{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:45:24Z","timestamp":1791852324510,"version":"4.3.4"},"reference-count":42,"publisher":"Royal Society of Chemistry (RSC)","issue":"38","license":[{"start":{"date-parts":[[2020,8,21]],"date-time":"2020-08-21T00:00:00Z","timestamp":1597968000000},"content-version":"am","delay-in-days":598,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001804","name":"Canada Research Chairs","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001804","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100004489","name":"Mitacs","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100004489","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<p>\n                    Reactions of RC\ue002P (R =\n                    <italic>t<\/italic>\n                    Bu or Ad (admantyl)) with NHCs (SIMes,\n                    <bold>1a<\/bold>\n                    ; IMes,\n                    <bold>1b<\/bold>\n                    and IDipp,\n                    <bold>1d<\/bold>\n                    ), leading to 1,2,3-triphosphetenes\n                    <bold>2<\/bold>\n                    and\n                    <bold>3<\/bold>\n                    , a triphosphole\n                    <bold>4<\/bold>\n                    , and a di-1,2-dihydro-1,2-diphosphete-substituted diphosphene\n                    <bold>5<\/bold>\n                    , are reported.\n                  <\/p>","DOI":"10.1039\/c9dt03185e","type":"journal-article","created":{"date-parts":[[2019,8,21]],"date-time":"2019-08-21T11:24:25Z","timestamp":1566386665000},"page":"14242-14245","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Oligomerization of phosphaalkynes mediated by bulky N-heterocyclic carbenes: avenues to novel phosphorus frameworks"],"prefix":"10.1039","volume":"48","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4934-0367","authenticated-orcid":false,"given":"Liu Leo","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiliang","family":"Zhou","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7378-2301","authenticated-orcid":false,"given":"Youngsuk","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"},{"name":"Department of Chemistry"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Levy L.","family":"Cao","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8140-8355","authenticated-orcid":false,"given":"Douglas W.","family":"Stephan","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Toronto"},{"name":"Toronto"},{"name":"Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2019]]},"reference":[{"key":"C9DT03185E-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1769","DOI":"10.1021\/ja01468a058","volume":"83","author":"Gier","year":"1961","journal-title":"J. Am. Chem. Soc."},{"key":"C9DT03185E-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1515\/znb-1981-0105","volume":"36","author":"Becker","year":"1981","journal-title":"Z. Naturforsch., B: Anorg. Chem., Org. Chem."},{"key":"C9DT03185E-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1021\/cr00099a007","volume":"90","author":"Regitz","year":"1990","journal-title":"Chem. Rev."},{"key":"C9DT03185E-(cit4)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1484","DOI":"10.1002\/anie.198814841","volume":"27","author":"Regitz","year":"1988","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C9DT03185E-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1327","DOI":"10.1021\/cr00089a015","volume":"88","author":"Nixon","year":"1988","journal-title":"Chem. Rev."},{"key":"C9DT03185E-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1578","DOI":"10.1002\/anie.200200557","volume":"42","author":"Mathey","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"16968","DOI":"10.1002\/anie.201803888","volume":"57","author":"Goicoechea","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"755","DOI":"10.1039\/DT9830000755","author":"Laurent","year":"1983","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"C9DT03185E-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1013","DOI":"10.1002\/anie.198910131","volume":"28","author":"Wettling","year":"1989","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C9DT03185E-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1337","DOI":"10.1055\/s-1994-25691","author":"Gei\u00dfler","year":"1994","journal-title":"Synthesis"},{"key":"C9DT03185E-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1337","DOI":"10.1002\/anie.199713371","volume":"36","author":"Mack","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C9DT03185E-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1016\/j.ccr.2013.10.005","volume":"270\u2013271","author":"Chirila","year":"2014","journal-title":"Coord. Chem. Rev."},{"key":"C9DT03185E-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9592","DOI":"10.1002\/anie.201703633","volume":"56","author":"Rummel","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1002\/anie.199500811","volume":"34","author":"Binger","year":"1995","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C9DT03185E-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1233","DOI":"10.1002\/(SICI)1521-3773(19980518)37:9<1233::AID-ANIE1233>3.0.CO;2-X","volume":"37","author":"Tabellion","year":"1998","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2071","DOI":"10.1002\/(SICI)1099-0682(199812)1998:12<2071::AID-EJIC2071>3.0.CO;2-M","volume":"1998","author":"Binger","year":"1998","journal-title":"Eur. J. Inorg. Chem."},{"key":"C9DT03185E-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"758","DOI":"10.1002\/anie.199207581","volume":"31","author":"Wettling","year":"1992","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C9DT03185E-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"C31","DOI":"10.1016\/0022-328X(89)85103-4","volume":"375","author":"Bartsch","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"C9DT03185E-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2202","DOI":"10.1002\/anie.199422021","volume":"33","author":"Caliman","year":"1994","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"C9DT03185E-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1929","DOI":"10.1039\/B618515K","author":"Jones","year":"2007","journal-title":"Dalton Trans."