{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T20:08:53Z","timestamp":1776197333080,"version":"3.50.1"},"reference-count":50,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2016,10,11]],"date-time":"2016-10-11T00:00:00Z","timestamp":1476144000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2016,10,11]],"date-time":"2016-10-11T00:00:00Z","timestamp":1476144000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Sci Rep"],"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A self-catenated Zn(II)-organic framework formulated as [Zn<jats:sub>2<\/jats:sub>(3,3\u2032-bpeab)(oba)<jats:sub>2<\/jats:sub>]\u00b7DMF (1) exhibiting a six-connected 4<jats:sup>4<\/jats:sup>\u00b76<jats:sup>10<\/jats:sup>\u00b78 topology has been successfully synthesized through the mixed-ligand of kinked 3,3\u2032-bis[2-(4-pyridyl)ethenyl]azobenzene (3,3\u2032-bpeab) and 4,4\u2032-oxybis-benzoic acid (H<jats:sub>2<\/jats:sub>oba) under solvothermal condition. UV light triggers isomerization of complex 1 in a single-crystal-to-single-crystal (SCSC) manner, giving rise to a conformational supramolecular isomer 1_UV through the pedal motion of photoresponsive double bonds. Dynamic photo-switching in the obtained light-responsive supramolecular isomers leads to instantly reversible CO<jats:sub>2<\/jats:sub> uptake. Furthermore, the ligand originated fluorescence emission of water-resistant complex 1 is selectively sensitive to 4-nitrotoluene (4-NT) owing to a higher quenching efficiency of the perilous explosive over other structurally similar nitroaromatics, prefiguring the potentials of 1 as a fluorescence sensor towards 4-NT in aquatic media.<\/jats:p>","DOI":"10.1038\/srep34870","type":"journal-article","created":{"date-parts":[[2016,10,11]],"date-time":"2016-10-11T09:50:14Z","timestamp":1476179414000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Light-triggered Supramolecular Isomerism in a Self-catenated Zn(II)-organic Framework: Dynamic Photo-switching CO2 Uptake and Detection of Nitroaromatics"],"prefix":"10.1038","volume":"6","author":[{"given":"Wei-Chao","family":"Song","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xun-Zhe","family":"Cui","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhong-Yi","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"En-Cui","family":"Yang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao-Jun","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2016,10,11]]},"reference":[{"key":"BFsrep34870_CR1","doi-asserted-by":"publisher","first-page":"695","DOI":"10.1038\/nchem.444","volume":"1","author":"S Horike","year":"2009","unstructured":"Horike, S., Shimomura, S. & Kitagawa, S. Soft porous crystals. Nat. Chem. 1, 695\u2013704 (2009).","journal-title":"Nat. Chem."},{"key":"BFsrep34870_CR2","doi-asserted-by":"publisher","first-page":"5789","DOI":"10.1039\/C4CS00129J","volume":"43","author":"J-P Zhang","year":"2014","unstructured":"Zhang, J.-P., Liao, P.-Q., Zhou, H.-L., Lin, R.-B. & Chen, X.-M. Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers. Chem. Soc. Rev. 43, 5789\u20135814 (2014).","journal-title":"Chem. Soc. Rev."},{"key":"BFsrep34870_CR3","doi-asserted-by":"publisher","first-page":"5432","DOI":"10.1002\/adma.201501523","volume":"27","author":"Z Chang","year":"2015","unstructured":"Chang, Z., Yang, D.-H., Xu, J., Hu, T.-L. & Bu, X.-H. Flexible metal-organic frameworks: recent advances and potential applications. Adv. Mater. 27, 5432\u20135441 (2015).","journal-title":"Adv. Mater."},{"key":"BFsrep34870_CR4","doi-asserted-by":"publisher","first-page":"4767","DOI":"10.1002\/anie.201001551","volume":"49","author":"D Liu","year":"2010","unstructured":"Liu, D. et al. Single-crystal-to-single-crystal transformations of two three-dimensional coordination polymers through regioselective [2\u2009+\u20092] photodimerization reactions. Angew. Chem. Int. Ed. 49, 4767\u20134770 (2010).