{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:42:31Z","timestamp":1785890551499,"version":"3.56.0"},"reference-count":58,"publisher":"Royal Society of Chemistry (RSC)","issue":"5","content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<p>A building set for chiral phosphorus. The principle of stereotopic face differentiation is successfully applied to a P\ue001C bond. A divergent ligand synthesis is feasible after reduction of the chiral auxiliary.<\/p>","DOI":"10.1039\/c5dt02564h","type":"journal-article","created":{"date-parts":[[2015,7,30]],"date-time":"2015-07-30T11:03:36Z","timestamp":1438254216000},"page":"1904-1917","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels\u2013Alder reactions towards ligand design and functionalisation"],"prefix":"10.1039","volume":"45","author":[{"given":"Tobias","family":"M\u00f6ller","sequence":"first","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Faculty of Chemistry and Mineralogy"},{"name":"Institute of Inorganic Chemistry"},{"name":"D-04103 Leipzig"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Wonneberger","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Faculty of Chemistry and Mineralogy"},{"name":"Institute of Inorganic Chemistry"},{"name":"D-04103 Leipzig"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menyh\u00e1rt B.","family":"S\u00e1rosi","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Faculty of Chemistry and Mineralogy"},{"name":"Institute of Inorganic Chemistry"},{"name":"D-04103 Leipzig"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Coburger","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Faculty of Chemistry and Mineralogy"},{"name":"Institute of Inorganic Chemistry"},{"name":"D-04103 Leipzig"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evamarie","family":"Hey-Hawkins","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Leipzig"},{"name":"Faculty of Chemistry and Mineralogy"},{"name":"Institute of Inorganic Chemistry"},{"name":"D-04103 Leipzig"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2016]]},"reference":[{"key":"C5DT02564H-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1021\/ar00087a006","volume":"16","author":"Knowles","year":"1983","journal-title":"Acc. Chem. Res."},{"key":"C5DT02564H-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2567","DOI":"10.1021\/ja00842a058","volume":"97","author":"Knowles","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit1c)\/*[position()=1]","first-page":"1445","author":"Knowles","year":"1968","journal-title":"Chem. Commun."},{"key":"C5DT02564H-(cit1d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5946","DOI":"10.1021\/ja00460a018","volume":"99","author":"Vineyard","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit2a)\/*[position()=1]","volume-title":"Asymmetric Synthesis \u2013 The Essentials","year":"2007","unstructured":"Asymmetric Synthesis \u2013 The Essentials, ed. M. Christmann and S. Br\u00e4se, Wiley-VCH, Weinheim, 2nd edn, 2007"},{"key":"C5DT02564H-(cit2b)\/*[position()=1]","volume-title":"Asymmetric Synthesis \u2013 More Methods and Applications","volume":"2","year":"2012","unstructured":"Asymmetric Synthesis \u2013 More Methods and Applications, ed. M. Christmann and S. Br\u00e4se, Wiley-VCH, Weinheim, vol. 2, 2012"},{"key":"C5DT02564H-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"169","DOI":"10.1007\/3-540-45731-3_7","volume":"220","author":"Guga","year":"2002","journal-title":"Top. Curr. Chem."},{"key":"C5DT02564H-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/b11148","volume":"229","author":"Crepy","year":"2003","journal-title":"Top. Curr. Chem."},{"key":"C5DT02564H-(cit3c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.tetasy.2012.01.007","volume":"23","author":"Kolodiazhnyi","year":"2012","journal-title":"Tetrahedron: Asymmetry"},{"key":"C5DT02564H-(cit3d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/j.ccr.2006.05.009","volume":"251","author":"Grabulosa","year":"2007","journal-title":"Coord. Chem. Rev."},{"key":"C5DT02564H-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1578","DOI":"10.1002\/anie.200200557","volume":"42","author":"Mathey","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5DT02564H-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"503","DOI":"10.1351\/pac199971030503","volume":"71","author":"Yoshifuji","year":"1999","journal-title":"Pure Appl. Chem."},{"key":"C5DT02564H-(cit4c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2011","DOI":"10.1351\/pac200577122011","volume":"77","author":"Yoshifuji","year":"2005","journal-title":"Pure Appl. Chem."