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Here, we employ the state-of-the-art many-body dispersion (MBD) approach, coupled with density functional theory methods, to study the interactions of benzene with low-index coinage metal surfaces. The many-body effects contribute mostly to the (111) surface, and leastly to the (110) surface. This corresponds to the same sequence of planar atomic density of face-centered-cubic lattices,<jats:italic>i.e.<\/jats:italic>, (111)\u2009&gt;\u2009(100)\u2009&gt;\u2009(110). The binding energy for benzene\/Au(110) is even stronger than that for benzene\/Ag(110), due to a larger broadening of molecular orbitals in the former case. On the other hand, our calculations show almost identical binding energies for benzene on Ag(111) and Au(111), which contradicts the classic<jats:italic>d<\/jats:italic>-band center theory that could well predict the trend in chemisorption energies for various small molecules on a number of metal surfaces. Our results provide important insight into the benchmark adsorption systems with opener surfaces, which could help in designing more complex functional interfaces.<\/jats:p>","DOI":"10.1038\/srep39529","type":"journal-article","created":{"date-parts":[[2016,12,22]],"date-time":"2016-12-22T10:47:03Z","timestamp":1482403623000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Aromatic molecules on low-index coinage metal surfaces: Many-body dispersion effects"],"prefix":"10.1038","volume":"6","author":[{"given":"Yingda","family":"Jiang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sha","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2016,12,22]]},"reference":[{"key":"BFsrep39529_CR1","doi-asserted-by":"crossref","unstructured":"Koch, N., Ueno, N. & Wee, A. 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