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Commun."],"abstract":"<p>\n                    Di-pyrone 2\n                    <italic>H<\/italic>\n                    ,2\u2032\n                    <italic>H<\/italic>\n                    -[3,3\u2032-bipyran]-2,2\u2032-dione undergoes four consecutive pericyclic reactions with (CH\n                    <sub>3<\/sub>\n                    )\n                    <sub>3<\/sub>\n                    Si-C\ue002P to form an unprecedented chiral cage compound triphosphatricyclo[3.2.1.0\n                    <sup>2,7<\/sup>\n                    ]oct-3-ene in high yield.\n                  <\/p>","DOI":"10.1039\/c9cc07462g","type":"journal-article","created":{"date-parts":[[2019,10,9]],"date-time":"2019-10-09T04:24:46Z","timestamp":1570595086000},"page":"13812-13815","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Four consecutive reactions in one pot: cascade formation of an unprecedented triphosphatricyclo[3.2.1.0\n                    <sup>2,7<\/sup>\n                    ]oct-3-ene"],"prefix":"10.1039","volume":"55","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1129-9688","authenticated-orcid":false,"given":"Steven","family":"Giese","sequence":"first","affiliation":[{"name":"Institute of Chemistry and Biochemistry"},{"name":"Freie Universit\u00e4t Berlin"},{"name":"14195 Berlin"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1124-437X","authenticated-orcid":false,"given":"D\u00e1niel","family":"Buzs\u00e1ki","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry"},{"name":"Budapest University of Technology and Economics"},{"name":"MTA-BME Computation Driven Chemistry Research Group"},{"name":"H-1111 Budapest"},{"name":"Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2207-8410","authenticated-orcid":false,"given":"L\u00e1szl\u00f3","family":"Nyul\u00e1szi","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry"},{"name":"Budapest University of Technology and Economics"},{"name":"MTA-BME Computation Driven Chemistry Research Group"},{"name":"H-1111 Budapest"},{"name":"Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4700-0502","authenticated-orcid":false,"given":"Christian","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Institute of Chemistry and Biochemistry"},{"name":"Freie Universit\u00e4t Berlin"},{"name":"14195 Berlin"},{"name":"Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2019]]},"reference":[{"key":"C9CC07462G-(cit1a)\/*[position()=1]","volume-title":"Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain","year":"2001","unstructured":"Phosphorus-Carbon Heterocyclic Chemistry: The Rise of a New Domain , ed.  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