y. Quaternary Zn\u2013Ag\u2013In\u2013Se quantum dots for biomedical optical imaging of RGD-modified micelles. ACS Appl. Mater. Inter. 5, 10858\u201310865 (2013).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR34","doi-asserted-by":"crossref","unstructured":"Yuan, X. et al. Dual emissive manganese and copper co-doped Zn-In-S Quantum Dots as a single color-convertor for high color rendering white-light-emitting diodes. ACS Appl. Mater. Inter. 8659\u20138666 (2015).","DOI":"10.1021\/acsami.5b00925"},{"key":"BFsrep24459_CR35","doi-asserted-by":"publisher","first-page":"2402","DOI":"10.1039\/C4TB01957A","volume":"3","author":"T Jiang","year":"2015","unstructured":"Jiang, T. et al. Aqueous synthesis of color tunable Cu doped Zn\u2013In\u2013S\/ZnS nanoparticles in the whole visible region for cellular imaging. J. Mater. Chem. B 3, 2402\u20132410 (2015).","journal-title":"J. Mater. Chem. B"},{"key":"BFsrep24459_CR36","doi-asserted-by":"publisher","first-page":"3403","DOI":"10.1039\/C3NR06168J","volume":"6","author":"J Ke","year":"2014","unstructured":"Ke, J., Li, X., Zhao, Q., Shi, Y. & Chen, G. A novel approach to synthesize ultrasmall Cu doped Zn\u2013In\u2013Se nanocrystal emitters in a colloidal system. Nanoscale 6, 3403\u20133409 (2014).","journal-title":"Nanoscale"},{"key":"BFsrep24459_CR37","doi-asserted-by":"publisher","first-page":"5078","DOI":"10.1039\/c3cp00046j","volume":"15","author":"D Deng","year":"2013","unstructured":"Deng, D., Cao, J., Qu, L., Achilefu, S. & Gu, Y. Highly luminescent water-soluble quaternary Zn\u2013Ag\u2013In\u2013S quantum dots for tumor cell-targeted imaging. Phys. Chem. Chem. Phys. 15, 5078\u20135083 (2013).","journal-title":"Phys. Chem. Chem. Phys."},{"key":"BFsrep24459_CR38","doi-asserted-by":"publisher","first-page":"15227","DOI":"10.1038\/srep15227","volume":"5","author":"A Zhang","year":"2015","unstructured":"Zhang, A. et al. Non-blinking (Zn)CuInS\/ZnS quantum dots prepared by in situ interfacial alloying approach. Sci. Rep. 5, 15227 (2015).","journal-title":"Sci. Rep."},{"key":"BFsrep24459_CR39","doi-asserted-by":"publisher","first-page":"4550","DOI":"10.1039\/c3tc30680a","volume":"1","author":"T Xuan","year":"2013","unstructured":"Xuan, T. et al. One-pot synthesis of high quality CdS nanocrystals by microwave irradiation in an organic phase: a green route for mass production. J. Mater. Chem. C 1, 4550\u20134555 (2013).","journal-title":"J. Mater. Chem. C"},{"key":"BFsrep24459_CR40","doi-asserted-by":"publisher","first-page":"5111","DOI":"10.1039\/C4TC00601A","volume":"2","author":"C Wang","year":"2014","unstructured":"Wang, C. et al. Synthesis of Ag doped ZnlnSe ternary quantum dots with tunable emission. J. Mater. Chem. C 2, 5111\u20135115 (2014).","journal-title":"J. Mater. Chem. C"},{"key":"BFsrep24459_CR41","doi-asserted-by":"publisher","first-page":"7222","DOI":"10.1021\/ja0580845","volume":"128","author":"X Gou","year":"2006","unstructured":"Gou, X. et al. Shape-controlled synthesis of ternary chalcogenide ZnIn2S4 and CuIn (S, Se)2 nano-\/microstructures via facile solution route. J. Am. Chem. Soc. 128, 7222\u20137229 (2006).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep24459_CR42","doi-asserted-by":"publisher","first-page":"9766","DOI":"10.1021\/ic800752t","volume":"47","author":"Z Chen","year":"2008","unstructured":"Chen, Z. et al. Low-temperature and template-free synthesis of ZnIn2S4 microspheres. Inorg. Chem. 47, 9766\u20139772 (2008).","journal-title":"Inorg. Chem."},{"key":"BFsrep24459_CR43","doi-asserted-by":"publisher","first-page":"10148","DOI":"10.1016\/j.ijhydene.2010.07.171","volume":"35","author":"S Shen","year":"2010","unstructured":"Shen, S., Zhao, L. & Guo, L. ZnmIn2S3+ m (m\u2009=\u20091\u20135, integer): A new series of visible-light-driven photocatalysts for splitting water to hydrogen. Int. J. Hydrogen Energ. 