{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T08:32:24Z","timestamp":1782894744328,"version":"3.54.5"},"reference-count":54,"publisher":"Royal Society of Chemistry (RSC)","issue":"44","content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<p>\n                    A straightforward synthesis of P-chiral polycyclic 7-phospha-norbornenes\n                    <italic>via<\/italic>\n                    an asymmetric Diels\u2013Alder reaction is presented.\n                  <\/p>","DOI":"10.1039\/c4cc00318g","type":"journal-article","created":{"date-parts":[[2014,3,17]],"date-time":"2014-03-17T05:32:39Z","timestamp":1395034359000},"page":"5826-5828","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["P-chiral phosphorus heterocycles: a straightforward synthesis"],"prefix":"10.1039","volume":"50","author":[{"given":"Tobias","family":"M\u00f6ller","sequence":"first","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Fakult\u00e4t f\u00fcr Chemie und Mineralogie"},{"name":"Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Wonneberger","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Fakult\u00e4t f\u00fcr Chemie und Mineralogie"},{"name":"Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nadja","family":"Kretzschmar","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Fakult\u00e4t f\u00fcr Chemie und Mineralogie"},{"name":"Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evamarie","family":"Hey-Hawkins","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Fakult\u00e4t f\u00fcr Chemie und Mineralogie"},{"name":"Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2014]]},"reference":[{"key":"C4CC00318G-(cit1a)\/*[position()=1]","volume-title":"Asymmetric Catalysis on Industrial Scale. Challenges, Approaches and Solutions","year":"2010","unstructured":"Asymmetric Catalysis on Industrial Scale. Challenges, Approaches and Solutions , ed.  H.-U. Blaser  and  H.-J. Federsel ,  Wiley-VCH ,  Weinheim , 2nd edn,  2010"},{"key":"C4CC00318G-(cit1b)\/*[position()=1]","volume-title":"Chirality in Industry II: Developments in the Commercial Manufacture and Applications of Optically Active Compounds","author":"Collins","year":"1997","unstructured":"A. N. Collins  ,  G. N.Sheldrake  and  J.Crosby ,  Chirality in Industry II: Developments in the Commercial Manufacture and Applications of Optically Active Compounds ,  Wiley-VCH ,  Weinheim ,  1997"},{"key":"C4CC00318G-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2567","DOI":"10.1021\/ja00842a058","volume":"97","author":"Knowles","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"942","DOI":"10.1002\/anie.196809422","volume":"7","author":"Horner","year":"1968","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C4CC00318G-(cit2c)\/*[position()=1]","first-page":"1445","author":"Knowles","year":"1968","journal-title":"Chem. Commun."},{"key":"C4CC00318G-(cit2d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/j.ccr.2006.05.009","volume":"251","author":"Grabulosa","year":"2007","journal-title":"Coord. Chem. Rev."},{"key":"C4CC00318G-(cit2e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.tetasy.2012.01.007","volume":"23","author":"Kolodiazhnyi","year":"2012","journal-title":"Tetrahedron: Asymmetry"},{"key":"C4CC00318G-(cit2f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7477","DOI":"10.1039\/c0cc01939a","volume":"46","author":"Harvey","year":"2010","journal-title":"Chem. Commun."},{"key":"C4CC00318G-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"16604","DOI":"10.1002\/chem.201203671","volume":"18","author":"M\u00f6ller","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"key":"C4CC00318G-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"169","DOI":"10.1021\/ar030008o","volume":"37","author":"Leung","year":"2004","journal-title":"Acc. Chem. Res."},{"key":"C4CC00318G-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4933","DOI":"10.1016\/j.jorganchem.2005.08.009","volume":"690","author":"Loh","year":"2005","journal-title":"J. Organomet. Chem."},{"key":"C4CC00318G-(cit4c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3083","DOI":"10.1016\/j.jorganchem.2006.03.024","volume":"691","author":"Pullarkat","year":"2006","journal-title":"J. Organomet. Chem."},{"key":"C4CC00318G-(cit4d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6254","DOI":"10.1021\/om900586q","volume":"28","author":"Liu","year":"2009","journal-title":"Organometallics"},{"key":"C4CC00318G-(cit4e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11394","DOI":"10.1021\/ic9014543","volume":"48","author":"Liu","year":"2009","journal-title":"Inorg. Chem."},{"key":"C4CC00318G-(cit4f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5422","DOI":"10.1021\/jo025713+","volume":"67","author":"Mattmann","year":"2002","journal-title":"J. Org. Chem."