{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T22:44:08Z","timestamp":1787697848688,"version":"build-2784847793"},"reference-count":98,"publisher":"Royal Society of Chemistry (RSC)","issue":"9","funder":[{"DOI":"10.13039\/100010127","name":"J\u00fcrgen Manchot Stiftung","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100010127","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100008131","name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100008131","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<p>\n                    A systematic, efficient route to the first heavier tetrylidyne complexes of niobium [(\u03ba\n                    <sup>3<\/sup>\n                    -tmps)(CO)\n                    <sub>2<\/sub>\n                    Nb\ue002E\u2013R] (E = Si\u2013Sn; R = aryl) starting from the carbonyl niobate (NMe\n                    <sub>4<\/sub>\n                    )[Nb(CO)\n                    <sub>4<\/sub>\n                    (\u03ba\n                    <sup>2<\/sup>\n                    -tmps)] is presented.\n                  <\/p>","DOI":"10.1039\/c7sc02708g","type":"journal-article","created":{"date-parts":[[2017,7,14]],"date-time":"2017-07-14T08:23:43Z","timestamp":1500020623000},"page":"6290-6299","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(\u03ba\n                    <sup>3<\/sup>\n                    -tmps)(CO)\n                    <sub>2<\/sub>\n                    Nb\ue002E\u2013R] (E = Si, Ge, Sn; tmps = MeSi(CH\n                    <sub>2<\/sub>\n                    PMe\n                    <sub>2<\/sub>\n                    )\n                    <sub>3<\/sub>\n                    ; R = aryl)"],"prefix":"10.1039","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6225-8977","authenticated-orcid":false,"given":"Alexander C.","family":"Filippou","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie"},{"name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn"},{"name":"53121 Bonn"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3371-0784","authenticated-orcid":false,"given":"David","family":"Hoffmann","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie"},{"name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn"},{"name":"53121 Bonn"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6489-2106","authenticated-orcid":false,"given":"Gregor","family":"Schnakenburg","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie"},{"name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn"},{"name":"53121 Bonn"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2017]]},"reference":[{"key":"C7SC02708G-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3296","DOI":"10.1002\/anie.201000837","volume":"49","author":"Filippou","year":"2010","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1122","DOI":"10.1002\/anie.201005794","volume":"50","author":"Filippou","year":"2011","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit1c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11780","DOI":"10.1021\/ja406799y","volume":"135","author":"Hayes","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit1d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"565","DOI":"10.1002\/anie.201308433","volume":"53","author":"Filippou","year":"2014","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit1e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1021\/acs.organomet.6b00095","volume":"35","author":"Fukuda","year":"2016","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit1f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3444","DOI":"10.1021\/acs.organomet.6b00670","volume":"35","author":"Yoshimoto","year":"2016","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11966","DOI":"10.1021\/ja963132u","volume":"118","author":"Simons","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"650","DOI":"10.1021\/ja992937+","volume":"122","author":"Pu","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit2c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2778","DOI":"10.1002\/1521-3773(20000804)39:15<2778::AID-ANIE2778>3.0.CO;2-2","volume":"39","author":"Filippou","year":"2000","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit2d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4503","DOI":"10.1021\/om049625m","volume":"23","author":"Filippou","year":"2004","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit2e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5979","DOI":"10.1002\/anie.200501968","volume":"44","author":"Filippou","year":"2005","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit2f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5987","DOI":"10.1002\/anie.200602061","volume":"45","author":"Filippou","year":"2006","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit2g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"813","DOI":"10.1002\/ange.201107120","volume":"124","author":"Filippou","year":"2012","journal-title":"Angew. Chem."},{"key":"C7SC02708G-(cit2h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2930","DOI":"10.1002\/anie.201107501","volume":"51","author":"Hashimoto","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"C7SC02708G-(cit2i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"748","DOI":"10.1021\/om201176n","volume":"31","author":"Filippou","year":"2012","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit2j)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1021\/om301144h","volume":"32","author":"Hicks","year":"2013","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit2k)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4232","DOI":"10.1039\/C2CC37126J","volume":"49","author":"Fukuda","year":"2013","journal-title":"Chem. Commun."