{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T22:28:39Z","timestamp":1790029719531,"version":"4.0.1"},"reference-count":51,"publisher":"Royal Society of Chemistry (RSC)","issue":"33","license":[{"start":{"date-parts":[[2018,7,2]],"date-time":"2018-07-02T00:00:00Z","timestamp":1530489600000},"content-version":"vor","delay-in-days":182,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100004663","name":"Ministry of Science and Technology, Taiwan","doi-asserted-by":"crossref","award":["106-2113-M-259-010"],"award-info":[{"award-number":["106-2113-M-259-010"]}],"id":[{"id":"10.13039\/501100004663","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<p>Cuboctahedral copper clusters containing a twelve-coordinated main group element (Cl, Br, S) at the center have been synthesized and characterized.<\/p>","DOI":"10.1039\/c8sc01508b","type":"journal-article","created":{"date-parts":[[2018,7,2]],"date-time":"2018-07-02T05:08:40Z","timestamp":1530508120000},"page":"6785-6795","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":65,"title":["Synthesis and structural characterization of inverse-coordination clusters from a two-electron superatomic copper nanocluster"],"prefix":"10.1039","volume":"9","author":[{"given":"Kiran Kumarvarma","family":"Chakrahari","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"National Dong Hwa University"},{"name":"Hualien 97401"},{"name":"Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rhone P. Brocha","family":"Silalahi","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"National Dong Hwa University"},{"name":"Hualien 97401"},{"name":"Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian-Hong","family":"Liao","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"National Dong Hwa University"},{"name":"Hualien 97401"},{"name":"Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samia","family":"Kahlal","sequence":"additional","affiliation":[{"name":"Univ Rennes"},{"name":"CNRS"},{"name":"ISCR-UMR 6226"},{"name":"F-35000 Rennes"},{"name":"France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu-Chiao","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Chemistry"},{"name":"Academia Sinica"},{"name":"Taipei 11528"},{"name":"Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jyh-Fu","family":"Lee","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Research Center"},{"name":"Hsinchu 30076"},{"name":"Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7632-9369","authenticated-orcid":false,"given":"Ming-Hsi","family":"Chiang","sequence":"additional","affiliation":[{"name":"Institute of Chemistry"},{"name":"Academia Sinica"},{"name":"Taipei 11528"},{"name":"Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4469-7922","authenticated-orcid":false,"given":"Jean-Yves","family":"Saillard","sequence":"additional","affiliation":[{"name":"Univ Rennes"},{"name":"CNRS"},{"name":"ISCR-UMR 6226"},{"name":"F-35000 Rennes"},{"name":"France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0801-6499","authenticated-orcid":false,"given":"C. W.","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"National Dong Hwa University"},{"name":"Hualien 97401"},{"name":"Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2018]]},"reference":[{"key":"C8SC01508B-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ccr.2017.02.016","volume":"338","author":"Haiduc","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"C8SC01508B-(cit1b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.ccr.2017.08.012","volume":"348","author":"Haiduc","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"C8SC01508B-(cit2a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4571","DOI":"10.1039\/b923388a","volume":"46","author":"Liu","year":"2010","journal-title":"Chem. Commun."},{"key":"C8SC01508B-(cit2b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7752","DOI":"10.1021\/ic400959a","volume":"52","author":"Latouche","year":"2013","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit3a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4704","DOI":"10.1021\/ja401576s","volume":"135","author":"Dhayal","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit3b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11222","DOI":"10.1021\/ja904089t","volume":"131","author":"Liu","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit3c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/j.ccr.2006.05.010","volume":"251","author":"Lobana","year":"2007","journal-title":"Coord. Chem. Rev."},{"key":"C8SC01508B-(cit4a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2260","DOI":"10.1021\/ic402960e","volume":"53","author":"Liao","year":"2014","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit4b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1016\/S1387-7003(02)00800-6","volume":"6","author":"Chen","year":"2003","journal-title":"Inorg. Chem. Commun."},{"key":"C8SC01508B-(cit4c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3216","DOI":"10.1021\/ic020732n","volume":"42","author":"Liu","year":"2003","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit4d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3950","DOI":"10.1016\/j.ica.2004.05.040","volume":"357","author":"Liu","year":"2004","journal-title":"Inorg. Chim. Acta"},{"key":"C8SC01508B-(cit4e)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"976","DOI":"10.1039\/b300887h","author":"Liu","year":"2003","journal-title":"Chem. Commun."},{"key":"C8SC01508B-(cit4f)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4464","DOI":"10.1021\/ic049533p","volume":"43","author":"Liu","year":"2004","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit4g)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"923","DOI":"10.1080\/10426500590906445","volume":"180","author":"Liu","year":"2005","journal-title":"Phosphorus, Sulfur Silicon Relat. Elem."},{"key":"C8SC01508B-(cit4h)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4836","DOI":"10.1039\/c3cc41280f","volume":"49","author":"Wei","year":"2013","journal-title":"Chem. Commun."},{"key":"C8SC01508B-(cit4i)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7439","DOI":"10.1021\/ic3007475","volume":"51","author":"Li","year":"2012","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit5a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14384","DOI":"10.1039\/c3dt51835c","volume":"42","author":"Li","year":"2013","journal-title":"Dalton Trans."