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR5","doi-asserted-by":"publisher","first-page":"1905","DOI":"10.1021\/acs.chemmater.5b00046","volume":"27","author":"F-X Coudert","year":"2015","unstructured":"Coudert, F.-X. Responsive metal\u2013organic frameworks and framework materials: under pressure, taking the heat, in the spotlight, with friends. Chem. Mater. 27, 1905\u20131916 (2015).","journal-title":"Chem. Mater."},{"key":"BFsrep34870_CR6","doi-asserted-by":"publisher","first-page":"11550","DOI":"10.1002\/anie.201306304","volume":"52","author":"Q Chen","year":"2013","unstructured":"Chen, Q. et al. A controllable gate effect in cobalt(II) organic frameworks by reversible structure transformations. Angew. Chem. Int. Ed. 52, 11550\u201311553 (2013).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR7","doi-asserted-by":"publisher","first-page":"9298","DOI":"10.1002\/anie.201311124","volume":"53","author":"F Luo","year":"2014","unstructured":"Luo, F. et al. Photoswitching CO2 capture and release in a photochromic diarylethene metal-organic framework. Angew. Chem. Int. Ed. 53, 9298\u20139301 (2014).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR8","doi-asserted-by":"publisher","first-page":"99","DOI":"10.1021\/ja209197f","volume":"134","author":"J Park","year":"2012","unstructured":"Park, J. et al. Reversible Alteration of CO2 adsorption upon photochemical or thermal treatment in a metal\u2013organic framework. J. Am. Chem. Soc. 134, 99 (2012).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep34870_CR9","doi-asserted-by":"publisher","first-page":"3695","DOI":"10.1002\/anie.201206359","volume":"52","author":"R Lyndon","year":"2013","unstructured":"Lyndon, R. et al. Dynamic photo-switching in metal-organic frameworks as a route to low-energy carbon dioxide capture and release. Angew. Chem. Int. Ed. 52, 3695\u20133698 (2013).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR10","doi-asserted-by":"publisher","first-page":"7882","DOI":"10.1021\/acs.chemmater.5b02211","volume":"27","author":"R Lyndon","year":"2015","unstructured":"Lyndon, R. et al. Visible light-triggered capture and release of CO2 from stable metal organic frameworks. Chem. Mater. 27, 7882\u20137888 (2015).","journal-title":"Chem. Mater."},{"key":"BFsrep34870_CR11","doi-asserted-by":"publisher","first-page":"451","DOI":"10.1039\/C3CC47816E","volume":"50","author":"A Chanthapally","year":"2014","unstructured":"Chanthapally, A., Oh, W. T. & Vittal, J. J. Photoreactivity of polymorphs of a ladder polymer with criss-cross and parallel orientations of C=C bonds. Chem. Commun. 50, 451\u2013453 (2014).","journal-title":"Chem. Commun."},{"key":"BFsrep34870_CR12","doi-asserted-by":"publisher","first-page":"558","DOI":"10.1021\/ja409272p","volume":"136","author":"S-Y Yang","year":"2014","unstructured":"Yang, S.-Y. et al. Crystallographic snapshots of the interplay between reactive guest and host molecules in a porous coordination polymer: stereochemical coupling and feedback mechanism of three photoactive centers triggered by UV-induced isomerization, dimerization, and polymerization reactions. J. Am. Chem. Soc. 136, 558\u2013561 (2014).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep34870_CR13","doi-asserted-by":"publisher","first-page":"4903","DOI":"10.1039\/C5CE00594A","volume":"17","author":"F-L Hu","year":"2015","unstructured":"Hu, F.-L., Wang, S.-L., Abrahams, B. F. & Lang, J.