},{"key":"C7SC02708G-(cit2l)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5676","DOI":"10.1002\/chem.201300017","volume":"19","author":"Filippou","year":"2013","journal-title":"Chem.\u2013Eur. J."},{"key":"C7SC02708G-(cit2n)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1530","DOI":"10.1021\/acs.organomet.7b00110","volume":"36","author":"Lebedev","year":"2017","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"445","DOI":"10.1002\/anie.200390135","volume":"42","author":"Filippou","year":"2003","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3339","DOI":"10.1021\/om030303c","volume":"22","author":"Filippou","year":"2003","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit3c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1007\/s10751-008-9821-7","volume":"185","author":"Rohde","year":"2008","journal-title":"Hyperfine Interact."},{"key":"C7SC02708G-(cit3d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11525","DOI":"10.1021\/ja406290t","volume":"135","author":"Filippou","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2243","DOI":"10.1002\/anie.200353477","volume":"43","author":"Filippou","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6512","DOI":"10.1002\/anie.200461725","volume":"43","author":"Filippou","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit4c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5799","DOI":"10.1002\/anie.200801331","volume":"47","author":"Filippou","year":"2008","journal-title":"Angew. Chem. Int. Ed."},{"key":"C7SC02708G-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"807","DOI":"10.1007\/s11172-005-0325-1","volume":"54","author":"Lalov","year":"2005","journal-title":"Russ. Chem. Bull."},{"key":"C7SC02708G-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5717","DOI":"10.1021\/om800712k","volume":"27","author":"Shinohara","year":"2008","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit7c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10864","DOI":"10.1021\/ja301547x","volume":"134","author":"Arp","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit8a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1016\/S0022-328X(00)85128-1","volume":"36","author":"Davison","year":"1972","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit8b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"C41","DOI":"10.1016\/S0022-328X(00)85584-9","volume":"233","author":"Calderazzo","year":"1982","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit8c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1021\/om00080a011","volume":"3","author":"Pfahl","year":"1984","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit8d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1989","DOI":"10.1039\/dt9850001989","author":"Calderazzo","year":"1985","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C7SC02708G-(cit8e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4166","DOI":"10.1021\/ja00037a019","volume":"114","author":"Carnahan","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit8f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6518","DOI":"10.1021\/ic980752i","volume":"37","author":"Barybin","year":"1998","journal-title":"Inorg. Chem."},{"key":"C7SC02708G-(cit8g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2688","DOI":"10.1021\/ja9738079","volume":"120","author":"Daff","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit9a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"388","DOI":"10.1021\/om00075a006","volume":"2","author":"Dewey","year":"1983","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit9b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1865","DOI":"10.1021\/ic00155a009","volume":"22","author":"Calderazzo","year":"1983","journal-title":"Inorg. Chem."},{"key":"C7SC02708G-(cit9c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1002\/9780470132593.ch49","volume-title":"Inorganic Syntheses","author":"Calderazzo","year":"1990","unstructured":"F. Calderazzo , G.Pampaloni and J. E.Ellis, Inorganic Syntheses, John Wiley & Sons, Hoboken, NJ, USA, 1990, p. 192"},{"key":"C7SC02708G-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1920","DOI":"10.1021\/om960929l","volume":"16","author":"Simons","year":"1997","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit11a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"239","DOI":"10.1016\/S0022-328X(00)86276-2","volume":"31","author":"Davison","year":"1971","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit11b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/S0022-328X(00)82701-1","volume":"233","author":"Bechthold","year":"1982","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit11c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1016\/0022-328X(84)80629-4","volume":"276","author":"Bachmann","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit11d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/0022-328X(90)85121-E","volume":"383","author":"Calderazzo","year":"1990","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1399","DOI":"10.1515\/znb-1983-1114","volume":"38","author":"Karsch","year":"1983","journal-title":"Z. Naturforsch., B: Anorg. Chem., Org. Chem."},{"key":"C7SC02708G-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"434","DOI":"10.1021\/ic50156a039","volume":"15","author":"Wrighton","year":"1976","journal-title":"Inorg. Chem."},{"key":"C7SC02708G-(cit14)\/*[position()=1]","volume-title":"Infrared and Raman Spectra of Inorganic and Coordination Compounds","author":"Nakamoto","year":"2009","unstructured":"K. Nakamoto , Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, Hoboken, 2009"},{"key":"C7SC02708G-(cit15a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1016\/0092-640X(89)90008-9","volume":"42","author":"Raghavan","year":"1989","journal-title":"At. Data Nucl. Data Tables"},{"key":"C7SC02708G-(cit15b)\/*[position()=1]","volume-title":"Nuclear Magnetic Resonance Spectroscopy","author":"Nelson","year":"2003","unstructured":"J. H. Nelson , Nuclear Magnetic Resonance Spectroscopy, Pearson Education, 2003"},{"key":"C7SC02708G-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9246","DOI":"10.1002\/chem.201403083","volume":"20","author":"Agou","year":"2014","journal-title":"Chem.