},{"key":"C5DT02564H-(cit4d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2881","DOI":"10.1246\/bcsj.70.2881","volume":"70","author":"Yoshifuji","year":"1997","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"C5DT02564H-(cit4e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1827","DOI":"10.1080\/10426500212305","volume":"177","author":"Yoshifuji","year":"2002","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"C5DT02564H-(cit4f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1016\/S0022-328X(00)00458-7","volume":"611","author":"Yoshifuji","year":"2000","journal-title":"J. Organomet. Chem."},{"key":"C5DT02564H-(cit4g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"793","DOI":"10.1021\/om00117a040","volume":"9","author":"Marinetti","year":"1990","journal-title":"Organometallics"},{"key":"C5DT02564H-(cit4h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1021\/ar00014a006","volume":"25","author":"Mathey","year":"1992","journal-title":"Acc. Chem. Res."},{"key":"C5DT02564H-(cit4i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"855","DOI":"10.1351\/pac199163060855","volume":"63","author":"Mathey","year":"1991","journal-title":"Pure Appl. Chem."},{"key":"C5DT02564H-(cit4j)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1616","DOI":"10.1002\/ange.200200557","volume":"115","author":"Mathey","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5DT02564H-(cit4k)\/*[position()=1]","volume-title":"Multiple Bonds and Low Coordination in Phosphorus Chemistry","author":"Regitz","year":"1990","unstructured":"M.\n              Regitz\n            , O. J.Scherer and R.Appel, Multiple Bonds and Low Coordination in Phosphorus Chemistry, G. Thieme Verlag, 1990"},{"key":"C5DT02564H-(cit4l)\/*[position()=1]","volume-title":"Phosphorus: the Carbon Copy","author":"Dillon","year":"1998","unstructured":"K. B.\n              Dillon\n            , F.Mathey and J. F.Nixon, Phosphorus: the Carbon Copy, Wiley, 1998"},{"key":"C5DT02564H-(cit5a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1021\/ja00027a034","volume":"114","author":"de Vaumas","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit5b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1657","DOI":"10.1002\/1099-0682(200207)2002:7<1657::AID-EJIC1657>3.0.CO;2-W","author":"Sava","year":"2002","journal-title":"Eur. J. Inorg. Chem."},{"key":"C5DT02564H-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"16604","DOI":"10.1002\/chem.201203671","volume":"18","author":"M\u00f6ller","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"key":"C5DT02564H-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"954","DOI":"10.1021\/ar030118v","volume":"37","author":"Mathey","year":"2004","journal-title":"Acc. Chem. Res."},{"key":"C5DT02564H-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6871","DOI":"10.1021\/ja00361a022","volume":"105","author":"Charrier","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit7c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/0022-328X(84)85010-X","volume":"263","author":"Mercier","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"C5DT02564H-(cit7d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1016\/S0040-4039(00)86875-6","volume":"23","author":"de Lauzon","year":"1982","journal-title":"Tetrahedron Lett."},{"key":"C5DT02564H-(cit7e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4754","DOI":"10.1021\/jo00281a013","volume":"54","author":"le Goff","year":"1989","journal-title":"J. Org. Chem."},{"key":"C5DT02564H-(cit7f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4595","DOI":"10.1021\/ja00405a058","volume":"103","author":"Mathey","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit7g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/0022-328X(93)83346-W","volume":"462","author":"Mercier","year":"1993","journal-title":"J. Organomet. Chem."},{"key":"C5DT02564H-(cit7h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1272","DOI":"10.1039\/C39820001272","author":"de Lauzon","year":"1982","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"C5DT02564H-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1238","DOI":"10.1021\/ja00212a037","volume":"110","author":"Evans","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2835","DOI":"10.1021\/om00054a056","volume":"10","author":"Sierra","year":"1991","journal-title":"Organometallics"},{"key":"C5DT02564H-(cit10a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1125","DOI":"10.1021\/jo00240a048","volume":"53","author":"Feringa","year":"1988","journal-title":"J. Org. Chem."},{"key":"C5DT02564H-(cit10b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"719","DOI":"10.1016\/S0957-4166(00)82382-4","volume":"1","author":"Jansen","year":"1990","journal-title":"Tetrahedron: Asymmetry"},{"key":"C5DT02564H-(cit12a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1039\/C0CC00601G","volume":"47","author":"Steinmann","year":"2011","journal-title":"Chem. Commun."