{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T01:33:58Z","timestamp":1790386438468,"version":"4.1.0"},"reference-count":49,"publisher":"Royal Society of Chemistry (RSC)","issue":"12","funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<p>\n                    The first 4d\/4f polyphosphides were obtained from reactions of the divalent metallocenes [Cp*\n                    <sub>2<\/sub>\n                    Ln(thf)\n                    <sub>2<\/sub>\n                    ] (Ln = Sm, Yb) with [{CpMo(CO)\n                    <sub>2<\/sub>\n                    }\n                    <sub>2<\/sub>\n                    (\u03bc,\u03b7\n                    <sup>2:2<\/sup>\n                    -P\n                    <sub>2<\/sub>\n                    )] or [Cp*Mo(CO)\n                    <sub>2<\/sub>\n                    (\u03b7\n                    <sup>3<\/sup>\n                    -P\n                    <sub>3<\/sub>\n                    )]. New aggregation of the central phosphorus scaffold in combination with P\u2013P bond formation within the coordination sphere of the transition metal was observed.\n                  <\/p>","DOI":"10.1039\/c5sc02252e","type":"journal-article","created":{"date-parts":[[2015,9,29]],"date-time":"2015-09-29T04:01:02Z","timestamp":1443499262000},"page":"7179-7184","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["The approach to 4d\/4f-polyphosphides"],"prefix":"10.1039","volume":"6","author":[{"given":"Nicholas","family":"Arleth","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"Karlsruhe Institute of Technology"},{"name":"76131 Karlsruhe"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael T.","family":"Gamer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"Karlsruhe Institute of Technology"},{"name":"76131 Karlsruhe"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ralf","family":"K\u00f6ppe","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"Karlsruhe Institute of Technology"},{"name":"76131 Karlsruhe"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolay A.","family":"Pushkarevsky","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS"},{"name":"Novosibirsk State University"},{"name":"630090 Novosibirsk"},{"name":"Russia"},{"name":"Institute of Inorganic Chemistry"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey N.","family":"Konchenko","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"Karlsruhe Institute of Technology"},{"name":"76131 Karlsruhe"},{"name":"Germany"},{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Fleischmann","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"University of Regensburg"},{"name":"93040 Regensburg"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Bodensteiner","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"University of Regensburg"},{"name":"93040 Regensburg"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"University of Regensburg"},{"name":"93040 Regensburg"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter W.","family":"Roesky","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"Karlsruhe Institute of Technology"},{"name":"76131 Karlsruhe"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2015]]},"reference":[{"key":"C5SC02252E-(cit1)\/*[position()=1]","volume-title":"Comprehensive Coordination Chemistry II","author":"Downing","year":"2003","unstructured":"J. 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