35, 10148\u201310154 (2010).","journal-title":"Int. J. Hydrogen Energ."},{"key":"BFsrep24459_CR44","doi-asserted-by":"publisher","first-page":"8945","DOI":"10.1021\/jp2011183","volume":"115","author":"B Mao","year":"2011","unstructured":"Mao, B., Chuang, C.-H., Wang, J. & Burda, C. Synthesis and photophysical properties of ternary I\u2013III\u2013VI AgInS2 nanocrystals: intrinsic versus surface states. J. Phys. Chem. C 115, 8945\u20138954 (2011).","journal-title":"J. Phys. Chem. C"},{"key":"BFsrep24459_CR45","doi-asserted-by":"publisher","first-page":"364","DOI":"10.1016\/j.jlumin.2013.09.063","volume":"146","author":"D Deng","year":"2014","unstructured":"Deng, D., Qu, L., Cheng, Z., Achilefu, S. & Gu, Y. Highly luminescent water-soluble quaternary Zn\u2013Ag\u2013In\u2013S quantum dots and their unique precursor S\/In ratio-dependent spectral shifts. J. Lumin. 146, 364\u2013370 (2014).","journal-title":"J. Lumin."},{"key":"BFsrep24459_CR46","doi-asserted-by":"publisher","first-page":"12388","DOI":"10.1021\/ja0750470","volume":"129","author":"T Torimoto","year":"2007","unstructured":"Torimoto, T. et al. Facile synthesis of ZnS-AgInS2 solid solution nanoparticles for a color-adjustable luminophore. J. Am. Chem. Soc. 129, 12388\u201312389 (2007).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep24459_CR47","doi-asserted-by":"publisher","first-page":"2481","DOI":"10.1002\/adfm.201303263","volume":"24","author":"G Chen","year":"2014","unstructured":"Chen, G. et al. Tracking of transplanted human mesenchymal stem cells in living mice using near\u2010infrared Ag2S quantum dots. Adv. Funct. Mater. 24, 2481\u20132488 (2014).","journal-title":"Adv. Funct. Mater."},{"key":"BFsrep24459_CR48","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1007\/s11051-015-2953-1","volume":"17","author":"AE Raevskaya","year":"2015","unstructured":"Raevskaya, A. E., Ivanchenko, M. V., Stroyuk, O. L., Kuchmiy, S. Y. & Plyusnin, V. F. Luminescent Ag-doped In2S3 nanoparticles stabilized by mercaptoacetate in water and glycerol. J. Nanopart. Res. 17, 1\u201312 (2015).","journal-title":"J. Nanopart. Res."},{"key":"BFsrep24459_CR49","doi-asserted-by":"publisher","first-page":"6764","DOI":"10.1021\/acsami.5b00166","volume":"7","author":"SH Park","year":"2015","unstructured":"Park, S. H. et al. Highly bright yellow-green-emitting CuInS2 colloidal quantum dots with core\/shell\/shell architecture for white light-emitting diodes. ACS Appl. Mater. Inter. 7, 6764\u20136771 (2015).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR50","doi-asserted-by":"publisher","first-page":"7342","DOI":"10.1021\/acsami.5b00664","volume":"7","author":"HC Yoon","year":"2015","unstructured":"Yoon, H. C., Oh, J. H., Ko, M., Yoo, H. & Do, Y. R. Synthesis and characterization of green Zn\u2013Ag\u2013In\u2013S and red Zn\u2013Cu\u2013In\u2013S quantum dots for ultrahigh color quality of down-converted white LEDs. ACS Appl. Mater. Inter. 7, 7342\u20137350, (2015).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR51","doi-asserted-by":"publisher","first-page":"15379","DOI":"10.1021\/am503889z","volume":"6","author":"P-H Chuang","year":"2014","unstructured":"Chuang, P.-H., Lin, C. C. & Liu, R.-S. Emission-tunable CuInS2\/ZnS quantum dots: structure, optical properties and application in white light-emitting diodes with high color rendering index. ACS Appl. Mater. Inter. 6, 15379\u201315387 (2014).