{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T19:42:26Z","timestamp":1782934946407,"version":"3.54.5"},"reference-count":37,"publisher":"Royal Society of Chemistry (RSC)","issue":"26","funder":[{"DOI":"10.13039\/501100000275","name":"Leverhulme Trust","doi-asserted-by":"crossref","award":["RPG-2013-053"],"award-info":[{"award-number":["RPG-2013-053"]}],"id":[{"id":"10.13039\/501100000275","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<p>\n                    Reaction of (\n                    <sup>Ar\u2032<\/sup>\n                    NacNac)ZnI with K\/Hg gave {(\n                    <sup>Ar\u2032<\/sup>\n                    NacNac)Zn}\n                    <sub>2<\/sub>\n                    Hg (\n                    <bold>1<\/bold>\n                    ), the first example of a bond between two different Group 12 metals. DFT and QTAIM analyses suggest a formal Zn(\n                    <sc>i<\/sc>\n                    )\u2013Hg(0)\u2013Zn(\n                    <sc>i<\/sc>\n                    ) linkage;\n                    <bold>1<\/bold>\n                    reacts with I\n                    <sub>2<\/sub>\n                    , FpI or Fp\n                    <sub>2<\/sub>\n                    to give products of the type (\n                    <sup>Ar\u2032<\/sup>\n                    NacNac)ZnX (X = I or Fp; Fp = CpFe(CO)\n                    <sub>2<\/sub>\n                    ).\n                  <\/p>","DOI":"10.1039\/c5cc00637f","type":"journal-article","created":{"date-parts":[[2015,2,17]],"date-time":"2015-02-17T07:57:33Z","timestamp":1424159853000},"page":"5743-5746","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Synthesis, molecular and electronic structure, and reactions of a Zn\u2013Hg\u2013Zn bonded complex"],"prefix":"10.1039","volume":"51","author":[{"given":"Matthew P.","family":"Blake","sequence":"first","affiliation":[{"name":"Chemistry Research Laboratory"},{"name":"University of Oxford"},{"name":"Oxford OX1 3TA"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolas","family":"Kaltsoyannis","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University College London"},{"name":"Christopher Ingold Laboratories"},{"name":"London WC1H 0AJ"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philip","family":"Mountford","sequence":"additional","affiliation":[{"name":"Chemistry Research Laboratory"},{"name":"University of Oxford"},{"name":"Oxford OX1 3TA"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2015]]},"reference":[{"key":"C5CC00637F-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","DOI":"10.1007\/b136230","volume-title":"Multiple Bonds Between metal Atoms","author":"Cotton","year":"2005","unstructured":"F. A. Cotton , C. A.Murillo and R. A.Walton, Multiple Bonds Between metal Atoms, Springer, New York, 3rd edn, 2005"},{"key":"C5CC00637F-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2658","DOI":"10.1002\/1521-3773(20000804)39:15<2658::AID-ANIE2658>3.0.CO;2-C","volume":"39","author":"Gade","year":"2000","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5CC00637F-(cit1c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4329","DOI":"10.1021\/cr3000048","volume":"112","author":"Bauer","year":"2012","journal-title":"Chem. Rev."},{"key":"C5CC00637F-(cit1d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13566","DOI":"10.1002\/chem.201200783","volume":"18","author":"Oelkers","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5CC00637F-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1136","DOI":"10.1126\/science.1101356","volume":"305","author":"Resa","year":"2004","journal-title":"Science"},{"key":"C5CC00637F-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"693","DOI":"10.1021\/ja0668217","volume":"129","author":"Grirrane","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"C5CC00637F-(cit2c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11944","DOI":"10.1021\/ja053819r","volume":"127","author":"Wang","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"C5CC00637F-(cit2d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4302","DOI":"10.1002\/anie.200605251","volume":"46","author":"Fedushkin","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5CC00637F-(cit2e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1773","DOI":"10.1002\/chem.201002443","volume":"17","author":"Nayek","year":"2011","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5CC00637F-(cit2f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15105","DOI":"10.1002\/chem.201202560","volume":"18","author":"Stasch","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5CC00637F-(cit2g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1590","DOI":"10.1021\/om801155j","volume":"28","author":"Schulz","year":"2009","journal-title":"Organometallics"},{"key":"C5CC00637F-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10406","DOI":"10.1021\/ja00065a005","volume":"115","author":"Mason","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"C5CC00637F-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10847","DOI":"10.1021\/ja072682x","volume":"129","author":"Zhu","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"C5CC00637F-(cit3c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7221","DOI":"10.1039\/b917185a","author":"Zhou","year":"2009","journal-title":"Chem. Commun."