\u2013Eur. J."},{"key":"C7SC02708G-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5622","DOI":"10.1021\/om020583g","volume":"21","author":"Eichler","year":"2002","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6316","DOI":"10.1021\/om200912x","volume":"30","author":"Lei","year":"2011","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit19a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1021\/om00146a007","volume":"6","author":"Arnold","year":"1987","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit19b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1518","DOI":"10.1021\/om00003a064","volume":"14","author":"Anti\u00f1olo","year":"1995","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit19c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10133","DOI":"10.1021\/ja00145a033","volume":"117","author":"Nikonov","year":"1995","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit19d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2947","DOI":"10.1002\/(SICI)1521-3765(19991001)5:10<2947::AID-CHEM2947>3.0.CO;2-Z","volume":"5","author":"Nikonov","year":"1999","journal-title":"Chem.\u2013Eur. J."},{"key":"C7SC02708G-(cit19e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1631","DOI":"10.1039\/b000089m","author":"Bakhmutov","year":"2000","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C7SC02708G-(cit19f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1917","DOI":"10.1002\/1099-0682(200009)2000:9<1917::AID-EJIC1917>3.0.CO;2-M","author":"Nikonov","year":"2000","journal-title":"Eur. J. Inorg. Chem."},{"key":"C7SC02708G-(cit19g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3037","DOI":"10.1039\/b110998g","author":"Nikonov","year":"2002","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C7SC02708G-(cit19h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1021\/ic026017v","volume":"42","author":"Nikonov","year":"2003","journal-title":"Inorg. Chem."},{"key":"C7SC02708G-(cit19i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2845","DOI":"10.1021\/om034239a","volume":"23","author":"Dorogov","year":"2004","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit19j)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"771","DOI":"10.1002\/ejic.200300134","author":"Dorogov","year":"2004","journal-title":"Eur. J. Inorg. Chem."},{"key":"C7SC02708G-(cit19k)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1021\/ic061314b","volume":"46","author":"Dorogov","year":"2007","journal-title":"Inorg. Chem."},{"key":"C7SC02708G-(cit19l)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"296","DOI":"10.1002\/chem.200700271","volume":"14","author":"Ignatov","year":"2008","journal-title":"Chem.\u2013Eur. J."},{"key":"C7SC02708G-(cit20a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1523","DOI":"10.1021\/om971001b","volume":"17","author":"Anti\u00f1olo","year":"1998","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit20b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2178","DOI":"10.1021\/om0206453","volume":"22","author":"Nikonov","year":"2003","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit21a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1016\/0022-328X(84)80195-3","volume":"267","author":"N\u00e4umann","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit21b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"345","DOI":"10.1016\/0022-328X(84)85037-8","volume":"263","author":"Skripkin","year":"1984","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit21c)\/*[position()=1]","first-page":"1136","volume":"11","author":"Skripkin","year":"1985","journal-title":"Koord. Khim."},{"key":"C7SC02708G-(cit21d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1407","DOI":"10.1039\/DT9910001407","author":"Green","year":"1991","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C7SC02708G-(cit21e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1699","DOI":"10.1039\/DT9910001699","author":"Green","year":"1991","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C7SC02708G-(cit21f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"825","DOI":"10.1002\/(SICI)1099-0682(199905)1999:5<825::AID-EJIC825>3.0.CO;2-Y","author":"Nikonov","year":"1999","journal-title":"Eur. J. Inorg. Chem."},{"key":"C7SC02708G-(cit23)\/*[position()=1]","volume-title":"Inorganic Chemistry","author":"Holleman","year":"2001","unstructured":"A. F. Holleman , E.Wiberg and N.Wiberg, Inorganic Chemistry, Academic Press, San Diego, 2001"},{"key":"C7SC02708G-(cit24a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3511","DOI":"10.1002\/chem.200401299","volume":"11","author":"Pyykk\u00f6","year":"2005","journal-title":"Chem.\u2013Eur. J."},{"key":"C7SC02708G-(cit24b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2326","DOI":"10.1021\/jp5065819","volume":"119","author":"Pyykk\u00f6","year":"2015","journal-title":"J. Phys. Chem. A"},{"key":"C7SC02708G-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5806","DOI":"10.1021\/jp8111556","volume":"113","author":"Mantina","year":"2009","journal-title":"J. Phys. Chem. A"},{"key":"C7SC02708G-(cit26)\/*[position()=1]","unstructured":"For example quantum chemical studies on the model compounds trans-[Cl(PH3)4W\ue002EPh] (E = Si\u2013Pb) at the B3LYP\/TZVPP(W,E)\/6-311G*(C,H,P,Cl) level of theory reveal that the energy required for bending the tetrylidyne ligand up to 20\u00b0 is rather small (max. 20 kJ mol\u22121) and decreases with increasing atomic number of E"},{"key":"C7SC02708G-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0022-328X(00)89415-2","volume":"77","author":"Todd","year":"1974","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit28a)\/*[position()=1]","first-page":"485","volume":"23","author":"Ireland","year":"1976","journal-title":"J. Magn. Reson."