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR52","doi-asserted-by":"publisher","first-page":"17623","DOI":"10.1021\/acsami.5b05503","volume":"7","author":"C Zhao","year":"2015","unstructured":"Zhao, C. et al. Small GSH-capped CuInS2 quantum dots: MPA-assisted aqueous phase transfer and bioimaging applications. ACS Appl. Mater. Inter. 7, 17623\u201317629 (2015).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR53","doi-asserted-by":"publisher","first-page":"1007","DOI":"10.1021\/ja1089809","volume":"133","author":"BB Srivastava","year":"2010","unstructured":"Srivastava, B. B., Jana, S. & Pradhan, N. Doping Cu in semiconductor nanocrystals: some old and some new physical insights. J. Am. Chem. Soc. 133, 1007\u20131015 (2010).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep24459_CR54","doi-asserted-by":"publisher","first-page":"4136","DOI":"10.1021\/ja070099a","volume":"129","author":"I Robel","year":"2007","unstructured":"Robel, I., Kuno, M. & Kamat, P. V. Size-dependent electron injection from excited CdSe quantum dots into TiO2 nanoparticles. J. Am. Chem. Soc. 129, 4136\u20134137 (2007).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep24459_CR55","doi-asserted-by":"publisher","first-page":"2011","DOI":"10.1021\/am4050772","volume":"6","author":"MF Foda","year":"2014","unstructured":"Foda, M. F., Huang, L., Shao, F. & Han, H.-Y. Biocompatible and highly luminescent near-infrared CuInS2\/ZnS quantum dots embedded silica beads for cancer cell imaging. ACS Appl. Mater. Inter. 6, 2011\u20132017 (2014).","journal-title":"ACS Appl. Mater. Inter."},{"key":"BFsrep24459_CR56","doi-asserted-by":"publisher","first-page":"6434","DOI":"10.1021\/cm8006827","volume":"20","author":"H Zhong","year":"2008","unstructured":"Zhong, H. et al. Controlled synthesis and optical properties of colloidal ternary chalcogenide CuInS2 nanocrystals. Chem. Mater. 20, 6434\u20136443 (2008).","journal-title":"Chem. Mater."},{"key":"BFsrep24459_CR57","doi-asserted-by":"publisher","first-page":"7933","DOI":"10.1021\/acs.jpcc.5b00413","volume":"119","author":"X Kang","year":"2015","unstructured":"Kang, X., Huang, L., Yang, Y. & Pan, D. Scaling up the aqueous synthesis of visible light emitting multinary AgInS2\/ZnS core\/shell quantum dots. J. Phys. Chem. C 119, 7933\u20137940 (2015).","journal-title":"J. Phys. Chem. C"},{"key":"BFsrep24459_CR58","doi-asserted-by":"publisher","first-page":"20876","DOI":"10.1021\/jp204831y","volume":"115","author":"S Xu","year":"2011","unstructured":"Xu, S. et al. Effect of shell thickness on the optical properties in CdSe\/CdS\/Zn0.5Cd0.5S\/ZnS and CdSe\/CdS\/ZnxCd1\u2013xS\/ZnS core\/multishell nanocrystals. J. Phy. Chem. C 115, 20876\u201320881 (2011).","journal-title":"J. Phy. Chem. C"}],"container-title":["Scientific Reports"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/srep24459","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/srep24459.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/srep24459.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,1,4]],"date-time":"2023-01-04T18:20:08Z","timestamp":1672856408000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/srep24459"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,4,14]]},"references-count":58,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2016,7,26]]}},"alternative-id":["BFsrep24459"],"URL":"https:\/\/doi.org\/10.1038\/srep24459","relation":{},"ISSN":["2045-2322"],"issn-type":[{"value":"2045-2322","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,4,14]]},"assertion":[{"value":"28 October 2015","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"29 March 2016","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"14 April 2016","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing financial interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"24459"}}