},{"key":"C8SC01508B-(cit5b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14135","DOI":"10.1021\/acs.inorgchem.7b02269","volume":"56","author":"Latouche","year":"2017","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit5c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4306","DOI":"10.1021\/ic049589j","volume":"43","author":"Liu","year":"2004","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1544","DOI":"10.1002\/anie.198815441","volume":"27","author":"Scherbaum","year":"1988","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C8SC01508B-(cit7a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7901","DOI":"10.1021\/ja3123784","volume":"135","author":"Hu","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit7b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1560","DOI":"10.1021\/ja065428y","volume":"129","author":"Yang","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit8a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1822","DOI":"10.1021\/ic00087a017","volume":"33","author":"Hilsenbeck","year":"1994","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit8b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2678","DOI":"10.1021\/ic00114a028","volume":"34","author":"Zhang","year":"1995","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit9a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"500","DOI":"10.1002\/asia.201701753","volume":"13","author":"Silalahi","year":"2018","journal-title":"Chem.\u2013Asian J."},{"key":"C8SC01508B-(cit9b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14704","DOI":"10.1002\/anie.201608609","volume":"55","author":"Chakrahari","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8SC01508B-(cit10a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"611","DOI":"10.1103\/RevModPhys.65.611","volume":"65","author":"de Heer","year":"1993","journal-title":"Rev. Mod. Phys."},{"key":"C8SC01508B-(cit10b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13705","DOI":"10.1103\/PhysRevB.51.13705","volume":"51","author":"Khanna","year":"1995","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"C8SC01508B-(cit10c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9157","DOI":"10.1073\/pnas.0801001105","volume":"105","author":"Walter","year":"2008","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"C8SC01508B-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13319","DOI":"10.1021\/jacs.5b07574","volume":"137","author":"Nguyen","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8385","DOI":"10.1021\/acs.chemmater.6b03879","volume":"28","author":"Nguyen","year":"2016","journal-title":"Chem. Mater."},{"key":"C8SC01508B-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"394","DOI":"10.1021\/jacs.7b10960","volume":"140","author":"Cook","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.inoche.2010.10.001","volume":"14","author":"Chao","year":"2011","journal-title":"Inorg. Chem. Commun."},{"key":"C8SC01508B-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1002\/0471725587.ch2","volume":"53","author":"Hogarth","year":"2005","journal-title":"Prog. Inorg. Chem."},{"key":"C8SC01508B-(cit16a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3702","DOI":"10.1002\/anie.201410332","volume":"54","author":"Dhayal","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8SC01508B-(cit16b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9943","DOI":"10.1002\/chem.201602275","volume":"22","author":"Dhayal","year":"2016","journal-title":"Chem.\u2013Eur. J."},{"key":"C8SC01508B-(cit16c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10178","DOI":"10.1002\/anie.201704800","volume":"56","author":"Chang","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8SC01508B-(cit16d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6855","DOI":"10.1039\/C8NR00172C","volume":"10","author":"Lin","year":"2018","journal-title":"Nanoscale"},{"key":"C8SC01508B-(cit17a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1002\/anie.198403111","volume":"23","author":"Betz","year":"1984","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C8SC01508B-(cit17b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1317","DOI":"10.1002\/(SICI)1521-3749(200006)626:6<1317::AID-ZAAC1317>3.0.CO;2-7","volume":"626","author":"Rei\u00df","year":"2000","journal-title":"Z. Anorg. Allg. Chem."},{"key":"C8SC01508B-(cit17c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1838","DOI":"10.1002\/(SICI)1521-3773(20000515)39:10<1838::AID-ANIE1838>3.0.CO;2-A","volume":"39","author":"Wiberg","year":"2000","journal-title":"Angew. Chem., Int. Ed."},{"key":"C8SC01508B-(cit17d)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1871","DOI":"10.1039\/C2CS35252D","volume":"42","author":"Fuhr","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"C8SC01508B-(cit18a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"787","DOI":"10.1002\/anie.199207871","volume":"31","author":"Huang","year":"1992","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C8SC01508B-(cit18b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5708","DOI":"10.1021\/ja00040a033","volume":"114","author":"Albano","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"C8SC01508B-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3663","DOI":"10.1021\/acs.inorgchem.6b00201","volume":"55","author":"Kishore","year":"2016","journal-title":"Inorg. Chem."},{"key":"C8SC01508B-(cit22)\/*[position()=1]","first-page":"3","volume":"C71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr."},{"key":"C8SC01508B-(cit25a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9982","DOI":"10.1063\/1.472933","volume":"105","author":"Perdew","year":"1996","journal-title":"J. Chem. Phys."},{"key":"C8SC01508B-(cit25b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"C8SC01508B-(cit25c)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1396","DOI":"10.1103\/PhysRevLett.78.1396","volume":"78","author":"Perdew","year":"1997","journal-title":"Phys. Rev. Lett."},{"key":"C8SC01508B-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"C8SC01508B-(cit28)\/*[position()=1]","volume-title":"Density Functionals: Theory and Applications, (Lecture Notes in physics)","volume":"vol. 500","author":"Burke","year":"1998","unstructured":"K. Burke and E. K. U.Gross , A guided tour of Time-Dependent Density Functional Theory , in Density Functionals: Theory and Applications, (Lecture Notes in physics) , ed. D. Joubert , Springer , 1998 , vol. 500"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2018\/SC\/C8SC01508B","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:11:35Z","timestamp":1783447895000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/9\/33\/6785-6795\/621968"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018]]},"references-count":51,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2018]]}},"URL":"https:\/\/doi.org\/10.1039\/c8sc01508b","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C8SC01508B","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C8SC01508B","name":"related_data"},{"value":"Ming-Hsi Chiang (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-7632-9369","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Ming-Hsi Chiang (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/E-2044-2015","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Jean-Yves Saillard (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-4469-7922","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"C. W. Liu (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-0801-6499","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 3 April 2018; Accepted 30 June 2018; Accepted Manuscript published 2 July 2018; Advance Article published 18 July 2018; Version of Record published 22 August 2018","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}