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The two complexes exhibited biased C\u2013S bond cleavage rates upon removing protective ligands and applied for fabricating silver sulfide nanoclusters with variable sizes.<\/p>","DOI":"10.1039\/c4dt04021j","type":"journal-article","created":{"date-parts":[[2015,1,22]],"date-time":"2015-01-22T06:03:47Z","timestamp":1421906627000},"page":"3963-3966","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Designed synthesis of size-tunable Ag\n                    <sub>2<\/sub>\n                    S nanoclusters via distinguishable C\u2013S bond cleavage reaction of alkyl- and aryl-thiolates"],"prefix":"10.1039","volume":"44","author":[{"given":"Hang-Qing","family":"Chen","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)"},{"name":"Department of Chemistry"},{"name":"Tsinghua University"},{"name":"Beijing 100084"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)"},{"name":"Department of Chemistry"},{"name":"Tsinghua University"},{"name":"Beijing 100084"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Guo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)"},{"name":"Department of Chemistry"},{"name":"Tsinghua University"},{"name":"Beijing 100084"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan-Yan","family":"Fu","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Fuzhou University"},{"name":"Fuzhou 350108"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liang","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)"},{"name":"Department of Chemistry"},{"name":"Tsinghua University"},{"name":"Beijing 100084"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2015]]},"reference":[{"key":"C4DT04021J-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/S0040-6090(99)00684-7","volume":"359","author":"Akamatsu","year":"2000","journal-title":"Thin Solid Films"},{"key":"C4DT04021J-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5685","DOI":"10.1002\/anie.200460566","volume":"43","author":"Lim","year":"2004","journal-title":"Angew. 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