-P. Observance of a large conformational change associated with the rotation of the naphthyl groups during the photodimerization of criss-cross aligned C=C bonds within a 2D coordination polymer. CrystEngComm 17, 4903\u20134911 (2015).","journal-title":"CrystEngComm"},{"key":"BFsrep34870_CR14","doi-asserted-by":"publisher","first-page":"414","DOI":"10.1002\/anie.201308606","volume":"53","author":"I-H Park","year":"2014","unstructured":"Park, I.-H. et al. Metal-organic organopolymeric hybrid framework by reversible [2+2] cycloaddition reaction. Angew. Chem. Int. Ed. 53, 414\u2013419 (2014).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR15","doi-asserted-by":"publisher","first-page":"5842","DOI":"10.1002\/anie.201310211","volume":"53","author":"J Park","year":"2014","unstructured":"Park, J., Sun, L.-B., Chen, Y.-P., Perry, Z. & Zhou, H.-C. Azobenzene-functionalized metal-organic polyhedra for the optically responsive capture and release of guest molecules. Angew. Chem. Int. Ed. 53, 5842\u20135846 (2014).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR16","first-page":"397","volume":"254","author":"L Zhang","year":"2013","unstructured":"Zhang, L. et al. Coumarin-modified microporous-mesoporous Zn-MOF-74 showing ultra-high uptake capacity and photo-switched storage\/release of UVI ions. J. Hazard Mater. 254, 397\u2013405 (2013).","journal-title":"J. Hazard Mater."},{"key":"BFsrep34870_CR17","doi-asserted-by":"publisher","first-page":"2047","DOI":"10.1039\/C5GC02182K","volume":"18","author":"LL Gong","year":"2016","unstructured":"Gong, L. L., Feng, X. F., Luo, F., Yi, X. F. & Zheng, A. M. Removal and safe reuse of highly toxic allyl alcohol using a highly selective photo-sensitive metal\u2013organic framework. Green Chem. 18, 2047\u20132055 (2016).","journal-title":"Green Chem."},{"key":"BFsrep34870_CR18","doi-asserted-by":"publisher","first-page":"11587","DOI":"10.1021\/acs.inorgchem.5b02037","volume":"54","author":"LL Gong","year":"2015","unstructured":"Gong, L. L., Feng, X. F. & Luo, F. Novel azo-metal\u2212organic framework showing a 10-connected bct net, breathing behavior, and unique photoswitching behavior toward CO2 . Inorg. Chem. 54, 11587\u221211589 (2015).","journal-title":"Inorg. Chem."},{"key":"BFsrep34870_CR19","doi-asserted-by":"publisher","first-page":"5815","DOI":"10.1039\/C4CS00010B","volume":"43","author":"Z Hu","year":"2014","unstructured":"Hu, Z., Deibert, B. J. & Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 43, 5815\u20135840 (2014).","journal-title":"Chem. Soc. Rev."},{"key":"BFsrep34870_CR20","doi-asserted-by":"publisher","first-page":"6204","DOI":"10.1021\/jacs.6b01663","volume":"138","author":"B Wang","year":"2016","unstructured":"Wang, B. et al. Highly stable Zr(IV)-based metal-organic frameworks for the detection and removal of antibiotics and organic explosives in water. J. Am. Chem. Soc. 138, 6204\u20136216 (2016).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep34870_CR21","doi-asserted-by":"publisher","first-page":"11475","DOI":"10.1002\/chem.201500595","volume":"21","author":"F-Y Yi","year":"2015","unstructured":"Yi, F.-Y., Li, J.-P., Wu, D. & Sun, Z.-M. A series of multifunctional metal-organic frameworks showing excellent luminescent sensing, sensitization, and adsorbent abilities. Chem. Eur. J. 21, 11475\u201311482 (2015).","journal-title":"Chem. Eur. J."},{"key":"BFsrep34870_CR22","doi-asserted-by":"publisher","first-page":"965","DOI":"10.1002\/chem.201405167","volume":"21","author":"B Joarder","year":"2015","unstructured":"Joarder, B., Desai, A. V., Samanta, P., Mukherjee, S. & Ghosh, S. K. Selective and sensitive aqueous-phase detection of 2,4,6-trinitrophenol (TNP) by an amine-functionalized metal-organic framework. Chem. Eur. J. 21, 965\u2013969 (2015).","journal-title":"Chem. Eur. J."