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Although high-temperature CO<jats:sub>2<\/jats:sub> electroreduction in solid oxide electrolysis cells is industrially relevant, current catalysts have modest energy efficiency and a limited lifetime at high current densities, generally below 70% and 200\u2009h, respectively, at 1\u2009A\u2009cm<jats:sup>\u2212<\/jats:sup>\n            <jats:sup>2<\/jats:sup> and temperatures of 800\u2009\u00b0C or higher<jats:sup>4\u20138<\/jats:sup>. Here we develop an encapsulated Co\u2013Ni alloy catalyst using Sm<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>-doped CeO<jats:sub>2<\/jats:sub> that exhibits an energy efficiency of 90% and a lifetime of more than 2,000\u2009h at 1\u2009A\u2009cm<jats:sup>\u2212<\/jats:sup>\n            <jats:sup>2<\/jats:sup> for high-temperature CO<jats:sub>2<\/jats:sub>-to-CO conversion at 800\u2009\u00b0C. Its selectivity towards CO is about 100%, and its single-pass yield reaches 90%. We show that the efficacy of our catalyst arises from its unique encapsulated structure and optimized alloy composition, which simultaneously enable enhanced CO<jats:sub>2<\/jats:sub> adsorption, moderate CO adsorption and suppressed metal agglomeration. This work provides an efficient strategy for the design of catalysts for high-temperature reactions that overcomes the typical trade-off between activity and stability and has potential industrial applications.<\/jats:p>","DOI":"10.1038\/s41586-025-08978-0","type":"journal-article","created":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T15:02:25Z","timestamp":1747234945000},"page":"1156-1161","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":119,"title":["Encapsulated Co\u2013Ni alloy boosts high-temperature CO2 electroreduction"],"prefix":"10.1038","volume":"641","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8352-0583","authenticated-orcid":false,"given":"Wenchao","family":"Ma","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8725-5051","authenticated-orcid":false,"given":"Jordi","family":"Morales-Vidal","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaming","family":"Tian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng-Ting","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3407-4297","authenticated-orcid":false,"given":"Seongmin","family":"Jin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhao","family":"Ren","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julian","family":"Taubmann","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6499-5914","authenticated-orcid":false,"given":"Christodoulos","family":"Chatzichristodoulou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0967-0583","authenticated-orcid":false,"given":"Jeremy","family":"Luterbacher","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7480-9940","authenticated-orcid":false,"given":"Hao Ming","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"N\u00faria","family":"L\u00f3pez","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8335-1196","authenticated-orcid":false,"given":"Xile","family":"Hu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2025,5,14]]},"reference":[{"key":"8978_CR1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav3506","volume":"364","author":"P De Luna","year":"2019","unstructured":"De Luna, P. et al. 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DFT source data of \u201cEncapsulated Co-Ni alloy boosts high-temperature CO2 electroreduction\u201d. ioChem-BD https:\/\/doi.org\/10.19061\/iochem-bd-1-314 (2024).","DOI":"10.19061\/iochem-bd-1-314"}],"container-title":["Nature"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41586-025-08978-0.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41586-025-08978-0","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41586-025-08978-0.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,28]],"date-time":"2025-05-28T12:01:52Z","timestamp":1748433712000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41586-025-08978-0"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,14]]},"references-count":54,"journal-issue":{"issue":"8065","published-print":{"date-parts":[[2025,5,29]]}},"alternative-id":["8978"],"URL":"https:\/\/doi.org\/10.1038\/s41586-025-08978-0","relation":{},"ISSN":["0028-0836","1476-4687"],"issn-type":[{"value":"0028-0836","type":"print"},{"value":"1476-4687","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,14]]},"assertion":[{"value":"14 August 2023","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"3 April 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"14 May 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"W.M. and X.H. are inventors on a European patent application (PCT\/EP2024\/069715) that includes the catalyst described in this work. The other authors declare no competing interests.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}]}}