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Commun."],"abstract":"<p>\n                    The parent phosphenium ion (PH\n                    <sub>2<\/sub>\n                    <sup>+<\/sup>\n                    ), and even any phosphenium salts bearing a hydrogen (HRP\n                    <sup>+<\/sup>\n                    ), had never been observed, but can be isolated using a bulky NHC. Computational investigations show that most of the positive charge is localized at phosphorus.\n                  <\/p>","DOI":"10.1039\/c5cc05241f","type":"journal-article","created":{"date-parts":[[2015,7,8]],"date-time":"2015-07-08T07:01:20Z","timestamp":1436338880000},"page":"12732-12735","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":85,"title":["Isolation of a Lewis base stabilized parent phosphenium (PH\n                    <sub>2<\/sub>\n                    <sup>+<\/sup>\n                    ) and related species"],"prefix":"10.1039","volume":"51","author":[{"given":"Liu Leo","family":"Liu","sequence":"first","affiliation":[{"name":"UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555)"},{"name":"Department of Chemistry and Biochemistry"},{"name":"University of California, San Diego"},{"name":"La Jolla"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David A.","family":"Ruiz","sequence":"additional","affiliation":[{"name":"UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555)"},{"name":"Department of Chemistry and Biochemistry"},{"name":"University of California, San Diego"},{"name":"La Jolla"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fatme","family":"Dahcheh","sequence":"additional","affiliation":[{"name":"UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555)"},{"name":"Department of Chemistry and Biochemistry"},{"name":"University of California, San Diego"},{"name":"La Jolla"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guy","family":"Bertrand","sequence":"additional","affiliation":[{"name":"UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555)"},{"name":"Department of Chemistry and Biochemistry"},{"name":"University of California, San Diego"},{"name":"La Jolla"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2015]]},"reference":[{"key":"C5CC05241F-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2102","DOI":"10.1002\/anie.200905689","volume":"49","author":"Akta\u015f","year":"2010","journal-title":"Angew. 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