{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T06:01:00Z","timestamp":1782885660821,"version":"3.54.5"},"reference-count":53,"publisher":"Royal Society of Chemistry (RSC)","issue":"28","license":[{"start":{"date-parts":[[2019,6,20]],"date-time":"2019-06-20T00:00:00Z","timestamp":1560988800000},"content-version":"am","delay-in-days":535,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100007112","name":"University of Cape Town","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100007112","id-type":"DOI","asserted-by":"crossref"}]},{"name":"National Research Foundation"},{"DOI":"10.13039\/501100004513","name":"Harry Crossley Foundation","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100004513","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100006537","name":"Campus France","doi-asserted-by":"crossref","award":["PHC Protea N\u00b0 38229 ZF"],"award-info":[{"award-number":["PHC Protea N\u00b0 38229 ZF"]}],"id":[{"id":"10.13039\/501100006537","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<p>\n                    A series of Fr\u00e9chet-type organometallic dendrons containing\n                    <italic>N<\/italic>\n                    ,\n                    <italic>O<\/italic>\n                    -salicylaldimine Rh(\n                    <sc>i<\/sc>\n                    ) entities at the focal point were evaluated in the hydroformylation of 1-octene.\n                  <\/p>","DOI":"10.1039\/c8dt01874j","type":"journal-article","created":{"date-parts":[[2018,6,20]],"date-time":"2018-06-20T10:00:25Z","timestamp":1529488825000},"page":"9418-9429","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Synthesis and hydroformylation evaluation of Fr\u00e9chet-type organometallic dendrons with\n                    <i>N<\/i>\n                    ,\n                    <i>O<\/i>\n                    -salicylaldimine Rh(\n                    <scp>i<\/scp>\n                    ) complexes at the focal point"],"prefix":"10.1039","volume":"47","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9184-9138","authenticated-orcid":false,"given":"Cody","family":"Williams","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Cape Town"},{"name":"Cape Town"},{"name":"South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4898-0290","authenticated-orcid":false,"given":"Michel","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Univ. Artois"},{"name":"CNRS"},{"name":"Centrale Lille"},{"name":"ENSCL"},{"name":"Univ. Lille"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5865-0979","authenticated-orcid":false,"given":"Eric","family":"Monflier","sequence":"additional","affiliation":[{"name":"Univ. Artois"},{"name":"CNRS"},{"name":"Centrale Lille"},{"name":"ENSCL"},{"name":"Univ. Lille"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6891-0412","authenticated-orcid":false,"given":"Selwyn F.","family":"Mapolie","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Polymer Science"},{"name":"Stellenbosch University"},{"name":"Matieland 7602"},{"name":"South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2892-5481","authenticated-orcid":false,"given":"Gregory S.","family":"Smith","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Cape Town"},{"name":"Cape Town"},{"name":"South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2018]]},"reference":[{"key":"C8DT01874J-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1055\/s-1978-24702","author":"Buhleier","year":"1978","journal-title":"Synthesis"},{"key":"C8DT01874J-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10139","DOI":"10.1039\/C7DT01916E","volume":"46","author":"Dzhardimalieva","year":"2017","journal-title":"Dalton Trans."},{"key":"C8DT01874J-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5274","DOI":"10.1021\/cr500542t","volume":"115","author":"Yang","year":"2015","journal-title":"Chem. Rev."},{"key":"C8DT01874J-(cit2c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"352","DOI":"10.1039\/B711745K","volume":"38","author":"Carlmark","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"C8DT01874J-(cit2d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1039\/B901839P","volume":"40","author":"Mintzer","year":"2011","journal-title":"Chem. Soc. Rev."},{"key":"C8DT01874J-(cit2e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1665","DOI":"10.1021\/cr970069y","volume":"99","author":"Bosman","year":"1999","journal-title":"Chem. Rev."},{"key":"C8DT01874J-(cit2f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1857","DOI":"10.1021\/cr900327d","volume":"110","author":"Astruc","year":"2010","journal-title":"Chem. Rev."},{"key":"C8DT01874J-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"925","DOI":"10.1039\/C39930000925","author":"Newkome","year":"1993","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"C8DT01874J-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3728","DOI":"10.1021\/ic00019a032","volume":"30","author":"Campagna","year":"1991","journal-title":"Inorg. Chem."