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Herein we discover ambient catalyst-free disproportionation of N\n                    <jats:sub>2<\/jats:sub>\n                    by water plasma which occurs via the distinctive HONH-HNOH\n                    <jats:sup>+\u2022<\/jats:sup>\n                    intermediate to yield economically valuable nitroxyl (HNO) and hydroxylamine (NH\n                    <jats:sub>2<\/jats:sub>\n                    OH) products. Calculations suggest that the reaction is prompted by the coordination of electronically excited N\n                    <jats:sub>2<\/jats:sub>\n                    with water dimer radical cation, (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>+\u2022<\/jats:sup>\n                    , in its two-center-three-electron configuration. The reaction products are collected in a 76-needle array discharge reactor with product yields of 1.14\u2009\u03bcg\u2009cm\n                    <jats:sup>\u20132<\/jats:sup>\n                    h\n                    <jats:sup>\u20131<\/jats:sup>\n                    for NH\n                    <jats:sub>2<\/jats:sub>\n                    OH and 0.37\u2009\u03bcg\u2009cm\n                    <jats:sup>\u20132<\/jats:sup>\n                    h\n                    <jats:sup>\u20131<\/jats:sup>\n                    for HNO. Potential applications of these compounds are demonstrated to make ammonia (for NH\n                    <jats:sub>2<\/jats:sub>\n                    OH), as well as to chemically react and convert cysteine, and serve as a neuroprotective agent (for HNO). The conversion of N\n                    <jats:sub>2<\/jats:sub>\n                    into HNO and NH\n                    <jats:sub>2<\/jats:sub>\n                    OH by water plasma could offer great profitability and reduction of polluting emissions, thus giving an entirely look and perspectives to the problem of green N\n                    <jats:sub>2<\/jats:sub>\n                    fixation.\n                  <\/jats:p>","DOI":"10.1038\/s41467-024-45832-9","type":"journal-article","created":{"date-parts":[[2024,2,20]],"date-time":"2024-02-20T07:04:44Z","timestamp":1708412684000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Efficient catalyst-free N2 fixation by water radical cations under ambient conditions"],"prefix":"10.1038","volume":"15","author":[{"given":"Xiaoping","family":"Zhang","sequence":"first","affiliation":[]},{"given":"Rui","family":"Su","sequence":"additional","affiliation":[]},{"given":"Jingling","family":"Li","sequence":"additional","affiliation":[]},{"given":"Liping","family":"Huang","sequence":"additional","affiliation":[]},{"given":"Wenwen","family":"Yang","sequence":"additional","affiliation":[]},{"given":"Konstantin","family":"Chingin","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9374-1809","authenticated-orcid":false,"given":"Roman","family":"Balabin","sequence":"additional","affiliation":[]},{"given":"Jingjing","family":"Wang","sequence":"additional","affiliation":[]},{"given":"Xinglei","family":"Zhang","sequence":"additional","affiliation":[]},{"given":"Weifeng","family":"Zhu","sequence":"additional","affiliation":[]},{"given":"Keke","family":"Huang","sequence":"additional","affiliation":[]},{"given":"Shouhua","family":"Feng","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0576-0415","authenticated-orcid":false,"given":"Huanwen","family":"Chen","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2024,2,20]]},"reference":[{"key":"45832_CR1","doi-asserted-by":"publisher","first-page":"6741","DOI":"10.1126\/sciadv.aao6741","volume":"3","author":"LY Yeung","year":"2017","unstructured":"Yeung, L. 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