},{"key":"C5CC00637F-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6526","DOI":"10.1002\/anie.200704568","volume":"47","author":"Carmona","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5CC00637F-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3759","DOI":"10.1039\/c2cs15343b","volume":"41","author":"Li","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"C5CC00637F-(cit6)\/*[position()=1]","volume-title":"Structural Inorganic Chemistry","author":"Wells","year":"1984","unstructured":"A. F. Wells , Structural Inorganic Chemistry, Oxford University Press, Oxford, 5th edn, 1984"},{"key":"C5CC00637F-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1100","DOI":"10.1002\/(SICI)1521-3773(19990419)38:8<1100::AID-ANIE1100>3.0.CO;2-N","volume":"38","author":"Bravo-Zhivotovskii","year":"1999","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5CC00637F-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"746","DOI":"10.1021\/ci960015+","volume":"36","author":"Fletcher","year":"1996","journal-title":"J. Chem. Inf. Comput. Sci."},{"key":"C5CC00637F-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1527","DOI":"10.1039\/C39890001527","author":"H\u00e4mmerle","year":"1989","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"C5CC00637F-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1090","DOI":"10.1002\/ejic.200400932","author":"Cole","year":"2005","journal-title":"Eur. J. Inorg. Chem."},{"key":"C5CC00637F-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"633","DOI":"10.1039\/DT9820000633","author":"Kergoat","year":"1982","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C5CC00637F-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1016\/j.ccr.2011.11.008","volume":"256","author":"Bollermann","year":"2012","journal-title":"Coord. Chem. Rev."},{"key":"C5CC00637F-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"772","DOI":"10.1002\/anie.201005808","volume":"50","author":"Bollermann","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5CC00637F-(cit14a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15358","DOI":"10.1021\/ja207487j","volume":"113","author":"Blake","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"C5CC00637F-(cit14b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3315","DOI":"10.1039\/c3cc41360h","volume":"49","author":"Blake","year":"2013","journal-title":"Chem. Commun."},{"key":"C5CC00637F-(cit15a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1039\/b801115j","author":"Cordero","year":"2008","journal-title":"Dalton Trans."},{"key":"C5CC00637F-(cit15b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"186","DOI":"10.1002\/chem.200800987","volume":"15","author":"Pyykk\u00f6","year":"2009","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5CC00637F-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2851","DOI":"10.1039\/DT9940002851","author":"Green","year":"1994","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C5CC00637F-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198551683.001.0001","volume-title":"Atoms in Molecules: A Quantum Theory","author":"Bader","year":"1990","unstructured":"R. F. W. Bader , Atoms in Molecules: A Quantum Theory, Oxford University Press, Oxford, 1990"},{"key":"C5CC00637F-(cit19a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi","year":"1964","journal-title":"J. Phys. Chem."},{"key":"C5CC00637F-(cit19b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8617","DOI":"10.1039\/c3dt50599e","volume":"42","author":"Alvarez","year":"2013","journal-title":"Dalton Trans."},{"key":"C5CC00637F-(cit21a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8424","DOI":"10.1002\/chem.201100774","volume":"17","author":"Vlaisavljevich","year":"2011","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5CC00637F-(cit21b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2360","DOI":"10.1021\/ic991316e","volume":"39","author":"Bianchi","year":"2000","journal-title":"Inorg. Chem."},{"key":"C5CC00637F-(cit21c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2804","DOI":"10.1002\/chem.201304125","volume":"20","author":"Butovskii","year":"2014","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5CC00637F-(cit21d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"383","DOI":"10.1016\/S0010-8545(02)00252-7","volume":"238\u2013239","author":"Macchi","year":"2003","journal-title":"Coord. Chem. Rev."},{"key":"C5CC00637F-(cit22)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1296","DOI":"10.1016\/0022-1902(63)80397-8","volume":"25","author":"King","year":"1963","journal-title":"J. Inorg. Nucl. Chem."}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2015\/CC\/C5CC00637F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:52:42Z","timestamp":1782928362000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/51\/26\/5743-5746\/466470"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015]]},"references-count":37,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2015]]}},"URL":"https:\/\/doi.org\/10.1039\/c5cc00637f","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C5CC00637F","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C5CC00637F","name":"related_data"},{"value":"The Royal Society of Chemistry has an exclusive publication licence for this journal","name":"copyright_licence","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"The accepted version of this article will be made freely available after a 12 month embargo period","name":"copyright_licence","label":"OPEN ACCESS","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 22 January 2015; Accepted 17 February 2015; Accepted Manuscript published 17 February 2015; Advance Article published 27 February 2015; Version of Record published 17 March 2015","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}