{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T18:09:55Z","timestamp":1782929395506,"version":"3.54.5"},"reference-count":53,"publisher":"Royal Society of Chemistry (RSC)","issue":"36","license":[{"start":{"date-parts":[[2019,8,15]],"date-time":"2019-08-15T00:00:00Z","timestamp":1565827200000},"content-version":"am","delay-in-days":591,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100006764","name":"Technische Universit\u00e4t Berlin","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100006764","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"crossref","award":["EP\/R026912\/1"],"award-info":[{"award-number":["EP\/R026912\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<p>\n                    The compounds EtOC(\ue001O)CHNN(PR\n                    <sub>3<\/sub>\n                    ) (R = Ph\n                    <bold>1<\/bold>\n                    , Cy\n                    <bold>2<\/bold>\n                    ,\n                    <italic>t<\/italic>\n                    Bu\n                    <bold>3<\/bold>\n                    ) were prepared\n                    <italic>via<\/italic>\n                    the reactions of the diazomethane and a phosphine and their reactivity has been explored.\n                  <\/p>","DOI":"10.1039\/c8dt02420k","type":"journal-article","created":{"date-parts":[[2018,8,14]],"date-time":"2018-08-14T22:34:13Z","timestamp":1534286053000},"page":"12742-12749","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Lewis and Br\u00f8nsted basicity of phosphine-diazomethane derivatives"],"prefix":"10.1039","volume":"47","author":[{"given":"Carolin","family":"Schneider","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada M5S 3H6"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4217-1038","authenticated-orcid":false,"given":"James H. W.","family":"LaFortune","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada M5S 3H6"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3142-2831","authenticated-orcid":false,"given":"Rebecca L.","family":"Melen","sequence":"additional","affiliation":[{"name":"School of Chemistry"},{"name":"Cardiff University"},{"name":"Cradiff"},{"name":"UK CF10 3AT"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8140-8355","authenticated-orcid":false,"given":"Douglas W.","family":"Stephan","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada M5S 3H6"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2018]]},"reference":[{"key":"C8DT02420K-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6400","DOI":"10.1002\/anie.201409800","volume":"54","author":"Stephan","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10018","DOI":"10.1021\/jacs.5b06794","volume":"137","author":"Stephan","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1021\/ar500375j","volume":"48","author":"Stephan","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"C8DT02420K-(cit4)\/*[position()=1]","first-page":"1","volume":"332","author":"Stephan","year":"2013","journal-title":"Top. Curr. Chem."},{"key":"C8DT02420K-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/128_2012_402","volume":"334","author":"Stephan","year":"2013","journal-title":"Top. Curr. Chem."},{"key":"C8DT02420K-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5740","DOI":"10.1039\/c2ob25339a","volume":"10","author":"Stephan","year":"2012","journal-title":"Org. Biomol. Chem."},{"key":"C8DT02420K-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6498","DOI":"10.1002\/ange.201409800","volume":"127","author":"Stephan","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1002\/anie.200903708","volume":"49","author":"Stephan","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1248","DOI":"10.1126\/science.aaf7229","volume":"354","author":"Stephan","year":"2016","journal-title":"Science"},{"key":"C8DT02420K-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1124","DOI":"10.1126\/science.1134230","volume":"314","author":"Welch","year":"2006","journal-title":"Science"},{"key":"C8DT02420K-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4968","DOI":"10.1002\/anie.200701215","volume":"46","author":"McCahill","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6594","DOI":"10.1021\/om1009044","volume":"29","author":"Dureen","year":"2010","journal-title":"Organometallics"},{"key":"C8DT02420K-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8396","DOI":"10.1021\/ja903650w","volume":"131","author":"Dureen","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9910","DOI":"10.1021\/ic901590s","volume":"48","author":"Dureen","year":"2009","journal-title":"Inorg. Chem."},{"key":"C8DT02420K-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9918","DOI":"10.1021\/ja904377v","volume":"131","author":"Otten","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9709","DOI":"10.1002\/anie.200905650","volume":"48","author":"Neu","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8947","DOI":"10.1039\/c0cc02862b","volume":"46","author":"Morton","year":"2010","journal-title":"Chem. Commun."},{"key":"C8DT02420K-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3270","DOI":"10.1039\/C6SC05607E","volume":"8","author":"Chi","year":"2017","journal-title":"Chem. Sci."},{"key":"C8DT02420K-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5321","DOI":"10.1021\/jacs.6b01497","volume":"138","author":"Chen","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit19a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2299","DOI":"10.1002\/ange.201208750","volume":"125","author":"Sajid","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit19b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"18567","DOI":"10.1021\/ja408815k","volume":"135","author":"Sajid","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4974","DOI":"10.1021\/ja401492s","volume":"135","author":"Dobrovetsky","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10156","DOI":"10.1021\/ja302652a","volume":"134","author":"Sajid","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit22)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2625","DOI":"10.1039\/C4SC00395K","volume":"5","author":"Stephan","year":"2014","journal-title":"Chem. Sci."},{"key":"C8DT02420K-(cit23)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"633","DOI":"10.1039\/C6CC07071J","volume":"53","author":"Ye","year":"2017","journal-title":"Chem. Commun."