{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T03:47:53Z","timestamp":1790048873334,"version":"4.0.1"},"reference-count":30,"publisher":"Royal Society of Chemistry (RSC)","issue":"24","funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21032004"],"award-info":[{"award-number":["21032004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21102080"],"award-info":[{"award-number":["21102080"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21221002"],"award-info":[{"award-number":["21221002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21290194"],"award-info":[{"award-number":["21290194"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21372138"],"award-info":[{"award-number":["21372138"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<p>\n                    Acid-promoted site- and stereo-selective bicyclization of alkynes to benzobicyclo[3.2.1]octanes was realized with atom- and step-economy. The reaction proceeded through two C\u2013C bonds formed on remote alkyl C\u2013H bonds\n                    <italic>via<\/italic>\n                    twice long-distance cationic rearrangement.\n                  <\/p>","DOI":"10.1039\/c6cc00452k","type":"journal-article","created":{"date-parts":[[2016,2,26]],"date-time":"2016-02-26T06:08:02Z","timestamp":1456466882000},"page":"4537-4540","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Acid-promoted bicyclization of arylacetylenes to benzobicyclo[3.2.1]octanes through cationic rearrangements"],"prefix":"10.1039","volume":"52","author":[{"given":"Xiang","family":"Su","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)"},{"name":"Department of Chemistry"},{"name":"Tsinghua University"},{"name":"Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihua","family":"Sun","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS)"},{"name":"CAS Key Laboratory of Photochemistry Institute of Chemistry"},{"name":"Chinese Academy of Sciences"},{"name":"Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiannian","family":"Yao","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS)"},{"name":"CAS Key Laboratory of Photochemistry Institute of Chemistry"},{"name":"Chinese Academy of Sciences"},{"name":"Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Chen","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS)"},{"name":"CAS Key Laboratory of Photochemistry Institute of Chemistry"},{"name":"Chinese Academy of Sciences"},{"name":"Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)"},{"name":"Department of Chemistry"},{"name":"Tsinghua University"},{"name":"Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2016]]},"reference":[{"key":"C6CC00452K-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"365","DOI":"10.1021\/cr950020x","volume":"96","author":"Negishi","year":"1996","journal-title":"Chem. Rev."},{"key":"C6CC00452K-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4268","DOI":"10.1002\/anie.200701589","volume":"47","author":"Michelet","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"C6CC00452K-(cit1c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3438","DOI":"10.1002\/chem.200501083","volume":"12","author":"Battiste","year":"2006","journal-title":"Chem. \u2013 Eur. J."},{"key":"C6CC00452K-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1471","DOI":"10.1126\/science.1962206","volume":"254","author":"Trost","year":"1991","journal-title":"Science"},{"key":"C6CC00452K-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1002\/anie.199502591","volume":"34","author":"Trost","year":"1995","journal-title":"Angew. Chem., Int. Ed."},{"key":"C6CC00452K-(cit2c)\/*[position()=1]","volume-title":"Organic Synthesis: Theory & Applications","author":"Wender","year":"1993","unstructured":"P. A.\n              Wender\n             and B. L.Miller, Toward the Ideal Synthesis: Connectivity Analysis and Multi-bond Forming Processes, in Organic Synthesis: Theory & Applications, ed. T. Hudlicky, JAI, Greenwich, CT, 1993, vol. 2, pp. 27\u201366"},{"key":"C6CC00452K-(cit2d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7529","DOI":"10.1016\/j.tet.2013.06.004","volume":"69","author":"Wender","year":"2013","journal-title":"Tetrahedron"},{"key":"C6CC00452K-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2654","DOI":"10.1002\/chem.200902374","volume":"16","author":"Jazzar","year":"2010","journal-title":"Chem. \u2013 Eur. J."},{"key":"C6CC00452K-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8960","DOI":"10.1002\/anie.201201666","volume":"51","author":"Yamaguchi","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"C6CC00452K-(cit3c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2022","DOI":"10.1039\/C0CS00027B","volume":"40","author":"Herrmann","year":"2011","journal-title":"Chem. Soc. Rev."},{"key":"C6CC00452K-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12180","DOI":"10.1021\/ja053337f","volume":"127","author":"Pastine","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3999","DOI":"10.1002\/anie.200900368","volume":"48","author":"Yang","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"C6CC00452K-(cit4c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5590","DOI":"10.1021\/ja101633x","volume":"132","author":"Jin","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit4d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11847","DOI":"10.1021\/ja103786c","volume":"132","author":"Kang","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit4e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2424","DOI":"10.1021\/ja110520p","volume":"133","author":"Mori","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit4f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2593","DOI":"10.1002\/anie.201208777","volume":"52","author":"Hansmann","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C6CC00452K-(cit4g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5898","DOI":"10.1021\/ol5028706","volume":"16","author":"Cai","year":"2014","journal-title":"Org. Lett."},{"key":"C6CC00452K-(cit4h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12528","DOI":"10.1021\/ja504818p","volume":"136","author":"Theunissen","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit4i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8851","DOI":"10.1021\/ja504361y","volume":"136","author":"Zhang","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit4j)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3776","DOI":"10.1021\/ol501655g","volume":"16","author":"Peng","year":"2014","journal-title":"Org. Lett."},{"key":"C6CC00452K-(cit5)\/*[position()=2]","doi-asserted-by":"crossref","first-page":"3744","DOI":"10.1021\/ja412706d","volume":"136","author":"Mori","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit6a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6905","DOI":"10.1021\/cr4001385","volume":"113","author":"Naredla","year":"2013","journal-title":"Chem. Rev."},{"key":"C6CC00452K-(cit6b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1021\/jo801682d","volume":"74","author":"Stang","year":"2009","journal-title":"J. Org. Chem."},{"key":"C6CC00452K-(cit6c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9277","DOI":"10.1021\/acs.chemrev.5b00041","volume":"115","author":"Akiyama","year":"2015","journal-title":"Chem. Rev."},{"key":"C6CC00452K-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2498","DOI":"10.1039\/c3ob00053b","volume":"11","author":"Zhang","year":"2013","journal-title":"Org. Biomol. Chem."},{"key":"C6CC00452K-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7333","DOI":"10.1021\/ja00439a600","volume":"98","author":"Olah","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC00452K-(cit11a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2224","DOI":"10.1021\/jo01299a037","volume":"45","author":"Ronald","year":"1980","journal-title":"J. Org. Chem."},{"key":"C6CC00452K-(cit11b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1021\/jo01289a015","volume":"45","author":"Selover","year":"1980","journal-title":"J. Org. Chem."},{"key":"C6CC00452K-(cit11c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4391","DOI":"10.1021\/jo952184j","volume":"61","author":"Nath","year":"1996","journal-title":"J. Org. Chem."},{"key":"C6CC00452K-(cit11d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5552","DOI":"10.1002\/anie.201400944","volume":"53","author":"Blair","year":"2014","journal-title":"Angew. Chem., Int. Ed."}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2016\/CC\/C6CC00452K","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T17:59:36Z","timestamp":1783533576000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/52\/24\/4537-4540\/512424"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016]]},"references-count":30,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2016]]}},"URL":"https:\/\/doi.org\/10.1039\/c6cc00452k","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C6CC00452K","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C6CC00452K","name":"related_data"},{"value":"The Royal Society of Chemistry has an exclusive publication licence for this journal","name":"copyright_licence","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 17 January 2016; Accepted 26 February 2016;  Accepted Manuscript published 26 February 2016;  Advance Article published 3 March 2016;  Version of Record published 15 March 2016","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}