},{"key":"BFsrep34870_CR23","doi-asserted-by":"publisher","first-page":"12690","DOI":"10.1039\/C5TA00322A","volume":"3","author":"J Qin","year":"2015","unstructured":"Qin, J. et al. Aqueous- and vapor-phase detection of nitroaromatic explosives by a water-stable fluorescent microporous MOF directed by an ionic liquid. J. Mater. Chem. A 3, 12690\u201312697 (2015).","journal-title":"J. Mater. Chem. A"},{"key":"BFsrep34870_CR24","doi-asserted-by":"publisher","first-page":"2850","DOI":"10.1021\/acs.accounts.5b00311","volume":"48","author":"NC Burtch","year":"2015","unstructured":"Burtch, N. C. & Walton, K. S. Modulating adsorption and stability properties in pillared metal-organic frameworks: a model system for understanding ligand effects. Acc. Chem. Res. 48, 2850\u20132857 (2015).","journal-title":"Acc. Chem. Res."},{"key":"BFsrep34870_CR25","doi-asserted-by":"publisher","first-page":"6528","DOI":"10.1002\/chem.200501308","volume":"12","author":"D-R Xiao","year":"2006","unstructured":"Xiao, D.-R. et al. A bridge between pillared-layer and helical structures: a series of three-dimensional pillared coordination polymers with multiform helical chains. Chem. Eur. J. 12, 6528\u20136541 (2006).","journal-title":"Chem. Eur. J."},{"key":"BFsrep34870_CR26","doi-asserted-by":"publisher","first-page":"2596","DOI":"10.1039\/C6CE00371K","volume":"18","author":"Y-N Gong","year":"2016","unstructured":"Gong, Y.-N., Zhong, D.-C. & Lu, T.-B. Interpenetrating metal\u2013organic frameworks. CrystEngComm 18, 2596\u20132606 (2016).","journal-title":"CrystEngComm"},{"key":"BFsrep34870_CR27","doi-asserted-by":"publisher","first-page":"4153","DOI":"10.1021\/ja106851d","volume":"133","author":"S Pramanik","year":"2011","unstructured":"Pramanik, S., Zheng, C. Zhang, X., Emge, T. J. & Li, J. New microporous metal-organic framework demonstrating unique selectivity for detection of high explosives and aromatic compounds. J. Am. Chem. Soc. 133, 4153\u20134155 (2011).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep34870_CR28","doi-asserted-by":"publisher","first-page":"136","DOI":"10.1016\/j.jorganchem.2006.07.048","volume":"692","author":"M Kondo","year":"2007","unstructured":"Kondo, M. et al. Synthesis and structural determination of new multidimensional coordination polymers with 4,4\u2032-oxybis(benzoate) building ligands: Construction of coordination polymers with heteroorganic bridges. J. Organomet. Chem. 692, 136\u2013141 (2007).","journal-title":"J. Organomet. Chem."},{"key":"BFsrep34870_CR29","doi-asserted-by":"publisher","first-page":"10949","DOI":"10.1039\/C4CE01635A","volume":"16","author":"Y Ge","year":"2014","unstructured":"Ge, Y., Li, N.-Y., Ma, W., Liu, D. & Tang, X.-Y. Structural diversity and photoluminescence properties of zinc coordination polymers constructed from 1,4-bis[2-(4-pyridyl)ethenyl]-2,3,5,6-tetramethylbenzene and para-dicarboxylates. CrystEngComm 16, 10949\u201310958 (2014).","journal-title":"CrystEngComm"},{"key":"BFsrep34870_CR30","doi-asserted-by":"publisher","first-page":"2712","DOI":"10.1002\/ejic.201100227","volume":"17","author":"J Li","year":"2011","unstructured":"Li, J. et al. Solvothermal synthesis and structural characterisation of metal-organic frameworks with paddle-wheel Zinc carboxylate clusters and mixed ligands. Eur. J. Inorg. Chem. 17, 2712\u20132719 (2011).","journal-title":"Eur. J. Inorg. Chem."},{"key":"BFsrep34870_CR31","doi-asserted-by":"publisher","first-page":"2092","DOI":"10.1021\/cg500033b","volume":"14","author":"MY Masoomi","year":"2014","unstructured":"Masoomi, M. Y., Stylianou, K. C., Morsali, A., Retailleau, P. & Maspoch, D. Selective CO2 capture in metal\u2013organic frameworks with azine-functionalized pores generated by mechanosynthesis. Cryst. Growth Des. 14, 2092\u20132096 (2014).","journal-title":"Cryst. Growth Des."},{"key":"BFsrep34870_CR32","unstructured":"Reticular Chemistry Structure Resource (RCSR), http:\/\/rcsr.anu.edu.au\/."