{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T21:22:38Z","timestamp":1791840158378,"version":"4.3.4"},"reference-count":54,"publisher":"Royal Society of Chemistry (RSC)","issue":"63","funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"crossref","award":["DE-SC0006518"],"award-info":[{"award-number":["DE-SC0006518"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<p>\n                    Reactions of Ce[N(SiMe\n                    <sub>3<\/sub>\n                    )Ph\n                    <sup>F<\/sup>\n                    ]\n                    <sub>3<\/sub>\n                    (\u2013Ph\n                    <sup>F<\/sup>\n                    = pentafluorophenyl) toward small molecules of the type E\n                    <sub>1<\/sub>\n                    \ue001C\ue001E\n                    <sub>2<\/sub>\n                    (E\n                    <sub>1<\/sub>\n                    , E\n                    <sub>2<\/sub>\n                    = O, S, NR), including carbon disulfide, carbodiimide, carbon dioxide, isocyanate and isothiocyanate are reported, resulting in distinct products, including cerium(\n                    <sc>iii<\/sc>\n                    ) dithiocarbamate, cerium(\n                    <sc>iii<\/sc>\n                    ) guanidinate, isocyanates and unsymmetric carbodiimides.\n                  <\/p>","DOI":"10.1039\/c6cc03719d","type":"journal-article","created":{"date-parts":[[2016,7,8]],"date-time":"2016-07-08T07:02:30Z","timestamp":1467961350000},"page":"9813-9816","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Reactions of a cerium(\n                    <scp>iii<\/scp>\n                    ) amide with heteroallenes: insertion, silyl-migration and de-insertion"],"prefix":"10.1039","volume":"52","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2063-8605","authenticated-orcid":false,"given":"Haolin","family":"Yin","sequence":"first","affiliation":[{"name":"P. Roy and Diana T. Vagelos Laboratories"},{"name":"Department of Chemistry"},{"name":"University of Pennsylvania"},{"name":"Philadelphia"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick J.","family":"Carroll","sequence":"additional","affiliation":[{"name":"P. Roy and Diana T. Vagelos Laboratories"},{"name":"Department of Chemistry"},{"name":"University of Pennsylvania"},{"name":"Philadelphia"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric J.","family":"Schelter","sequence":"additional","affiliation":[{"name":"P. Roy and Diana T. Vagelos Laboratories"},{"name":"Department of Chemistry"},{"name":"University of Pennsylvania"},{"name":"Philadelphia"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2016]]},"reference":[{"key":"C6CC03719D-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1002\/9780470740385","volume-title":"Metal Amide Chemistry","author":"Lappert","year":"2008","unstructured":"M. F.\n            Lappert\n          , A. V.Protchenko, P. P.Power and A. L.Seeber, Metal Amide Chemistry, John Wiley & Sons, Hoboken, 2008, p. 85"},{"key":"C6CC03719D-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3795","DOI":"10.1021\/cr0306788","volume":"108","author":"M\u00fcller","year":"2008","journal-title":"Chem. Rev."},{"key":"C6CC03719D-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9637","DOI":"10.1039\/c1dt10563a","volume":"40","author":"Zhang","year":"2011","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2529","DOI":"10.1021\/om0109509","volume":"21","author":"Li","year":"2002","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"180","DOI":"10.1016\/S0022-328X(01)01478-4","volume":"647","author":"Shen","year":"2002","journal-title":"J. Organomet. Chem."},{"key":"C6CC03719D-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4529","DOI":"10.1021\/om010403n","volume":"20","author":"Evans","year":"2001","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit6a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5385","DOI":"10.1021\/om0340342","volume":"22","author":"Zhang","year":"2003","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit6b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1806","DOI":"10.1039\/b817776g","author":"Zhang","year":"2009","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit6c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4926","DOI":"10.1016\/j.jorganchem.2005.08.005","volume":"690","author":"Ma","year":"2005","journal-title":"J. Organomet. Chem."},{"key":"C6CC03719D-(cit6d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3298","DOI":"10.1039\/b813711k","author":"Zhang","year":"2009","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit6e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1016\/S0022-328X(03)00147-5","volume":"672","author":"Zhang","year":"2003","journal-title":"J. Organomet. Chem."},{"key":"C6CC03719D-(cit6f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3303","DOI":"10.1021\/om049866u","volume":"23","author":"Zhang","year":"2004","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit6g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2167","DOI":"10.1002\/ejic.200300856","author":"Zhou","year":"2004","journal-title":"Eur. J. Inorg. Chem."},{"key":"C6CC03719D-(cit6h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1934","DOI":"10.1021\/om061094+","volume":"26","author":"Pi","year":"2007","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit6i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2190","DOI":"10.1039\/b618151a","author":"Pi","year":"2007","journal-title":"Chem. Commun."},{"key":"C6CC03719D-(cit6j)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5890","DOI":"10.1039\/c3dt33069a","volume":"42","author":"Tu","year":"2013","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit6k)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5409","DOI":"10.1021\/om400698j","volume":"32","author":"Yi","year":"2013","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit6l)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9379","DOI":"10.1021\/ic701148z","volume":"46","author":"Xu","year":"2007","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit6m)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9944","DOI":"10.1002\/anie.200803581","volume":"47","author":"Cui","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"C6CC03719D-(cit6n)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5552","DOI":"10.1021\/ic800782r","volume":"47","author":"Zhang","year":"2008","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit6o)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7009","DOI":"10.1039\/c3dt32882a","volume":"42","author":"Wang","year":"2013","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1021\/ic061722f","volume":"46","author":"Zhang","year":"2006","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3916","DOI":"10.1021\/om900246b","volume":"28","author":"Han","year":"2009","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit8a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"457","DOI":"10.1021\/cr60279a002","volume":"72","author":"Ozaki","year":"1972","journal-title":"Chem. Rev."