{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T18:54:27Z","timestamp":1790276067903,"version":"4.1.0"},"reference-count":25,"publisher":"Royal Society of Chemistry (RSC)","issue":"18","license":[{"start":{"date-parts":[[2019,1,30]],"date-time":"2019-01-30T00:00:00Z","timestamp":1548806400000},"content-version":"am","delay-in-days":394,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","award":["Sche 384\/32-1"],"award-info":[{"award-number":["Sche 384\/32-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<p>\n                    Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{Cp\n                    <sup>BIG<\/sup>\n                    Fe(CO)\n                    <sub>2<\/sub>\n                    }\n                    <sub>2<\/sub>\n                    (\u03bc,\u03b7\n                    <sup>1:1<\/sup>\n                    -As\n                    <sub>4<\/sub>\n                    )] (\n                    <bold>1b<\/bold>\n                    ) in comparison to its P analogues. The thermolysis leads to novel arsenic-rich compounds, whereas the photolysis of [{Cp\n                    <sup>BIG<\/sup>\n                    Fe(CO)\n                    <sub>2<\/sub>\n                    }\n                    <sub>2<\/sub>\n                    (\u03bc,\u03b7\n                    <sup>1:1<\/sup>\n                    -E\n                    <sub>4<\/sub>\n                    )] (\n                    <bold>1a<\/bold>\n                    : E = P;\n                    <bold>1b<\/bold>\n                    : E = As) exclusively results in the decarbonylation products.\n                  <\/p>","DOI":"10.1039\/c7cc09730a","type":"journal-article","created":{"date-parts":[[2018,1,30]],"date-time":"2018-01-30T10:36:49Z","timestamp":1517308609000},"page":"2244-2247","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(Cp\n                    <sup>BIG<\/sup>\n                    Fe)\n                    <sub>2<\/sub>\n                    (\u03bc,\u03b7\n                    <sup>4:4<\/sup>\n                    -E\n                    <sub>4<\/sub>\n                    )] (E = P and As)"],"prefix":"10.1039","volume":"54","author":[{"given":"S.","family":"Heinl","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"University of Regensburg"},{"name":"93053 Regensburg"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1932-6647","authenticated-orcid":false,"given":"A. 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Y. Timoshkin (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-1932-6647","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"A. Y. Timoshkin (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/B-1174-2012","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"M. Scheer (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-2182-5020","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Authors can choose between single-blind and double-blind peer review","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 20 December 2017; Accepted 29 January 2018;  Accepted Manuscript published 30 January 2018;  Advance Article published 12 February 2018;  Version of Record published 27 February 2018","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}