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Commun."],"abstract":"<p>\n                    Two contrasting pathways in a SnCl\n                    <sub>4<\/sub>\n                    -catalyzed reaction of geminal bis(silyl) enol derivatives with \u03b2,\u03b3-unsaturated ketoesters have been achieved by tuning the R group in the enol moiety.\n                  <\/p>","DOI":"10.1039\/c6cc04593f","type":"journal-article","created":{"date-parts":[[2016,7,19]],"date-time":"2016-07-19T05:10:23Z","timestamp":1468905023000},"page":"10137-10140","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Tunable reactivity of geminal bis(silyl) enol derivatives leading to selective exo-IEDDA or Sakurai allylation with a \u03b2,\u03b3-unsaturated ketoester"],"prefix":"10.1039","volume":"52","author":[{"given":"Zubao","family":"Gan","sequence":"first","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry"},{"name":"West China School of Pharmacy"},{"name":"Sichuan University"},{"name":"Chengdu"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwen","family":"Chu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry"},{"name":"West China School of Pharmacy"},{"name":"Sichuan University"},{"name":"Chengdu"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Hu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry"},{"name":"West China School of Pharmacy"},{"name":"Sichuan University"},{"name":"Chengdu"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhishan","family":"Su","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology"},{"name":"Ministry of Education"},{"name":"College of Chemistry"},{"name":"Sichuan University"},{"name":"Chengdu"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changwei","family":"Hu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology"},{"name":"Ministry of Education"},{"name":"College of Chemistry"},{"name":"Sichuan University"},{"name":"Chengdu"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry"},{"name":"West China School of Pharmacy"},{"name":"Sichuan University"},{"name":"Chengdu"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenlei","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry"},{"name":"West China School of Pharmacy"},{"name":"Sichuan University"},{"name":"Chengdu"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2016]]},"reference":[{"key":"C6CC04593F-(cit1a)\/*[position()=1]","first-page":"139","author":"Gao","year":"2013","journal-title":"Synlett"},{"key":"C6CC04593F-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2271","DOI":"10.1039\/c1sc00356a","volume":"2","author":"Luo","year":"2011","journal-title":"Chem. 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