{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T10:09:01Z","timestamp":1790417341232,"version":"4.1.0"},"reference-count":23,"publisher":"Springer Science and Business Media LLC","issue":"5","license":[{"start":{"date-parts":[[2013,5,1]],"date-time":"2013-05-01T00:00:00Z","timestamp":1367366400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"},{"start":{"date-parts":[[2013,5,1]],"date-time":"2013-05-01T00:00:00Z","timestamp":1367366400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/www.springer.com\/tdm"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Photochem Photobiol Sci"],"published-print":{"date-parts":[[2013,5]]},"DOI":"10.1039\/c2pp25358e","type":"journal-article","created":{"date-parts":[[2012,11,26]],"date-time":"2012-11-26T14:00:50Z","timestamp":1353938450000},"page":"751-759","update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Photoassisted defluorination of fluorinated substrates and pharmaceuticals by a wide bandgap metal oxide in aqueous media"],"prefix":"10.1007","volume":"12","author":[{"given":"Hisao","family":"Hidaka","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tohru","family":"Tsukamoto","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Toshiyuki","family":"Oyama","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoshihiro","family":"Mitsutsuka","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takeji","family":"Takamura","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nick","family":"Serpone","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"297","published-online":{"date-parts":[[2013,5,1]]},"reference":[{"issue":"8","key":"120506_CR1","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1021\/cen-v086n008.p013","volume":"86","author":"B Halford","year":"2008","unstructured":"B. Halford, Pharmaceuticals have been finding their way into our environment for a long time, but just what are they doing there?, Chem. Eng. News, 2008, 86, (8), 13\u201317 See http:\/\/pubs.acs.org\/subscribe\/journals\/cen\/86\/i08\/toc\/toc_i08.html.","journal-title":"Chem. Eng. News"},{"key":"120506_CR2","doi-asserted-by":"publisher","first-page":"1049","DOI":"10.1021\/es0517419","volume":"40","author":"H Hori","year":"2006","unstructured":"H. Hori, Y. Yamamoto, A. Sato, N. Yamashita, S. Taniyasu, S. Kutsuna, Efficient decomposition of environmentally persistent perfluorooctanesulfonate and related fluorochemicals using zerovalent iron in subcritical water, Environ. Sci. Technol., 2006, 40, 1049\u20131054.","journal-title":"Environ. Sci. Technol."},{"key":"120506_CR3","doi-asserted-by":"publisher","first-page":"785","DOI":"10.1016\/j.chemosphere.2006.10.023","volume":"67","author":"R Dillert","year":"2007","unstructured":"R. Dillert, D. Bahnemann, H. Hidaka, Light-induced degradation of perfluorocarboxylic acids in the presence of titanium dioxide, Chemosphere, 2007, 67, 785\u2013792.","journal-title":"Chemosphere"},{"key":"120506_CR4","doi-asserted-by":"publisher","first-page":"51","DOI":"10.1016\/j.cej.2006.07.016","volume":"128","author":"K Selvam","year":"2007","unstructured":"K. Selvam, M. Muruganandham, I. Muthuvel, M. Swaminathan, The influence of inorganic oxidants and metal ions on semiconductor sensitized photodegradation of 4-fluorophenol, Chem. Eng. J., 2007, 128, 51\u201357.","journal-title":"Chem. Eng. J."},{"key":"120506_CR5","doi-asserted-by":"publisher","first-page":"1204","DOI":"10.1016\/j.jfluchem.2006.06.009","volume":"127","author":"L Ravichandra","year":"2006","unstructured":"L. Ravichandra, K. Selvam, M. Muruganandham, M. Swaminathan, Photocatalytic cleavage of C\u2013F bond in pentafluorobenzoic acid with titanium dioxide-P25, J. Fluorine Chem., 2006, 127, 1204\u20131210.","journal-title":"J. Fluorine Chem."},{"key":"120506_CR6","doi-asserted-by":"publisher","first-page":"676","DOI":"10.1063\/1.1731237","volume":"33","author":"S Geller","year":"1960","unstructured":"S. Geller, Crystal structure of \u03b2-Ga2O3, J. Chem. Phys., 1960, 33, 676\u2013685.","journal-title":"J. Chem. Phys."},{"key":"120506_CR7","doi-asserted-by":"publisher","first-page":"1184","DOI":"10.1016\/j.catcom.2009.01.017","volume":"10","author":"B Zhao","year":"2009","unstructured":"B. Zhao, P. Zhang, Photocatalytic decomposition of perfluorooctanoic acid with \u03b2-Ga2O3 wide bandgap photocatalyst, Catal. Commun., 2009, 10, 1184\u20131187.","journal-title":"Catal. Commun."