},{"key":"BFsrep34870_CR33","doi-asserted-by":"publisher","first-page":"1889","DOI":"10.1021\/ic102305v","volume":"50","author":"MK Sharma","year":"2011","unstructured":"Sharma, M. K. & Bharadwaj, P. K. A dynamic open framework exhibiting guest- and\/or temperature-induced bicycle-pedal motion in single-crystal to single-crystal transformation. Inorg. Chem. 50, 1889\u20131897 (2011).","journal-title":"Inorg. Chem."},{"key":"BFsrep34870_CR34","doi-asserted-by":"publisher","first-page":"3173","DOI":"10.1039\/C4SC01132E","volume":"5","author":"HPG Thompson","year":"2014","unstructured":"Thompson, H. P. G. & Day, G. M. Which conformations make stable crystal structures? Mapping crystalline molecular geometries to the conformational energy landscape. Chem. Sci. 5, 3173\u20133182 (2014).","journal-title":"Chem. Sci."},{"key":"BFsrep34870_CR35","doi-asserted-by":"publisher","first-page":"10884","DOI":"10.1021\/ja011197d","volume":"123","author":"J Harada","year":"2001","unstructured":"Harada, J. & Ogawa, K. Invisible but common motion in organic crystals: a pedal motion in stilbenes and azobenzenes. J. Am. Chem. Soc. 123, 10884\u201310888 (2001).","journal-title":"J. Am. Chem. Soc."},{"key":"BFsrep34870_CR36","doi-asserted-by":"publisher","first-page":"5182","DOI":"10.1021\/cg500962y","volume":"14","author":"J Harada","year":"2014","unstructured":"Harada, J. & Ogawa, K. What molecules are likely or unlikely to undergo pedal motions in crystals? Cryst. Growth Des. 14, 5182\u20135188 (2014).","journal-title":"Cryst. Growth Des."},{"key":"BFsrep34870_CR37","doi-asserted-by":"publisher","first-page":"10307","DOI":"10.1002\/anie.201204475","volume":"51","author":"D Feng","year":"2012","unstructured":"Feng, D. et al. Zirconium-metalloporphyrin PCN-222: mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts. Angew. Chem. Int. Ed. 51, 10307\u201310310 (2012).","journal-title":"Angew. Chem. Int. Ed."},{"key":"BFsrep34870_CR38","doi-asserted-by":"publisher","first-page":"15697","DOI":"10.1039\/C5DT01770J","volume":"44","author":"X Zhang","year":"2015","unstructured":"Zhang, X., Zhang, Y.-Z., Zhang, D.-S., Zhu, B. & Li, J.-R. A hydrothermally stable Zn(II)-based metal-organic framework: structural modulation and gas adsorption. Dalton Trans. 44, 15697\u201315702 (2015).","journal-title":"Dalton Trans."},{"key":"BFsrep34870_CR39","doi-asserted-by":"publisher","first-page":"653","DOI":"10.1039\/C2CC35561B","volume":"49","author":"ZJ Zhang","year":"2013","unstructured":"Zhang, Z. J., Zhao, Y. G., Gong, Q. H., Li, Z. & Li, J. MOFs for CO2 capture and separation from flue gas mixtures: the effect of multifunctional sites on their adsorption capacity and selectivity. Chem. Commun. 49, 653\u2013661 (2013).","journal-title":"Chem. Commun."},{"key":"BFsrep34870_CR40","doi-asserted-by":"publisher","first-page":"2868","DOI":"10.1039\/C4EE00143E","volume":"7","author":"Z Zhang","year":"2014","unstructured":"Zhang, Z., Yao, Z.-Z., Xiang, S. & Chen, B. Perspective of microporous metal\u2013organic frameworks for CO2 capture and separation. Energy Environ. Sci. 7, 2868\u20132899 (2014).","journal-title":"Energy Environ. Sci."},{"key":"BFsrep34870_CR41","doi-asserted-by":"publisher","first-page":"228","DOI":"10.1039\/C4CS00230J","volume":"44","author":"M Eddaoudi","year":"2015","unstructured":"Eddaoudi, M., Sava, D. F., Eubank, J. F., Adil, K. & Guillerm, V. Zeolite-like metal-organic frameworks (ZMOFs): design, synthesis, and properties. Chem. Soc. Rev. 44, 228\u2013249 (2015).","journal-title":"Chem. Soc. Rev."