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Commun."],"abstract":"<p>\n                    Thiourea dioxide is applied as the source of sulfonyl groups for the efficient synthesis of heteroaryl sulfones and sulfonamides from heteroaryl halides under visible light irradiation. This transformation proceeds through a radical process\n                    <italic>via<\/italic>\n                    heteroaryl sulfinate intermediates, as supported by EPR spectroscopy and DFT calculations.\n                  <\/p>","DOI":"10.1039\/c9cc00008a","type":"journal-article","created":{"date-parts":[[2019,2,4]],"date-time":"2019-02-04T09:44:37Z","timestamp":1549273477000},"page":"2489-2492","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":81,"title":["Thiourea dioxide as a source of sulfonyl groups: photoredox generation of sulfones and sulfonamides from heteroaryl\/aryl halides"],"prefix":"10.1039","volume":"55","author":[{"given":"Shengqing","family":"Ye","sequence":"first","affiliation":[{"name":"Institute for Advanced Studies"},{"name":"Taizhou University"},{"name":"Taizhou 318000"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0043-6894","authenticated-orcid":false,"given":"Yuewen","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Fudan University"},{"name":"Shanghai 200438"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0967-6360","authenticated-orcid":false,"given":"Jie","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute for Advanced Studies"},{"name":"Taizhou University"},{"name":"Taizhou 318000"},{"name":"China"},{"name":"Department of Chemistry"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5471-8462","authenticated-orcid":false,"given":"Zhiming","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"Fudan University"},{"name":"Shanghai 200438"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2019]]},"reference":[{"key":"C9CC00008A-(cit1a)\/*[position()=1]","volume-title":"Organosulfur Chemistry","author":"Whitham","year":"1995","unstructured":"G. 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