},{"key":"C8DT02420K-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"809","DOI":"10.1002\/anie.201409969","volume":"54","author":"Longobardi","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8074","DOI":"10.1021\/ja00494a008","volume":"100","author":"Janda","year":"1978","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"896","DOI":"10.1126\/science.aaq1684","volume":"359","author":"L\u00e9gar\u00e9","year":"2018","journal-title":"Science"},{"key":"C8DT02420K-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"871","DOI":"10.1126\/science.aar7395","volume":"359","author":"Broere","year":"2018","journal-title":"Science"},{"key":"C8DT02420K-(cit28)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"805","DOI":"10.1002\/anie.196408051","volume":"3","author":"Appel","year":"1964","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C8DT02420K-(cit29)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3004","DOI":"10.1002\/anie.201206305","volume":"52","author":"Holzmann","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"957","DOI":"10.1021\/ja056575j","volume":"128","author":"Itoh","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit31)\/*[position()=1]","first-page":"3663","volume":"94","author":"Brown","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit32)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8044","DOI":"10.1021\/ja043612i","volume":"127","author":"Burgos","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"C8DT02420K-(cit33)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1223","DOI":"10.1002\/marc.200600252","volume":"27","author":"Bai","year":"2006","journal-title":"Macromol. Rapid Commun."},{"key":"C8DT02420K-(cit34)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"726","DOI":"10.1039\/C2DT31868G","volume":"42","author":"Neu","year":"2013","journal-title":"Dalton Trans."},{"key":"C8DT02420K-(cit35)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2657","DOI":"10.1039\/CC9960002657","author":"Metzler","year":"1996","journal-title":"Chem. Commun."},{"key":"C8DT02420K-(cit36)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1021\/om2011613","volume":"31","author":"Neu","year":"2012","journal-title":"Organometallics"},{"key":"C8DT02420K-(cit37)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"16588","DOI":"10.1002\/anie.201710337","volume":"56","author":"Tang","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit38)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"880","DOI":"10.1002\/anie.201711945","volume":"57","author":"Melen","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8DT02420K-(cit39)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10377","DOI":"10.1039\/C8DT01168K","volume":"47","author":"Ruddy","year":"2018","journal-title":"Dalton Trans."},{"key":"C8DT02420K-(cit40)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"619","DOI":"10.1002\/hlca.19190020163","author":"Staudinger","year":"1919","journal-title":"Helv. Chim. Acta"},{"key":"C8DT02420K-(cit41)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1291","DOI":"10.1515\/znb-1990-0912","volume":"45b","author":"Klein","year":"1990","journal-title":"Z. Naturforsch."},{"key":"C8DT02420K-(cit42)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1447","DOI":"10.1016\/S0040-4039(00)90087-X","author":"Walker","year":"1965","journal-title":"Tetrahedron Lett."},{"key":"C8DT02420K-(cit43)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"302","DOI":"10.1021\/om060508w","volume":"26","author":"Pedro","year":"2007","journal-title":"Organometallics"},{"key":"C8DT02420K-(cit44)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2791","DOI":"10.1021\/acs.organomet.5b00069","volume":"34","author":"Zou","year":"2015","journal-title":"Organometallics"},{"key":"C8DT02420K-(cit45)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"174","DOI":"10.1002\/chem.201503448","volume":"22","author":"Nikolaev","year":"2016","journal-title":"Chem. \u2013 Eur. J."},{"key":"C8DT02420K-(cit46)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"481","DOI":"10.1021\/om000586y","volume":"20","author":"Louie","year":"2001","journal-title":"Organometallics"},{"key":"C8DT02420K-(cit47)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"684","DOI":"10.1515\/znb-1960-1020","volume":"15b","author":"Ried","year":"1960","journal-title":"Z. Naturforschg."},{"key":"C8DT02420K-(cit48)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1904","DOI":"10.1021\/ic702485r","volume":"47","author":"Welch","year":"2008","journal-title":"Inorg. Chem."},{"key":"C8DT02420K-(cit50)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3098","DOI":"10.1103\/PhysRevA.38.3098","volume":"38","author":"Becke","year":"1988","journal-title":"Phys. Rev. A: At., Mol., Opt. Phys."},{"key":"C8DT02420K-(cit51)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"C8DT02420K-(cit52)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1057","DOI":"10.1039\/b515623h","volume":"8","author":"Weigend","year":"2006","journal-title":"Phys. Chem. Chem. Phys."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2018\/DT\/C8DT02420K","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:30:52Z","timestamp":1782927052000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/47\/36\/12742-12749\/602527"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018]]},"references-count":53,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2018]]}},"URL":"https:\/\/doi.org\/10.1039\/c8dt02420k","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C8DT02420K","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C8DT02420K","name":"related_data"},{"value":"James H. W. LaFortune (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-4217-1038","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Rebecca L. Melen (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-3142-2831","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Douglas W. Stephan (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-8140-8355","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 12 June 2018; Accepted 14 August 2018;  Accepted Manuscript published 15 August 2018;  Advance Article published 28 August 2018;  Version of Record published 18 September 2018","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}