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Commun."],"abstract":"<p>The traditional use of phosphorus compounds is as ligands for transition metals, however herein we synthesize Lewis acidic fluorophosphonium cation appended to a palladium complex and effect CO insertion into a Pd\u2013C bond to obtain an unprecedented metal-benzoyl derived phosphorane.<\/p>","DOI":"10.1039\/c6cc08561j","type":"journal-article","created":{"date-parts":[[2016,11,10]],"date-time":"2016-11-10T10:54:13Z","timestamp":1478775253000},"page":"13967-13970","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["A pendant phosphorus Lewis acid: route to a palladium-benzoyl derived phosphorane"],"prefix":"10.1039","volume":"52","author":[{"given":"Kelly F.","family":"Firth","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juri","family":"M\u00f6bus","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Douglas W.","family":"Stephan","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2016]]},"reference":[{"key":"C6CC08561J-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1374","DOI":"10.1126\/science.1241764","volume":"341","author":"Caputo","year":"2013","journal-title":"Science"},{"key":"C6CC08561J-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10917","DOI":"10.1073\/pnas.1407484111","volume":"111","author":"P\u00e9rez","year":"2014","journal-title":"Proc. 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