},{"key":"C8DT01874J-(cit3c)\/*[position()=1]","doi-asserted-by":"crossref","DOI":"10.1002\/3527600612","volume-title":"Dendrimers and Dendrons. Concepts, Syntheses, Applications","author":"Newkome","year":"2001","unstructured":"G. R. Newkome  ,  C. N.Moorefield  and  F.V\u00f6gtle ,  Dendrimers and Dendrons. Concepts, Syntheses, Applications ,  Wiley-VCH ,  Weinheim ,  2001"},{"key":"C8DT01874J-(cit3d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6743","DOI":"10.1021\/acs.chemrev.6b00008","volume":"116","author":"Ren","year":"2016","journal-title":"Chem. Rev."},{"key":"C8DT01874J-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2130","DOI":"10.1016\/j.addr.2005.09.011","volume":"57","author":"Caminade","year":"2005","journal-title":"Adv. Drug Delivery Rev."},{"key":"C8DT01874J-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1039\/C1NJ20458K","volume":"36","author":"Caminade","year":"2012","journal-title":"New J. Chem."},{"key":"C8DT01874J-(cit4c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3200","DOI":"10.1021\/ic049945y","volume":"43","author":"Gumienna-Kontecka","year":"2004","journal-title":"Inorg. Chem."},{"key":"C8DT01874J-(cit5a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12081","DOI":"10.1021\/ja053730l","volume":"127","author":"Parrott","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT01874J-(cit5b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1002\/ejic.200900869","volume":"2010","author":"S\u00e1nchez-M\u00e9ndez","year":"2010","journal-title":"Eur. J. Inorg. Chem."},{"key":"C8DT01874J-(cit5c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"19294","DOI":"10.1039\/C5DT02230D","volume":"44","author":"Lozano-Cruz","year":"2015","journal-title":"Dalton Trans."},{"key":"C8DT01874J-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10589","DOI":"10.1002\/chem.201300899","volume":"19","author":"Fleischer","year":"2013","journal-title":"Chem. \u2013 Eur. J."},{"key":"C8DT01874J-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2852","DOI":"10.1002\/anie.201208330","volume":"52","author":"Pospech","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT01874J-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2680","DOI":"10.1016\/j.tetlet.2012.03.062","volume":"53","author":"Behr","year":"2012","journal-title":"Tetrahedron Lett."},{"key":"C8DT01874J-(cit9a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13927","DOI":"10.1039\/c2dt31471a","volume":"41","author":"Hager","year":"2012","journal-title":"Dalton Trans."},{"key":"C8DT01874J-(cit9b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5675","DOI":"10.1021\/cr3001803","volume":"112","author":"Franke","year":"2012","journal-title":"Chem. Rev."},{"key":"C8DT01874J-(cit9c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13126","DOI":"10.1021\/ja0303384","volume":"125","author":"Lu","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT01874J-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"798","DOI":"10.1021\/ar0100778","volume":"35","author":"Dijkstra","year":"2002","journal-title":"Acc. Chem. Res."},{"key":"C8DT01874J-(cit11)\/*[position()=1]","first-page":"1","volume-title":"Dendrimer Catalysis","author":"Berger","year":"2006","unstructured":"A. Berger  ,  R. J. K.Gebbink  and  G.van Koten , in  Dendrimer Catalysis ,  Springer ,  2006 , p.  1"},{"key":"C8DT01874J-(cit12a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2991","DOI":"10.1021\/cr010323t","volume":"101","author":"Astruc","year":"2001","journal-title":"Chem. Rev."},{"key":"C8DT01874J-(cit12b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"34","DOI":"10.1016\/j.ica.2013.07.058","volume":"409","author":"Bagul","year":"2014","journal-title":"Inorg. Chim. Acta"},{"key":"C8DT01874J-(cit13a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3035","DOI":"10.1021\/ja983764b","volume":"121","author":"Bourque","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT01874J-(cit13b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1881","DOI":"10.1021\/jo991621h","volume":"65","author":"Arya","year":"2000","journal-title":"J. Org. Chem."},{"key":"C8DT01874J-(cit13c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2889","DOI":"10.1021\/ja003854s","volume":"123","author":"Arya","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT01874J-(cit13d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1016\/S1381-1169(01)00502-7","volume":"182","author":"Ropartz","year":"2002","journal-title":"J. Mol. Catal. A: Chem."},{"key":"C8DT01874J-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4323","DOI":"10.1039\/b206597e","author":"Ropartz","year":"2002","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C8DT01874J-(cit15a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"e3593","DOI":"10.1002\/aoc.3593","volume":"31","author":"Siangwata","year":"2017","journal-title":"Appl. Organomet. Chem."},{"key":"C8DT01874J-(cit15b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1016\/j.jorganchem.2017.07.037","volume":"848","author":"Govender","year":"2017","journal-title":"J. Organomet. Chem."