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Commun."],"abstract":"<p>\n                    The feisty nature of silicon(\n                    <sc>ii<\/sc>\n                    ) fluorides has been harnessed by two cyclic alkyl amino carbene (\n                    <italic>c<\/italic>\n                    AAC) ligands and (\n                    <italic>c<\/italic>\n                    AAC)\n                    <sub>2<\/sub>\n                    SiF\n                    <sub>2<\/sub>\n                    has been isolated at room temperature and structurally characterized.\n                  <\/p>","DOI":"10.1039\/c8cc01816b","type":"journal-article","created":{"date-parts":[[2018,4,10]],"date-time":"2018-04-10T11:35:52Z","timestamp":1523360152000},"page":"5046-5057","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Silicon-fluorine chemistry: from the preparation of SiF\n                    <sub>2<\/sub>\n                    to C\u2013F bond activation using silylenes and its heavier congeners"],"prefix":"10.1039","volume":"54","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4955-5408","authenticated-orcid":false,"given":"Sakya S.","family":"Sen","sequence":"first","affiliation":[{"name":"Inorganic Chemistry and Catalysis Division"},{"name":"CSIR-National Chemical Laboratory"},{"name":"Pune 411008"},{"name":"India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4454-1434","authenticated-orcid":false,"given":"Herbert W.","family":"Roesky","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry"},{"name":"Georg-August University"},{"name":"Goettingen"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2018]]},"reference":[{"key":"C8CC01816B-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1343","DOI":"10.1126\/science.214.4527.1343","volume":"214","author":"West","year":"1981","journal-title":"Science"},{"key":"C8CC01816B-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10481","DOI":"10.1002\/anie.201705644","volume":"56","author":"Alvarado-Beltran","year":"2017","journal-title":"Angew. 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