},{"key":"C6CC03719D-(cit8b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1021\/cr00046a004","volume":"81","author":"Williams","year":"1981","journal-title":"Chem. Rev."},{"key":"C6CC03719D-(cit9a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2981","DOI":"10.1021\/jo00908a038","volume":"40","author":"Ito","year":"1975","journal-title":"J. Org. Chem."},{"key":"C6CC03719D-(cit9b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5118","DOI":"10.1021\/jo00071a021","volume":"58","author":"Kiyoi","year":"1993","journal-title":"J. Org. Chem."},{"key":"C6CC03719D-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1840","DOI":"10.1039\/b204846a","author":"Mindiola","year":"2002","journal-title":"Chem. Commun."},{"key":"C6CC03719D-(cit11a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5585","DOI":"10.1021\/ja980173c","volume":"120","author":"Babcock","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC03719D-(cit11b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4437","DOI":"10.1021\/om990526w","volume":"18","author":"Babcock","year":"1999","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit12a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10912","DOI":"10.1021\/ja962281+","volume":"118","author":"Sita","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC03719D-(cit12b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1016\/j.poly.2011.06.010","volume":"32","author":"Stewart","year":"2012","journal-title":"Polyhedron"},{"key":"C6CC03719D-(cit12c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"756","DOI":"10.1021\/ja963450t","volume":"119","author":"Sita","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC03719D-(cit13a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"798","DOI":"10.1039\/C2SC21458J","volume":"4","author":"Yin","year":"2013","journal-title":"Chem. Sci."},{"key":"C6CC03719D-(cit13b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8234","DOI":"10.1021\/ic401130e","volume":"52","author":"Yin","year":"2013","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit13c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3470","DOI":"10.1039\/c4cc00448e","volume":"50","author":"Yin","year":"2014","journal-title":"Chem. Commun."},{"key":"C6CC03719D-(cit13d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5684","DOI":"10.1021\/acs.inorgchem.6b00785","volume":"55","author":"Yin","year":"2016","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit14a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3363","DOI":"10.1021\/cr970465g","volume":"97","author":"Plenio","year":"1997","journal-title":"Chem. Rev."},{"key":"C6CC03719D-(cit14b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"650","DOI":"10.1002\/cbic.200300752","volume":"5","author":"Plenio","year":"2004","journal-title":"ChemBioChem"},{"key":"C6CC03719D-(cit14c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6313","DOI":"10.1039\/C6DT00108D","volume":"45","author":"Yin","year":"2016","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9129","DOI":"10.1021\/ic501149u","volume":"53","author":"Mullane","year":"2014","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit16a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11769","DOI":"10.1039\/c1cc15179g","volume":"47","author":"Maddox","year":"2011","journal-title":"Chem. Commun."},{"key":"C6CC03719D-(cit16b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2109","DOI":"10.1039\/b303772j","author":"Cole","year":"2003","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8100","DOI":"10.1021\/ja035716j","volume":"125","author":"Ong","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC03719D-(cit18a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1333","DOI":"10.1039\/C2DT31698F","volume":"42","author":"Arnold","year":"2013","journal-title":"Dalton Trans."},{"key":"C6CC03719D-(cit18b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15454","DOI":"10.1039\/C5CC06707C","volume":"51","author":"Camp","year":"2015","journal-title":"Chem. Commun."},{"key":"C6CC03719D-(cit18c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5577","DOI":"10.1021\/om960606p","volume":"15","author":"Ciruelos","year":"1996","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit18d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1021\/om9508086","volume":"15","author":"Kloppenburg","year":"1996","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit18e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1865","DOI":"10.1021\/ic701843u","volume":"47","author":"Fullmer","year":"2008","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit18f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1416","DOI":"10.1021\/om401130q","volume":"33","author":"Whited","year":"2014","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit18g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3670","DOI":"10.1021\/acs.inorgchem.5b00305","volume":"54","author":"Whited","year":"2015","journal-title":"Inorg. Chem."},{"key":"C6CC03719D-(cit18h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9708","DOI":"10.1021\/ja2035706","volume":"133","author":"Sattler","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"C6CC03719D-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3087","DOI":"10.1021\/om00032a035","volume":"12","author":"Procopio","year":"1993","journal-title":"Organometallics"},{"key":"C6CC03719D-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1016\/S0022-328X(00)88322-9","volume":"46","author":"Sakakibara","year":"1972","journal-title":"J. Organomet. Chem."}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2016\/CC\/C6CC03719D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:08:38Z","timestamp":1782882518000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/52\/63\/9813-9816\/513258"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016]]},"references-count":54,"journal-issue":{"issue":"63","published-print":{"date-parts":[[2016]]}},"URL":"https:\/\/doi.org\/10.1039\/c6cc03719d","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C6CC03719D","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C6CC03719D","name":"related_data"},{"value":"Haolin Yin (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-2063-8605","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Haolin Yin (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/E-3493-2012","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"The Royal Society of Chemistry has an exclusive publication licence for this journal","name":"copyright_licence","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 3 May 2016; Accepted 7 July 2016;  Accepted Manuscript published 7 July 2016;  Advance Article published 15 July 2016;  Version of Record published 28 July 2016","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}