},{"key":"C8DT01874J-(cit15c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1016\/j.jorganchem.2015.04.029","volume":"796","author":"Siangwata","year":"2015","journal-title":"J. Organomet. Chem."},{"key":"C8DT01874J-(cit15d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1240","DOI":"10.1039\/C4DT02740J","volume":"44","author":"Matsinha","year":"2015","journal-title":"Dalton Trans."},{"key":"C8DT01874J-(cit15e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"128","DOI":"10.1016\/j.poly.2015.02.037","volume":"91","author":"Maqeda","year":"2015","journal-title":"Polyhedron"},{"key":"C8DT01874J-(cit15f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4318","DOI":"10.1002\/ejic.201300503","volume":"2013","author":"Matsinha","year":"2013","journal-title":"Eur. J. Inorg. Chem."},{"key":"C8DT01874J-(cit15g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"338","DOI":"10.1039\/C1GC15979H","volume":"14","author":"Makhubela","year":"2012","journal-title":"Green Chem."},{"key":"C8DT01874J-(cit15h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jorganchem.2017.03.049","volume":"840","author":"October","year":"2017","journal-title":"J. Organomet. Chem."},{"key":"C8DT01874J-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"414","DOI":"10.1134\/S0022476615030038","volume":"56","author":"Elroby","year":"2015","journal-title":"J. Struct. Chem."},{"key":"C8DT01874J-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3698","DOI":"10.1039\/b820072f","author":"Janiak","year":"2009","journal-title":"Dalton Trans."},{"key":"C8DT01874J-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"716","DOI":"10.1016\/j.inoche.2009.05.026","volume":"12","author":"Antonels","year":"2009","journal-title":"Inorg. Chem. Commun."},{"key":"C8DT01874J-(cit19a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"364","DOI":"10.2174\/1385272811317040006","volume":"17","author":"Guerrero","year":"2013","journal-title":"Curr. Org. Chem."},{"key":"C8DT01874J-(cit19b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12080","DOI":"10.1002\/anie.201106348","volume":"50","author":"Lara","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT01874J-(cit19c)\/*[position()=1]","volume-title":"Nanoparticles and Catalysis","author":"Louis","year":"2008","unstructured":"C. Louis   and  D.Astruc ,  Nanoparticles and Catalysis ,  2008"},{"key":"C8DT01874J-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4735","DOI":"10.1039\/jr9570004735","author":"Chatt","year":"1957","journal-title":"J. Chem. Soc."},{"key":"C8DT01874J-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4375","DOI":"10.1021\/ja00063a071","volume":"115","author":"Hawker","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT01874J-(cit22a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1226","DOI":"10.1126\/science.266.5188.1226","volume":"266","author":"Jansen","year":"1994","journal-title":"Science"},{"key":"C8DT01874J-(cit22b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1158","DOI":"10.1039\/C0DT00761G","volume":"40","author":"Govender","year":"2011","journal-title":"Dalton Trans."},{"key":"C8DT01874J-(cit23)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"885","DOI":"10.1107\/S0021889809030921","volume":"42","author":"Schulz","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"C8DT01874J-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Crystallogr."},{"key":"C8DT01874J-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr., Sect. C: Struct. Chem."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2018\/DT\/C8DT01874J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:44:24Z","timestamp":1782881064000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/47\/28\/9418-9429\/602329"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018]]},"references-count":53,"journal-issue":{"issue":"28","published-print":{"date-parts":[[2018]]}},"URL":"https:\/\/doi.org\/10.1039\/c8dt01874j","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C8DT01874J","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C8DT01874J","name":"related_data"},{"value":"Cody Williams (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-9184-9138","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Michel Ferreira (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-4898-0290","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Eric Monflier (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-5865-0979","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Selwyn F. Mapolie (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-6891-0412","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Selwyn F. Mapolie (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/E-6834-2013","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Gregory S. Smith (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-2892-5481","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 9 May 2018; Accepted 20 June 2018;  Accepted Manuscript published 20 June 2018;  Advance Article published 28 June 2018;  Version of Record published 17 July 2018","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}