{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T09:43:04Z","timestamp":1788342184509,"version":"build-2803163510"},"reference-count":82,"publisher":"Royal Society of Chemistry (RSC)","funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"crossref","award":["Discovery Grant"],"award-info":[{"award-number":["Discovery Grant"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100004261","name":"Research and Development Corporation of Newfoundland and Labrador","doi-asserted-by":"crossref","award":["Leverage R&D Fund"],"award-info":[{"award-number":["Leverage R&D Fund"]}],"id":[{"id":"10.13039\/501100004261","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Canada Foundation for Innovation","award":["JELF"],"award-info":[{"award-number":["JELF"]}]},{"DOI":"10.13039\/501100005616","name":"Memorial University of Newfoundland","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100005616","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Faraday Discuss."],"abstract":"<p>\n                    Amine-bis(phenolato)chromium(\n                    <sc>iii<\/sc>\n                    ) chloride complexes, [\n                    <bold>L<\/bold>\n                    CrCl], are capable of catalyzing the copolymerization of cyclohexene oxide with carbon dioxide to give poly(cyclohexane) carbonate. When combined with 4-(\n                    <italic>N<\/italic>\n                    ,\n                    <italic>N<\/italic>\n                    -dimethylamino)pyridine (DMAP) these catalyst systems yield low molecular weight polymers with moderately narrow polydispersities. The coordination chemistry of DMAP with five amine-bis(phenolato)chromium(\n                    <sc>iii<\/sc>\n                    ) chloride complexes was studied by matrix assisted laser desorption\/ionization time-of-flight mass spectrometry (MALDI-TOF MS). The amine-bis(phenolato) ligands were varied in the nature of their neutral pendant donor-group and include oxygen-containing tetrahydrofurfuryl and methoxyethyl moieties, or nitrogen-containing\n                    <italic>N<\/italic>\n                    ,\n                    <italic>N<\/italic>\n                    -dimethylaminoethyl or 2-pyridyl moieties. The relative abundance of mono and bis(DMAP) adducts, as well as DMAP-free ions is compared under various DMAP\u2009:\u2009Cr complex ratios. The [\n                    <bold>L<\/bold>\n                    Cr]\n                    <sup>+<\/sup>\n                    cations show the ability to bind two DMAP molecules to form six-coordinate complex ions in all cases, except when the pendant group is\n                    <italic>N<\/italic>\n                    ,\n                    <italic>N<\/italic>\n                    -dimethylaminoethyl (compound\n                    <bold>3<\/bold>\n                    ). Even in the presence of a 4\u2009:\u20091 ratio of DMAP to Cr, no ions corresponding to [\n                    <bold>L3<\/bold>\n                    Cr(DMAP)\n                    <sub>2<\/sub>\n                    ]\n                    <sup>+<\/sup>\n                    were observed for the complex containing the tertiary sp\n                    <sup>3<\/sup>\n                    -hybridized amino donor in the pendant arm. The difference in DMAP-binding ability of these compounds results in differences in catalytic activity for alternating copolymerization of CO\n                    <sub>2<\/sub>\n                    and cyclohexene oxide. Kinetic investigations by infrared spectroscopy of compounds\n                    <bold>2<\/bold>\n                    and\n                    <bold>3<\/bold>\n                    show that polycarbonate formation by\n                    <bold>3<\/bold>\n                    is twice as fast as that of compound\n                    <bold>2<\/bold>\n                    and that no initiation time is observed.\n                  <\/p>","DOI":"10.1039\/c5fd00046g","type":"journal-article","created":{"date-parts":[[2015,5,5]],"date-time":"2015-05-05T11:07:11Z","timestamp":1430824031000},"page":"31-46","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["A MALDI-TOF MS analysis study of the binding of 4-(N,N-dimethylamino)pyridine to amine-bis(phenolate) chromium(\n                    <scp>iii<\/scp>\n                    ) chloride complexes: mechanistic insight into differences in catalytic activity for CO\n                    <sub>2<\/sub>\n                    \/epoxide copolymerization"],"prefix":"10.1039","volume":"183","author":[{"given":"Christopher M.","family":"Kozak","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"Memorial University of Newfoundland"},{"name":"St. John's"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"April M.","family":"Woods","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Memorial University of Newfoundland"},{"name":"St. John's"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christina S.","family":"Bottaro","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Memorial University of Newfoundland"},{"name":"St. John's"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katalin","family":"Devaine-Pressing","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Memorial University of Newfoundland"},{"name":"St. John's"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaijie","family":"Ni","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Memorial University of Newfoundland"},{"name":"St. John's"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2015]]},"reference":[{"key":"C5FD00046G-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2388","DOI":"10.1021\/cr068363q","volume":"107","author":"Darensbourg","year":"2007","journal-title":"Chem. 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