},{"key":"120506_CR8","doi-asserted-by":"publisher","first-page":"543","DOI":"10.2138\/am-2000-0416","volume":"85","author":"Y Xu","year":"2000","unstructured":"Y. Xu, M. A. A. Schoonen, The absolute energy positions of conduction and valence bands of selected semiconducting minerals, Am. Mineral., 2000, 85, 543\u2013556.","journal-title":"Am. Mineral."},{"key":"120506_CR9","first-page":"122","volume":"164","author":"L L Basov","year":"1965","unstructured":"L. L. Basov, Yu. P. Solonitsyn, A. N. Terenin, Influence of illumination on the adsorptivity of some oxides, Dokl. Akad. Nauk SSSR, 1965, 164, 122\u2013124.","journal-title":"Dokl. Akad. Nauk SSSR"},{"key":"120506_CR10","first-page":"82","volume-title":"Uspehi Fotoniki (Advances in Photonics) LGU","author":"L L Basov","year":"1976","unstructured":"L. L. Basov, G. N. Kuzmin, I. M. Prudnikovand Yu. P. Solonitsyn, Photoadsorption processes on metal oxides, in Uspehi Fotoniki (Advances in Photonics) LGU, ed. T. H. I. Vilesov, Leningrad, Issue 6, 1976, pp. 82\u2013120."},{"key":"120506_CR11","doi-asserted-by":"publisher","first-page":"3666","DOI":"10.1007\/s11356-011-0665-3","volume":"19","author":"A V Emeline","year":"2012","unstructured":"A. V. Emeline, V. N. Kuznetsov, V. K. Ryabchuk, N. Serpone, On the way to the creation of next generation photoactive materials, Environ. Sci. Pollut. Res., 2012, 19, 3666\u20133675.","journal-title":"Environ. Sci. Pollut. Res."},{"key":"120506_CR12","doi-asserted-by":"publisher","first-page":"115","DOI":"10.1016\/j.jphotochem.2007.12.013","volume":"197","author":"H Hidaka","year":"2008","unstructured":"H. Hidaka, H. Honjou, T. Koike, Y. Mitsutsuka, T. Oyama, N. Serpone, Photoassisted dehalogenation and mineralization of chloro\/fluoro-benzoic acid derivatives in aqueous media, J. Photochem. Photobiol., A, 2008, 197, 115\u2013123.","journal-title":"J. Photochem. Photobiol., A"},{"key":"120506_CR13","doi-asserted-by":"publisher","first-page":"2782","DOI":"10.1016\/j.watres.2011.02.030","volume":"45","author":"F Mendez-Arriaga","year":"2011","unstructured":"F. Mendez-Arriaga, T. Otsu, T. Oyama, J. Gimenez, S. Esplugas, H. Hidaka, N. Serpone, Photooxidation of the antidepressant drug Fluoxetine (Prozac) in aqueous media by hybrid catalytic\/ozonation processes, Water Res., 2011, 45, 2782\u20132794.","journal-title":"Water Res."},{"key":"120506_CR14","doi-asserted-by":"publisher","first-page":"359","DOI":"10.1093\/mutage\/gen023","volume":"23","author":"K Misaki","year":"2008","unstructured":"K. Misaki, Y. Hisamatsu, H. Suzuki, T. Takamura-Enya, Evaluation of the mutagenicity of nitration products derived from phenalenone (1H-phenalen-1-one), Mutagenesis, 2008, 23, 359\u2013366.","journal-title":"Mutagenesis"},{"key":"120506_CR15","doi-asserted-by":"publisher","first-page":"1174","DOI":"10.1002\/asia.200700061","volume":"2","author":"T Takamura-Enya","year":"2007","unstructured":"T. Takamura-Enya, M. Kawanishi, T. Yagi, Y. Hisamatsu, Structural identification of DNA adducts derived from 3-nitrobenzanthrone, a potent carcinogen present in the atmosphere, Chem.\u2013Asian J., 2007, 2, 1174\u20131185.","journal-title":"Chem.\u2013Asian J."},{"key":"120506_CR16","doi-asserted-by":"publisher","first-page":"399","DOI":"10.1093\/mutage\/gel045","volume":"21","author":"T Takamura-Enya","year":"2006","unstructured":"T. Takamura-Enya, H. Suzuki, Y. Hisamatsu, Mutagenic activities and physicochemical properties of selected nitrobenzanthrones, Mutagenesis, 2006, 21, 399\u2013404.","journal-title":"Mutagenesis"},{"key":"120506_CR17","doi-asserted-by":"publisher","first-page":"8964","DOI":"10.1021\/la0005863","volume":"16","author":"C Minero","year":"2000","unstructured":"C. Minero, G. Marirlla, V. Maurino, D. Vione, E. Pelizzetti, Photocatalytic transformation of organic compounds in the presence of inorganic ions. 2. Competitive reactions of phenol and alcohols on a titanium dioxide-fluoride system, Langmuir, 2000, 16, 8964\u20138972.","journal-title":"Langmuir"},{"key":"120506_CR18","doi-asserted-by":"publisher","first-page":"928","DOI":"10.1021\/la00053a020","volume":"7","author":"C Minero","year":"1991","unstructured":"C. Minero, C. Aliberti, E. Pelizzetti, R. Terzian, N. Serpone, Kinetic studies in heterogeneous photocatalysis. 