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The dithiocarboxylate unit of these highly flexible ligands chiefly determined the steric requirements of the imidazolium moieties, irrespective of the metal used for complexation.\n                  <\/p>","DOI":"10.1039\/c7dt01889d","type":"journal-article","created":{"date-parts":[[2017,6,23]],"date-time":"2017-06-23T05:33:51Z","timestamp":1498196031000},"page":"9036-9048","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Synthesis and complexation of superbulky imidazolium-2-dithiocarboxylate ligands"],"prefix":"10.1039","volume":"46","author":[{"given":"Tom\u00e1s F.","family":"Beltr\u00e1n","sequence":"first","affiliation":[{"name":"Laboratory of Organometallic Chemistry and Homogeneous Catalysis"},{"name":"Institut de Chimie (B6a)"},{"name":"All\u00e9e du six Ao\u00fbt 13"},{"name":"Quartier Agora"},{"name":"Universit\u00e9 de Li\u00e8ge"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guillermo","family":"Zaragoza","sequence":"additional","affiliation":[{"name":"Unidade de Difracci\u00f3n de Raios X"},{"name":"Edificio CACTUS"},{"name":"Universidade de Santiago de Compostela"},{"name":"15782 Santiago de Compostela"},{"name":"Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1134-2992","authenticated-orcid":false,"given":"Lionel","family":"Delaude","sequence":"additional","affiliation":[{"name":"Laboratory of Organometallic Chemistry and Homogeneous Catalysis"},{"name":"Institut de Chimie (B6a)"},{"name":"All\u00e9e du six Ao\u00fbt 13"},{"name":"Quartier Agora"},{"name":"Universit\u00e9 de Li\u00e8ge"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2017]]},"reference":[{"key":"C7DT01889D-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1021\/ja00001a054","volume":"113","author":"Arduengo, III","year":"1991","journal-title":"J. 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