},{"key":"C5DT02564H-(cit12b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10021","DOI":"10.1021\/j100141a021","volume":"97","author":"Holthausen","year":"1993","journal-title":"J. Phys. Chem."},{"key":"C5DT02564H-(cit13a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3505","DOI":"10.1021\/ol006553w","volume":"2","author":"Pool","year":"2000","journal-title":"Org. Lett."},{"key":"C5DT02564H-(cit13b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5091","DOI":"10.1021\/ja025634f","volume":"124","author":"Birney","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit14a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6872","DOI":"10.1021\/ja983113f","volume":"121","author":"Nyul\u00e1szi","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit14b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9828","DOI":"10.1002\/anie.200905390","volume":"48","author":"Steinmann","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5DT02564H-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5826","DOI":"10.1039\/C4CC00318G","volume":"50","author":"M\u00f6ller","year":"2014","journal-title":"Chem. Commun."},{"key":"C5DT02564H-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"326","DOI":"10.1002\/cmr.10035","volume":"14","author":"Harris","year":"2002","journal-title":"Concepts Magn. Reson."},{"key":"C5DT02564H-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"983","DOI":"10.1055\/s-1981-29670","author":"Breque","year":"1981","journal-title":"Synthesis"},{"key":"C5DT02564H-(cit18a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1002\/anie.199700981","volume":"36","author":"Holand","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C5DT02564H-(cit18b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1002\/ange.19971090136","volume":"109","author":"Holand","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C5DT02564H-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1238","DOI":"10.1021\/ja00212a037","volume":"110","author":"Evans","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"C5DT02564H-(cit20a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5640","DOI":"10.1002\/anie.201301153","volume":"52","author":"Freitag","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5DT02564H-(cit20b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5750","DOI":"10.1002\/ange.201301153","volume":"125","author":"Freitag","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C5DT02564H-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1080\/03086648308073282","volume":"15","author":"Hinke","year":"1983","journal-title":"Phosphorus, Sulfur Relat. Elem."},{"key":"C5DT02564H-(cit22)\/*[position()=1]","first-page":"435","volume":"27","author":"Altomare","year":"1994","journal-title":"J. Appl. Crystallogr."},{"key":"C5DT02564H-(cit23)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"A64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr., Sect. A: Fundam. Crystallogr."},{"key":"C5DT02564H-(cit24)\/*[position()=1]","volume-title":"Diamond 3.2i","author":"Brandenburg","year":"2012","unstructured":"K.\n            Brandenburg\n          , Diamond 3.2i, Crystal Impact GbR, Bonn, 2012"},{"key":"C5DT02564H-(cit26a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"C5DT02564H-(cit26b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1021\/ar700111a","volume":"41","author":"Zhao","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"C5DT02564H-(cit26c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1016\/S0009-2614(99)00493-5","volume":"306","author":"Fast","year":"1999","journal-title":"Chem. Phys. Lett."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2016\/DT\/C5DT02564H","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T19:47:29Z","timestamp":1782848849000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/45\/5\/1904-1917\/477328"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016]]},"references-count":58,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2016]]}},"URL":"https:\/\/doi.org\/10.1039\/c5dt02564h","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C5DT02564H","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C5DT02564H","name":"related_data"},{"value":"The Royal Society of Chemistry has an exclusive publication licence for this journal","name":"copyright_licence","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)","URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/","name":"copyright_licence","label":"OPEN ACCESS","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 7 July 2015; Accepted 30 July 2015;  Accepted Manuscript published 30 July 2015;  Advance Article published 17 August 2015;  Version of Record published 27 January 2016","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}