},{"key":"C4CC00318G-(cit5a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6871","DOI":"10.1021\/ja00361a022","volume":"105","author":"Charrier","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit5b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1016\/S0040-4039(00)86875-6","volume":"23","author":"de Lauzon","year":"1982","journal-title":"Tetrahedron Lett."},{"key":"C4CC00318G-(cit5c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1016\/0022-328X(93)83419-V","volume":"463","author":"Brunet","year":"1993","journal-title":"J. Organomet. Chem."},{"key":"C4CC00318G-(cit6a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/j.mencom.2013.05.001","volume":"23","author":"Zagidullin","year":"2013","journal-title":"Mendeleev Commun."},{"key":"C4CC00318G-(cit6b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"43","DOI":"10.2174\/138527206775192997","volume":"10","author":"Quin","year":"2006","journal-title":"Curr. Org. Chem."},{"key":"C4CC00318G-(cit6c)\/*[position()=1]","volume-title":"Phosphorus-Carbon Heterocyclic Chemistry","author":"Quin","year":"2001","unstructured":"L. D. Quin   and  G. S.Quin , in  Phosphorus-Carbon Heterocyclic Chemistry , ed.  F. Mathey ,  Elsevier Science Ltd ,  Oxford ,  2001 ,  pp. 307\u2013362"},{"key":"C4CC00318G-(cit6d)\/*[position()=1]","volume-title":"Phosphorus-Carbon Heterocyclic Chemistry","author":"Quin","year":"2001","unstructured":"L. D. Quin  , in  Phosphorus-Carbon Heterocyclic Chemistry , ed.  F. Mathey ,  Elsevier Science Ltd ,  Oxford ,  2001 ,  pp. 219\u2013305"},{"key":"C4CC00318G-(cit6e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1080\/10426509408037448","volume":"87","author":"Mathey","year":"1994","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"C4CC00318G-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1229","DOI":"10.1021\/cr990321x","volume":"101","author":"Nyul\u00e1szi","year":"2001","journal-title":"Chem. Rev."},{"key":"C4CC00318G-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"754","DOI":"10.1002\/hc.20364","volume":"18","author":"Chesnut","year":"2007","journal-title":"Heteroat. Chem."},{"key":"C4CC00318G-(cit8a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1208","DOI":"10.1021\/jo0108156","volume":"67","author":"Mattmann","year":"2002","journal-title":"J. Org. Chem."},{"key":"C4CC00318G-(cit8b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"755","DOI":"10.1021\/jo001096i","volume":"66","author":"Mattmann","year":"2001","journal-title":"J. Org. Chem."},{"key":"C4CC00318G-(cit9a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"667","DOI":"10.1039\/c39820000667","author":"Marinetti","year":"1982","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"C4CC00318G-(cit9b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6396","DOI":"10.1021\/ja00308a043","volume":"107","author":"Holt","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit10a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1016\/0040-4039(81)80086-X","volume":"22","author":"Mathey","year":"1981","journal-title":"Tetrahedron Lett."},{"key":"C4CC00318G-(cit10b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2427","DOI":"10.1016\/0040-4020(76)87028-7","volume":"32","author":"Kashman","year":"1976","journal-title":"Tetrahedron"},{"key":"C4CC00318G-(cit11a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"66","DOI":"10.15227\/orgsyn.080.0066","volume":"80","author":"Moradei","year":"2003","journal-title":"Org. Synth."},{"key":"C4CC00318G-(cit11b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1125","DOI":"10.1021\/jo00240a048","volume":"53","author":"Feringa","year":"1988","journal-title":"J. Org. Chem."},{"key":"C4CC00318G-(cit11c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1247","DOI":"10.1016\/S0957-4166(00)80024-5","volume":"2","author":"de Jong","year":"1991","journal-title":"Tetrahedron: Asymmetry"},{"key":"C4CC00318G-(cit12a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"926","DOI":"10.1139\/v64-135","volume":"42","author":"Tori","year":"1964","journal-title":"Can. J. Chem."},{"key":"C4CC00318G-(cit12b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"581","DOI":"10.1002\/mrc.1270020609","volume":"2","author":"Lippmaa","year":"1970","journal-title":"Org. Magn. Reson."},{"key":"C4CC00318G-(cit12c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"324","DOI":"10.1002\/mrc.1270060606","volume":"6","author":"Tori","year":"1974","journal-title":"Org. Magn. Reson."