{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T03:54:14Z","timestamp":1782964454652,"version":"3.54.5"},"reference-count":30,"publisher":"Royal Society of Chemistry (RSC)","issue":"8","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chem. 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Schmidbaur , Gold: Progress in Chemistry, Biochemistry and Technology, John Wiley & Sons, Chichester, 1999"},{"key":"B416472E-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","DOI":"10.1002\/9783527616077","volume-title":"Clusters and Colloids","author":"Schmid","year":"1994","unstructured":"G. Schmid , Clusters and Colloids, VCH, Weinheim, 1994"},{"key":"B416472E-(cit1c)\/*[position()=1]","doi-asserted-by":"crossref","DOI":"10.1002\/9783527618316","volume-title":"Metal Clusters in Chemistry","author":"Braunstein","year":"1999","unstructured":"P. Braunstein , L. A.Oro and P. R.Raithby, Metal Clusters in Chemistry, Wiley-VCH, Weinheim, 1999"},{"key":"B416472E-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"391","DOI":"10.1039\/cs9952400391","volume":"24","author":"Schmidbaur","year":"1995","journal-title":"Chem. Soc. Rev."},{"key":"B416472E-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1039\/a804249g","volume":"28","author":"Yam","year":"1999","journal-title":"Chem. Soc. Rev."},{"key":"B416472E-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1007\/BF03214710","volume":"23","author":"Schmidbaur","year":"1990","journal-title":"Gold Bull."},{"key":"B416472E-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"691","DOI":"10.1351\/pac199365040691","volume":"65","author":"Schmidbaur","year":"1993","journal-title":"Pure Appl. Chem."},{"key":"B416472E-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1039\/c39840000248","author":"Briant","year":"1984","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"B416472E-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1039\/c39810000201","author":"Briant","year":"1981","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"B416472E-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/0022-328X(94)00004-V","volume":"488","author":"Str\u00e4hle","year":"1995","journal-title":"J. Organomet. Chem."},{"key":"B416472E-(cit6a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2037","DOI":"10.1002\/cber.19931260912","volume":"126","author":"Beruda","year":"1993","journal-title":"Chem. Ber."},{"key":"B416472E-(cit6b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4969","DOI":"10.1021\/om00011a001","volume":"14","author":"Schmidbaur","year":"1995","journal-title":"Organometallics"},{"key":"B416472E-(cit6c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"817","DOI":"10.1002\/cber.19951280813","volume":"128","author":"Angermaier","year":"1995","journal-title":"Chem. Ber."},{"key":"B416472E-(cit6d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"222","DOI":"10.1002\/cber.19971300118","volume":"130","author":"Gabba\u00ef","year":"1997","journal-title":"Chem. Ber."},{"key":"B416472E-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"979","DOI":"10.1021\/ic00032a011","volume":"31","author":"Chapman","year":"1992","journal-title":"Inorg. Chem."},{"key":"B416472E-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1501","DOI":"10.1002\/anie.200250698","volume":"42","author":"Hagen","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"B416472E-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1748","DOI":"10.1002\/cber.19771100519","volume":"110","author":"Schmidbaur","year":"1977","journal-title":"Chem. Ber."},{"key":"B416472E-(cit10)\/*[position()=1]","unstructured":"A sample of 1a (124.3 mg, 0.20 mmol) was added to a dichloromethane solution (20 mL) of [(Et3P)AuCl] (70.1 mg, 0.20 mmol) at room temperature. After stirring for 1 h the solvent was removed and the mixture was washed with water. The remaining solid was dried under vacuum and yellow crystals of 2 (106.5 mg, 71%) were obtained by slow diffusion of hexane into a dichloromethane solution of the reaction product. Anal. Calcd. for C54H162Au3B33N3P3Sn3 (2250.6): 28.82 C, 7.26 H, 1.87 N, found: 28.65 C, 8.08 H, 2.04 N. 11B NMR (64 MHz, CD2Cl2) \u03b4 \u221214.2 (B2\u2013B11), \u22126.8 (B12). 31P {1H} NMR (202 MHz, CD2Cl2, 293 K) \u03b4 50.8 (s, 2J119\/117Sn\u201331P = 232.8 Hz); (193 K) \u03b4 51.2 (s, 2J {119\/117Sn\u201331P = 55.2 Hz; 119\/117Sn\u201331P = 286.7 Hz}), 52.6 (s, 2J {119\/117Sn\u201331P = 311.6 Hz}). X-ray crystal structure analysis of 2: crystal data for C54H162Au3B33N3P3Sn3\u00b7CH2Cl2, M = 2335.40, triclinic, space group P1\u0304 (No. 2), a = 1568.5(1), b = 1671.4(1), c = 2181.3(2) pm, \u03b1 = 100.47(1), \u03b2 = 97.73(1), \u03b3 = 116.27(1)\u00b0, V = 4.8901(7) nm3, \u03c1calc = 1.586 g cm\u22123, \u03bc = 5.375 mm\u22121, Z = 2, \u03bb = 71.073 pm, T = 120 K, 61516 reflections collected, 18924 independent (Rint = 0.097) and 11114 observed reflections [I > 2\u03c3(I)], 923 refined parameters, R1 = 0.041, wR2 = 0.080, all data R1 = 0.085, wR2 = 0.089. CCDC 253768. See http:\/\/www.rsc.org\/suppdata\/cc\/b4\/b416472e\/ for crystallographic data in .cif or other electronic format"},{"key":"B416472E-(cit11a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5699","DOI":"10.1021\/ic970725c","volume":"36","author":"Gabbai","year":"1997","journal-title":"Inorg. Chem."},{"key":"B416472E-(cit11b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3855","DOI":"10.1021\/ic00119a003","volume":"34","author":"Gabbai","year":"1995","journal-title":"Inorg. Chem."},{"key":"B416472E-(cit12)\/*[position()=1]","unstructured":"A sample of 1b (129.9 mg, 0.20 mmol) was added to a dichloromethane solution (20 mL) of [(dppm)Au2Cl2] (84.9 mg, 0.10 mmol) at room temperature. After stirring for 1 h the solvent was removed and the mixture was washed with water. The remaining solid was dried under vacuum and yellow crystals of 3 (131 mg, 39%) were obtained by slow diffusion of hexane into a dichloromethane solution of the reaction product. Anal. Calcd. for C102H208Au4B44N4P4Sn4 (3353.1): 36.54 C, 6.25 H, 1.67 N, found: 36.15 C, 6.23 H, 1.52 N. Crystal data for C102H208Au4B44N4P4Sn4, M = 3352.87, triclinic, space group P1\u0304 (No. 2), a = 1559.3(1), b = 1558.9(1), c = 1748.4(2) pm, \u03b1 = 68.08(1), \u03b2 = 64.03(1), \u03b3 = 74.25(1)\u00b0, V = 3.5147(5) nm3, \u03c1calc = 1.584 g cm\u22123, \u03bc = 4.944 mm\u22121, Z = 1, \u03bb = 71.073 pm, T = 160 K, 54953 reflections collected, 15436 independent (Rint = 0.067) and 9957 observed reflections [I > 2\u03c3(I)], 593 refined parameters, R1 = 0.044, wR2 = 0.098, all data R1 = 0.075, wR2 = 0.106. CCDC 253769. See http:\/\/www.rsc.org\/suppdata\/cc\/b4\/b416472e\/ for crystallographic data in .cif or other electronic format"},{"key":"B416472E-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4053","DOI":"10.1021\/ja00793a040","volume":"95","author":"Marisch","year":"1973","journal-title":"J. Am. Chem. 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