{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T18:32:17Z","timestamp":1789583537266,"version":"build-2803163510"},"reference-count":88,"publisher":"Royal Society of Chemistry (RSC)","issue":"1","funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<p>\n                    Alkyl\u2013B(C\n                    <sub>6<\/sub>\n                    F\n                    <sub>5<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    boranes are markedly \u03b1-CH-acidic. Using DFT we have calculated the p\n                    <italic>K<\/italic>\n                    <sub>a<\/sub>\n                    -values of a series of examples. Typically, (C\n                    <sub>6<\/sub>\n                    F\n                    <sub>5<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    B\u2013CH\n                    <sub>3<\/sub>\n                    [p\n                    <italic>K<\/italic>\n                    <sub>a<\/sub>\n                    (calcd) = 18.3 in DMSO, 16.2 in dichloromethane] is almost as CH-acidic as cyclopentadiene.\n                  <\/p>","DOI":"10.1039\/c4sc01711k","type":"journal-article","created":{"date-parts":[[2014,9,26]],"date-time":"2014-09-26T12:30:59Z","timestamp":1411734659000},"page":"816-825","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":71,"title":["\u03b1-CH acidity of alkyl\u2013B(C\n                    <sub>6<\/sub>\n                    F\n                    <sub>5<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    compounds \u2013 the role of stabilized borata-alkene formation in frustrated Lewis pair chemistry"],"prefix":"10.1039","volume":"6","author":[{"given":"Philip","family":"Moquist","sequence":"first","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guo-Qiang","family":"Chen","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"M\u00fcck-Lichtenfeld","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kathrin","family":"Bussmann","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Constantin G.","family":"Daniliuc","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerald","family":"Kehr","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerhard","family":"Erker","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut"},{"name":"Universit\u00e4t M\u00fcnster"},{"name":"48149 M\u00fcnster"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2015]]},"reference":[{"key":"C4SC01711K-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"985","DOI":"10.1002\/anie.199309851","volume":"32","author":"Berndt","year":"1993","journal-title":"Angew. 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