{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T04:52:46Z","timestamp":1782967966850,"version":"3.54.5"},"reference-count":26,"publisher":"Royal Society of Chemistry (RSC)","issue":"48","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Phys. Chem. Chem. Phys."],"DOI":"10.1039\/b612351a","type":"journal-article","created":{"date-parts":[[2006,11,24]],"date-time":"2006-11-24T06:59:10Z","timestamp":1164351550000},"page":"5643-5652","source":"Crossref","is-referenced-by-count":6,"title":["Energy transfer in thermal and hyperthermal collisions between CN(X\n                    <sup>2<\/sup>\n                    \u03a3\n                    <sup>+<\/sup>\n                    , v = 2) in selected rotational levels (N\n                    <sub>i<\/sub>\n                    = 0, 1, 6, 10, 15 and 20) and N\n                    <sub>2<\/sub>"],"prefix":"10.1039","volume":"8","author":[{"given":"Rouslan V.","family":"Olkhov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ian W. M.","family":"Smith","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2006]]},"reference":[{"key":"B612351A-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1994","DOI":"10.1063\/1.455097","volume":"89","author":"Farrow","year":"1988","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/0301-0104(89)80105-3","volume":"133","author":"Arnold","year":"1989","journal-title":"Chem. Phys."},{"key":"B612351A-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5123","DOI":"10.1063\/1.462754","volume":"96","author":"Yang","year":"1992","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9676","DOI":"10.1063\/1.469983","volume":"103","author":"Islam","year":"1995","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit4)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3882","DOI":"10.1063\/1.476517","volume":"109","author":"James","year":"1998","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4671","DOI":"10.1063\/1.1780163","volume":"121","author":"Carty","year":"2004","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3219","DOI":"10.1039\/a805898i","volume":"94","author":"Henton","year":"1998","journal-title":"J. Chem. Soc., Faraday Trans."},{"key":"B612351A-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8442","DOI":"10.1021\/jp0204859","volume":"106","author":"Hickson","year":"2002","journal-title":"J. Phys. Chem. A"},{"key":"B612351A-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5613","DOI":"10.1039\/B207549K","volume":"4","author":"Hickson","year":"2002","journal-title":"Phys. Chem. Chem. Phys."},{"key":"B612351A-(cit8a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1190","DOI":"10.1063\/1.466649","volume":"100","author":"Fei","year":"1994","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit8b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"546","DOI":"10.1016\/0009-2614(94)01356-Z","volume":"232","author":"Fei","year":"1995","journal-title":"Chem. Phys. Lett."},{"key":"B612351A-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1016\/S0009-2614(03)00438-X","volume":"372","author":"Hickson","year":"2003","journal-title":"Chem. Phys. Lett."},{"key":"B612351A-(cit10a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"791","DOI":"10.1002\/kin.550240904","volume":"24","author":"Herbert","year":"1992","journal-title":"Int. J. Chem. Kinet."},{"key":"B612351A-(cit10b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"461","DOI":"10.1016\/0009-2614(93)87091-G","volume":"211","author":"Sims","year":"1993","journal-title":"Chem. Phys. Lett."},{"key":"B612351A-(cit11)\/*[position()=1]","unstructured":"We have made preliminary measurements of the rate of vibrational relaxation of CN(v = 2) in collisions with N2 by measuring decays of the LIF signals from CN(v = 2) in much higher pressures of N2 (ca. 8 Torr), and at longer delays, than in the experiments reported here. These show that the rate coefficient for the vibrational relaxation of rotationally relaxed CN(v = 2) is \u22645 \u00d7 10\u221213 cm3 molecule\u22121 s\u22121; that is, insignificant compared to the rate coefficients for rotational energy transfer reported in the present paper"},{"key":"B612351A-(cit12a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6735","DOI":"10.1063\/1.480041","volume":"111","author":"Costen","year":"1999","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit12b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3885","DOI":"10.1063\/1.448879","volume":"82","author":"Nadler","year":"1985","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit13a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2088","DOI":"10.1063\/1.445996","volume":"79","author":"Nadler","year":"1983","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit13b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"553","DOI":"10.1063\/1.447746","volume":"81","author":"Nadler","year":"1984","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2608","DOI":"10.1063\/1.448311","volume":"82","author":"Nadler","year":"1985","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit15a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1393","DOI":"10.1039\/f29787401393","volume":"74","author":"Dickinson","year":"1978","journal-title":"J. Chem. Soc., Faraday Trans. 2"},{"key":"B612351A-(cit15b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/0022-2860(79)80265-3","volume":"51","author":"Bak","year":"1979","journal-title":"J. Mol. Struct."},{"key":"B612351A-(cit16)\/*[position()=1]","unstructured":"In ref. 9, Hickson et al. carried out a similar calculation. However, they assumed (incorrectly) that the photodissociation, even for low N levels, is dominated by the channel producing I atoms in the lower 2P3\/2 spin\u2013orbit level. Consequently, this led them to overestimate the translational speed of the CN radicals produced in low Ni levels by photodissociation of ICN at 266 nm"},{"key":"B612351A-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"910","DOI":"10.1016\/j.saa.2005.10.050","volume":"63","author":"Algappan","year":"2006","journal-title":"Spectrochim. Acta, Part A"},{"key":"B612351A-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3617","DOI":"10.1063\/1.1446033","volume":"116","author":"Brunet","year":"2002","journal-title":"J. Chem. Phys."},{"key":"B612351A-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"467","DOI":"10.1016\/0301-0104(74)85014-7","volume":"4","author":"Rubinson","year":"1974","journal-title":"Chem. Phys."}],"container-title":["Phys. Chem. Chem. Phys."],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2006\/CP\/B612351A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T03:48:01Z","timestamp":1782964081000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cp\/article\/8\/48\/5643-5652\/95949"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006]]},"references-count":26,"journal-issue":{"issue":"48","published-print":{"date-parts":[[2006]]}},"URL":"https:\/\/doi.org\/10.1039\/b612351a","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006]]}}}