6. AM1 simulated sunlight photodegradation over titania in aqueous media: a first case of fluorinated aromatics and identification of intermediates, Langmuir, 1991, 7, 928\u2013936.","journal-title":"Langmuir"},{"key":"120506_CR19","unstructured":"Organic Conception Diagram: in any chemical compound, a physical property depends much on the various types of intermolecular forces between molecules. The intermolecular force consists mainly of the Van Der Waal\u2019s force, the molecular mass, the electron affinity and the polarity of the molecules. As the functional group(s) of chemical compound may differ, it has a great impact on various physical properties of the molecules. Moreover, if each of the Van Der Waals force and the electron affinity, which affect much of the properties of an organic compound, could be identified individually, the characteristics of new unknown compounds, or a mixture of such compounds, could be predicted. In the principles of the Organic Conception Diagram, the property of a compound in terms of physical chemistry is considered in such a way that the property that depends on the Van Der Waals force is called \u201corganic\u201d and the one that depends on the electron affinity is called \u201cinorganic\u201d, thus considering the property of a compound as a combination of \u201corganic\u201d and \u201cinorganic\u201d natures (the Inorganic\/Organic Balance, or IOB). When considering the factors that affect various characteristics of an organic compound having hydrocarbons in its basic structure, it can be considered that the characteristics are based on two factors: the \u201corganic nature\u201d of hydrocarbons composed of the sequence of covalent bonds of the carbon chain, and the \u201cinorganic nature\u201d from the influence of the electron affinity (ion) that exists in the substitution functional group."},{"key":"120506_CR20","unstructured":"See NIHON EMULSION COw., LTD., Formulation Design with Organic Conceptual Diagram; http:\/\/www.nihon-emulsion.co.jp"},{"key":"120506_CR21","doi-asserted-by":"publisher","first-page":"163","DOI":"10.1248\/cpb1953.2.163","volume":"2","author":"A Fujita","year":"1954","unstructured":"A. Fujita, Prediction of organic compounds by a conceptional diagram, Parm. Bull., 1954, 2, 163\u2013173.","journal-title":"Parm. Bull."},{"key":"120506_CR22","first-page":"69","volume":"6","author":"Y Kozuki","year":"2009","unstructured":"Y. Kozuki, T. Ohtsubo, A predictive solubility tool for pesticide emulsifiable concentrate formulations, J. ASTM Int., 2009, 6, 69\u201381.","journal-title":"J. ASTM Int."},{"key":"120506_CR23","doi-asserted-by":"publisher","first-page":"2226","DOI":"10.1021\/j100184a037","volume":"96","author":"H Hidaka","year":"1992","unstructured":"H. Hidaka, J. Zhao, E. Pelizzetti, N. Serpone, Photodegradation of surfactants. 8. Comparison of photocatalytic processes between anionic sodium dodecylbenzenesulfonate and cationic benzyldodecyldlmethylammonlum chloride on the TiO2, surface, J. Phys. Chem., 1992, 96, 2226\u20132230.","journal-title":"J. Phys. Chem."}],"container-title":["Photochemical &amp; Photobiological Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1039\/c2pp25358e.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/link.springer.com\/article\/10.1039\/c2pp25358e\/fulltext.html","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2013\/PP\/C2PP25358E","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/link.springer.com\/content\/pdf\/10.1039\/c2pp25358e.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,11,2]],"date-time":"2022-11-02T14:12:45Z","timestamp":1667398365000},"score":1,"resource":{"primary":{"URL":"https:\/\/link.springer.com\/10.1039\/c2pp25358e"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,5]]},"references-count":23,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2013,5]]}},"alternative-id":["120506"],"URL":"https:\/\/doi.org\/10.1039\/c2pp25358e","relation":{},"ISSN":["1474-905X","1474-9092"],"issn-type":[{"value":"1474-905X","type":"print"},{"value":"1474-9092","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,5]]},"assertion":[{"value":"26 October 2012","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"26 November 2012","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"1 May 2013","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}}]}}