{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,5]],"date-time":"2026-07-05T19:16:47Z","timestamp":1783279007453,"version":"3.54.6"},"reference-count":21,"publisher":"Royal Society of Chemistry (RSC)","issue":"4","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Org. Biomol. Chem."],"DOI":"10.1039\/b414593c","type":"journal-article","created":{"date-parts":[[2005,1,10]],"date-time":"2005-01-10T05:45:40Z","timestamp":1105335940000},"page":"597-602","source":"Crossref","is-referenced-by-count":13,"title":["Kinetics of hydrolysis of 4-methoxyphenyl-2,2-dichloroethanoate in binary water\u2013cosolvent mixtures; the role of solvent activity and solute\u2013solute interactions"],"prefix":"10.1039","volume":"3","author":[{"given":"Theo","family":"Rispens","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Celia","family":"Cabaleiro-Lago","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan B. F. N.","family":"Engberts","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2005]]},"reference":[{"key":"B414593C-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1787","DOI":"10.1016\/0040-4039(78)80044-6","author":"Karzijn","year":"1978","journal-title":"Tetrahedron Lett."},{"key":"B414593C-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"886","DOI":"10.1002\/(SICI)1096-987X(199906)20:8<886::AID-JCC13>3.0.CO;2-J","volume":"20","author":"Lensink","year":"1999","journal-title":"J. Comput. Chem."},{"key":"B414593C-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6022","DOI":"10.1021\/j100307a041","volume":"91","author":"Blokzijl","year":"1987","journal-title":"J. Phys. Chem."},{"key":"B414593C-(cit4)\/*[position()=1]","first-page":"45","author":"Blandamer","year":"1986","journal-title":"Annu. Rep. Prog. Chem., Sect. C"},{"key":"B414593C-(cit5a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"841","DOI":"10.1002\/(SICI)1099-1395(199812)11:12<841::AID-POC100>3.0.CO;2-O","volume":"11","author":"Engberts","year":"1998","journal-title":"J. Phys. Org. Chem."},{"key":"B414593C-(cit5b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1701","DOI":"10.1039\/b104537g","author":"Engberts","year":"2001","journal-title":"Chem. Commun."},{"key":"B414593C-(cit5c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2809","DOI":"10.1039\/b305672d","volume":"1","author":"Otto","year":"2003","journal-title":"Org. Biomol. Chem."},{"key":"B414593C-(cit6)\/*[position()=1]","volume-title":"Chemical Thermodynamics","author":"Prigogine","year":"1952","unstructured":"I. Prigogine and R.Defay, Chemical Thermodynamics, transl. D. H. Everett, Longmans Green, London, 1952, ch. 21"},{"key":"B414593C-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1155","DOI":"10.1016\/0021-9614(87)90053-X","volume":"19","author":"French","year":"1987","journal-title":"J. Chem. Thermodyn."},{"key":"B414593C-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1051\/jcp\/1973700072","volume":"70","author":"Treiner","year":"1973","journal-title":"J. Chim. Phys.-Chim. Biol."},{"key":"B414593C-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1231","DOI":"10.1021\/ja00811a051","volume":"96","author":"Engbersen","year":"1974","journal-title":"J. Am. Chem. Soc."},{"key":"B414593C-(cit10)\/*[position()=1]","volume-title":"The Theory of Rate Processes","author":"Glasstone","year":"1941","unstructured":"S. Glasstone , K. J.Laidler and H.Eyring, The Theory of Rate Processes, McGraw-Hill, New York, 1941"},{"key":"B414593C-(cit11a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"753","DOI":"10.1039\/P29940000753","author":"Bentley","year":"1994","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"B414593C-(cit11b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2377","DOI":"10.1039\/P29960002377","author":"Bentley","year":"1996","journal-title":"J. Chem. Soc., Perkin Trans. 2"},{"key":"B414593C-(cit12)\/*[position()=1]","unstructured":"It is assumed that the volume fraction scales linearly with the molar concentration of water, which is in general true within a few percent"},{"key":"B414593C-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7481","DOI":"10.1021\/ja01054a043","volume":"91","author":"Fife","year":"1969","journal-title":"J. Am. Chem. Soc."},{"key":"B414593C-(cit16a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"856","DOI":"10.1021\/je00020a026","volume":"40","author":"Aminabhavi","year":"1995","journal-title":"J. Chem. Eng. Data"},{"key":"B414593C-(cit16b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"233","DOI":"10.1016\/S0378-3812(98)00369-0","volume":"149","author":"Kirnincic","year":"1998","journal-title":"Fluid Phase Equilib."},{"key":"B414593C-(cit16c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"856","DOI":"10.1139\/v77-119","volume":"55","author":"de Visser","year":"1977","journal-title":"Can. J. Chem."},{"key":"B414593C-(cit16d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"791","DOI":"10.1007\/BF00646798","volume":"9","author":"Benson","year":"1980","journal-title":"J. Solution Chem."},{"key":"B414593C-(cit16e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1289","DOI":"10.1023\/A:1021743907228","volume":"28","author":"Hovorka","year":"1999","journal-title":"J. Solution Chem."}],"container-title":["Org. Biomol. Chem."],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2005\/OB\/B414593C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,5]],"date-time":"2026-07-05T18:16:16Z","timestamp":1783275376000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ob\/article\/3\/4\/597-602\/160787"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005]]},"references-count":21,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2005]]}},"URL":"https:\/\/doi.org\/10.1039\/b414593c","relation":{},"ISSN":["1477-0520","1477-0539"],"issn-type":[{"value":"1477-0520","type":"print"},{"value":"1477-0539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005]]}}}