},{"key":"C9DT03185E-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2307","DOI":"10.1002\/1521-3773(20000703)39:13<2307::AID-ANIE2307>3.0.CO;2-D","volume":"39","author":"Hahn","year":"2000","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit22)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1039\/b008472g","author":"Meiners","year":"2001","journal-title":"Chem. Commun."},{"key":"C9DT03185E-(cit23)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3144","DOI":"10.1002\/1521-3773(20010903)40:17<3144::AID-ANIE3144>3.0.CO;2-F","volume":"40","author":"Hahn","year":"2001","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1021\/jacs.7b11791","volume":"140","author":"Liu","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"C9DT03185E-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7466","DOI":"10.1021\/jacs.8b04930","volume":"140","author":"Liu","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"C9DT03185E-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1041","DOI":"10.1039\/C7CC09090K","volume":"54","author":"Liu","year":"2018","journal-title":"Chem. Commun."},{"key":"C9DT03185E-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1002\/anie.201812592","volume":"58","author":"Liu","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit28)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8083","DOI":"10.1021\/jacs.9b03721","volume":"141","author":"Liu","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"C9DT03185E-(cit29)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10046","DOI":"10.1002\/anie.201702148","volume":"56","author":"Melaimi","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"256","DOI":"10.1021\/ar5003494","volume":"48","author":"Soleilhavoup","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"C9DT03185E-(cit31)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9457","DOI":"10.1021\/acs.chemrev.8b00067","volume":"118","author":"Huynh","year":"2018","journal-title":"Chem. Rev."},{"key":"C9DT03185E-(cit32)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9678","DOI":"10.1021\/acs.chemrev.8b00079","volume":"118","author":"Nesterov","year":"2018","journal-title":"Chem. Rev."},{"key":"C9DT03185E-(cit33)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"208","DOI":"10.1002\/chem.19960020213","volume":"2","author":"Pucknat","year":"1996","journal-title":"Chem. \u2013 Eur. J."},{"key":"C9DT03185E-(cit34)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3720","DOI":"10.1039\/C7SC00300E","volume":"8","author":"Hansmann","year":"2017","journal-title":"Chem. Sci."},{"key":"C9DT03185E-(cit35)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"934","DOI":"10.1002\/anie.200804432","volume":"48","author":"Piro","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit36)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3383","DOI":"10.1021\/om980078c","volume":"17","author":"Grobe","year":"1998","journal-title":"Organometallics"},{"key":"C9DT03185E-(cit37)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2939","DOI":"10.1002\/anie.201209109","volume":"52","author":"Back","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit38)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1895","DOI":"10.1039\/C4SC03264K","volume":"6","author":"Vummaleti","year":"2015","journal-title":"Chem. Sci."},{"key":"C9DT03185E-(cit39)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1305","DOI":"10.1039\/b001285h","author":"Clendenning","year":"2000","journal-title":"Chem. Commun."},{"key":"C9DT03185E-(cit40)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1016\/j.chempr.2016.04.001","volume":"1","author":"Liu","year":"2016","journal-title":"Chem"},{"key":"C9DT03185E-(cit41)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2322","DOI":"10.1002\/anie.201005866","volume":"50","author":"Sen","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9DT03185E-(cit42)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2223","DOI":"10.1039\/a805382k","author":"Nowotny","year":"1998","journal-title":"Chem. Commun."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2019\/DT\/C9DT03185E","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T17:33:28Z","timestamp":1783013608000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/48\/38\/14242-14245\/643167"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019]]},"references-count":42,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2019,10,1]]}},"URL":"https:\/\/doi.org\/10.1039\/c9dt03185e","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C9DT03185E","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=C9DT03185E","name":"related_data"},{"value":"Liu Leo Liu (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-4934-0367","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Liu Leo Liu (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/G-3389-2016","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Youngsuk Kim (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-7378-2301","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Youngsuk Kim (ResearcherID)","URL":"http:\/\/www.researcherid.com\/rid\/U-6407-2017","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Douglas W. Stephan (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-8140-8355","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 5 August 2019; Accepted 21 August 2019; Accepted Manuscript published 21 August 2019; Advance Article published 27 August 2019; Version of Record published 1 October 2019","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}