},{"key":"BFsrep34870_CR42","doi-asserted-by":"publisher","first-page":"9208","DOI":"10.1021\/es902566b","volume":"43","author":"YA Kholod","year":"2009","unstructured":"Kholod, Y. A. et al. Application of quantum chemical approximations to environmental problems: prediction of water solubility for nitro compounds. Environ. Sci. Technol. 43, 9208\u20139215 (2009).","journal-title":"Environ. Sci. Technol."},{"key":"BFsrep34870_CR43","doi-asserted-by":"publisher","first-page":"2276","DOI":"10.1002\/chem.201302455","volume":"20","author":"B Gole","year":"2014","unstructured":"Gole, B., Bar, A. K. & Mukherjee, P. S. Modification of extended open frameworks with fluorescent tags for sensing explosives: competition between size selectivity and electron deficiency. Chem. Eur. J. 20, 2276\u20132291 (2014).","journal-title":"Chem. Eur. J."},{"key":"BFsrep34870_CR44","doi-asserted-by":"publisher","first-page":"1744","DOI":"10.1021\/ic502686b","volume":"54","author":"L-L Lv","year":"2015","unstructured":"Lv, L.-L., Yang, J., Zhang, H.-M., Liu, Y.-Y. & Ma, J.-F. Metal-ion exchange, small-molecule sensing, selective dye adsorption, and reversible iodine uptake of three coordination polymers constructed by a new resorcin[4]arene-based tetracarboxylate. Inorg. Chem. 54, 1744\u20131755 (2015).","journal-title":"Inorg. Chem."},{"key":"BFsrep34870_CR45","doi-asserted-by":"publisher","first-page":"4627","DOI":"10.1021\/acs.cgd.5b00902","volume":"15","author":"S Mukherjee","year":"2015","unstructured":"Mukherjee, S., Desai, A. V., Manna, B., Inamdar, A. I. & Ghosh, S. K. Exploitation of guest accessible aliphatic amine functionality of a metal\u2013organic framework for selective detection of 2,4,6-trinitrophenol (TNP) in water. Cryst. Growth Des. 15, 4627\u20134634 (2015).","journal-title":"Cryst. Growth Des."},{"key":"BFsrep34870_CR46","doi-asserted-by":"publisher","first-page":"8915","DOI":"10.1039\/C4CC03053B","volume":"50","author":"SS Nagarkar","year":"2014","unstructured":"Nagarkar, S. S., Desai, A. V. & Ghosh, S. K. A fluorescent metal-organic framework for highly selective detection of nitro explosives in the aqueous phase. Chem. Commun. 50, 8915\u20138918 (2014).","journal-title":"Chem. Commun."},{"key":"BFsrep34870_CR47","unstructured":"Sheldrick, G. M. SADABS, University of G\u00f6ttingen, G\u00f6ttingen: Germany, 1996."},{"key":"BFsrep34870_CR48","unstructured":"Bruker AXS, SAINT software Reference Manual, WI, 1998."},{"key":"BFsrep34870_CR49","unstructured":"Sheldrick, G. M. SHELXL-97, Program for X-ray crystal structure refinement; University of G\u00f6ttingen: G\u00f6ttingen, Germany, 1997."},{"key":"BFsrep34870_CR50","unstructured":"Sheldrick, G. M. SHELXS-97, Program for X-ray crystal structure sloution; University of G\u00f6ttingen: G\u00f6ttingen, Germany, 1997."}],"container-title":["Scientific Reports"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/srep34870.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/srep34870","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/srep34870.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,1,5]],"date-time":"2023-01-05T01:50:44Z","timestamp":1672883444000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/srep34870"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,10,11]]},"references-count":50,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2016,12,16]]}},"alternative-id":["BFsrep34870"],"URL":"https:\/\/doi.org\/10.1038\/srep34870","relation":{},"ISSN":["2045-2322"],"issn-type":[{"value":"2045-2322","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,10,11]]},"assertion":[{"value":"12 July 2016","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"20 September 2016","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"11 October 2016","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare no competing financial interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"34870"}}