},{"key":"C4CC00318G-(cit12d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6803","DOI":"10.1021\/ja00856a033","volume":"97","author":"Olah","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit12e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"959","DOI":"10.1039\/c39800000959","author":"Quin","year":"1980","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"C4CC00318G-(cit12f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1246\/cl.1983.213","author":"Sakurai","year":"1983","journal-title":"Chem. Lett."},{"key":"C4CC00318G-(cit12g)\/*[position()=1]","volume-title":"Reviews on Heteroatom Chemistry Compounds","author":"Quin","year":"1990","unstructured":"L. D. Quin  ,  Reviews on Heteroatom Chemistry Compounds ,  MYU ,  Tokyo ,  1990 , vol. 3"},{"key":"C4CC00318G-(cit13a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1021\/ja00707a016","volume":"92","author":"Hanstein","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit13b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1039\/C0CC00601G","volume":"47","author":"Steinmann","year":"2011","journal-title":"Chem. Commun."},{"key":"C4CC00318G-(cit13c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10021","DOI":"10.1021\/j100141a021","volume":"97","author":"Holthausen","year":"1993","journal-title":"J. Phys. Chem."},{"key":"C4CC00318G-(cit13d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"783","DOI":"10.1039\/FT9908600783","volume":"86","author":"Rastelli","year":"1990","journal-title":"J. Chem. Soc., Faraday Trans."},{"key":"C4CC00318G-(cit13e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/0166-1280(87)80064-7","volume":"152","author":"Castro","year":"1987","journal-title":"THEOCHEM"},{"key":"C4CC00318G-(cit14a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1547","DOI":"10.1002\/(SICI)1521-3773(19980619)37:11<1547::AID-ANIE1547>3.0.CO;2-S","volume":"37","author":"van Eis","year":"1998","journal-title":"Angew. Chem., Int. Ed."},{"key":"C4CC00318G-(cit14b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"182","DOI":"10.1002\/(SICI)1098-1071(2000)11:3<182::AID-HC3>3.0.CO;2-X","volume":"11","author":"Gottardo","year":"2000","journal-title":"Heteroat. Chem."},{"key":"C4CC00318G-(cit14c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13978","DOI":"10.1021\/ja306902j","volume":"134","author":"Velian","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit15a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1021\/ar50001a003","volume":"1","author":"Hoffmann","year":"1968","journal-title":"Acc. Chem. Res."},{"key":"C4CC00318G-(cit15b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"779","DOI":"10.1002\/anie.198007791","volume":"19","author":"Sauer","year":"1980","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C4CC00318G-(cit16a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7021","DOI":"10.1021\/ja00335a027","volume":"106","author":"Quin","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"C4CC00318G-(cit16b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1080\/03086648508072724","volume":"25","author":"Quin","year":"1985","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"C4CC00318G-(cit16c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5831","DOI":"10.1016\/S0040-4039(00)94213-8","volume":"24","author":"Caster","year":"1983","journal-title":"Tetrahedron Lett."}],"container-title":["Chem. Commun."],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2014\/CC\/C4CC00318G","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T06:31:53Z","timestamp":1782887513000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/50\/44\/5826-5828\/426002"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014]]},"references-count":54,"journal-issue":{"issue":"44","published-print":{"date-parts":[[2014]]}},"URL":"https:\/\/doi.org\/10.1039\/c4cc00318g","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2014]]},"assertion":[{"value":"This document is CrossCheck deposited","name":"crosscheck","explanation":{"URL":"http:\/\/www.crossref.org\/crosscheck\/index.html"},"group":{"name":"crosscheck","label":"CROSSCHECK"}},{"value":"Supplementary Information","URL":"http:\/\/dx.doi.org\/10.1039\/C4CC00318G","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C4CC00318G","name":"related_data"},{"value":"The Royal Society of Chemistry has an exclusive publication licence for this journal","name":"copyright_licence","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"The accepted version of this article will be made freely available after a 12 month embargo period","name":"copyright_licence","label":"OPEN ACCESS","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"Received 14 January 2014; Accepted 16 March 2014;  Accepted Manuscript published 17 March 2014;  Advance Article published 28 March 2014;  Version of Record published 6 May 2014","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}