},{"key":"C7SC02708G-(cit28b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1515\/znb-1984-0310","volume":"39","author":"Rehder","year":"1984","journal-title":"Z. Naturforsch., B: Anorg. Chem., Org. Chem."},{"key":"C7SC02708G-(cit29a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/0022-328X(83)85114-6","volume":"254","author":"Puff","year":"1983","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit29b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/0022-328X(94)84050-4","volume":"474","author":"Fajar\u00ed","year":"1994","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit29c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"695","DOI":"10.1246\/cl.1996.695","volume":"25","author":"Kishikawa","year":"1996","journal-title":"Chem. Lett."},{"key":"C7SC02708G-(cit29d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5105","DOI":"10.1021\/om010548u","volume":"20","author":"Pu","year":"2001","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit29e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4835","DOI":"10.1021\/om060449m","volume":"25","author":"Matsumoto","year":"2006","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit29f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1023","DOI":"10.1021\/ja057205y","volume":"128","author":"Sugiyama","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"C7SC02708G-(cit29g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4242","DOI":"10.1002\/ejic.200800494","author":"Bonnefille","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"C7SC02708G-(cit29h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2246","DOI":"10.1016\/j.jorganchem.2009.03.005","volume":"694","author":"Bonnefille","year":"2009","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit29i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"657","DOI":"10.3987\/COM-08-11547","volume":"78","author":"Saito","year":"2009","journal-title":"Heterocycles"},{"key":"C7SC02708G-(cit29j)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1038\/nchem.1305","volume":"4","author":"Li","year":"2012","journal-title":"Nat. Chem."},{"key":"C7SC02708G-(cit29k)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"542","DOI":"10.1139\/cjc-2013-0496","volume":"92","author":"Pop","year":"2014","journal-title":"Can. J. Chem."},{"key":"C7SC02708G-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"539","DOI":"10.1080\/00945718708070217","volume":"17","author":"Rivi\u00e8re","year":"1987","journal-title":"Synth. React. Inorg. Met.-Org. Chem."},{"key":"C7SC02708G-(cit31)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1016\/S0022-328X(00)81069-4","volume":"191","author":"Herrmann","year":"1980","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit32)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/S0022-328X(97)00735-3","volume":"557","author":"Bitterwolf","year":"1998","journal-title":"J. Organomet. Chem."},{"key":"C7SC02708G-(cit33)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5602","DOI":"10.1021\/om980697l","volume":"17","author":"Pu","year":"1998","journal-title":"Organometallics"},{"key":"C7SC02708G-(cit34)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1711","DOI":"10.1039\/b010033l","author":"Childs","year":"2001","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C7SC02708G-(cit35a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6713","DOI":"10.1021\/jp991381+","volume":"103","author":"Noviandri","year":"1999","journal-title":"J. Phys. Chem. B"},{"key":"C7SC02708G-(cit35b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"288","DOI":"10.1139\/v05-262","volume":"84","author":"Aranzaes","year":"2006","journal-title":"Can. J. Chem."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2017\/SC\/C7SC02708G","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T05:30:46Z","timestamp":1782970246000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/8\/9\/6290-6299\/584223"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017]]},"references-count":98,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2017]]}},"URL":"https:\/\/doi.org\/10.1039\/c7sc02708g","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C7SC02708G","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C7SC02708G","name":"related_data"},{"value":"Alexander C. Filippou (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-6225-8977","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Alexander C. Filippou (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/H-5500-2016","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"David Hoffmann (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-3371-0784","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Gregor Schnakenburg (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-6489-2106","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"The Royal Society of Chemistry has an exclusive publication licence for this journal","name":"copyright_licence","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)","URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/","name":"copyright_licence","label":"OPEN ACCESS","group":{"name":"copyright_licensing","label":"COPYRIGHT AND LICENSING"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 18 June 2017; Accepted 2 July 2017; Advance Article published 14 July 2017; Version of Record published 21 August 2017","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}