{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T06:15:31Z","timestamp":1788848131067,"version":"build-2803163510"},"reference-count":50,"publisher":"Royal Society of Chemistry (RSC)","issue":"54","license":[{"start":{"date-parts":[[2019,10,2]],"date-time":"2019-10-02T00:00:00Z","timestamp":1569974400000},"content-version":"vor","delay-in-days":274,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["41703109"],"award-info":[{"award-number":["41703109"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21903089"],"award-info":[{"award-number":["21903089"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["41473096"],"award-info":[{"award-number":["41473096"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["41822706"],"award-info":[{"award-number":["41822706"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100000104","name":"National Aeronautics and Space Administration","doi-asserted-by":"crossref","award":["NNX13AJ36G"],"award-info":[{"award-number":["NNX13AJ36G"]}],"id":[{"id":"10.13039\/100000104","id-type":"DOI","asserted-by":"crossref"}]},{"name":"National Science Foundation","award":["NSF-EAR-0746241"],"award-info":[{"award-number":["NSF-EAR-0746241"]}]},{"name":"National Science Foundation","award":["NSF-OCE-0928247"],"award-info":[{"award-number":["NSF-OCE-0928247"]}]},{"name":"National Science Foundation","award":["NSF-OCE-1129499"],"award-info":[{"award-number":["NSF-OCE-1129499"]}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"crossref","award":["8182034"],"award-info":[{"award-number":["8182034"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<p>Methylphosphonic acid (MPn) is an intermediate in the synthesis of the phosphorus-containing nerve agents, such as sarin and VX, and a biosynthesis product of marine microbes with ramifications to global climate change and eutrophication.<\/p>","DOI":"10.1039\/c9ra05169d","type":"journal-article","created":{"date-parts":[[2019,10,2]],"date-time":"2019-10-02T05:23:38Z","timestamp":1569993818000},"page":"31325-31332","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Mechanism of methylphosphonic acid photo-degradation based on phosphate oxygen isotopes and density functional theory"],"prefix":"10.1039","volume":"9","author":[{"given":"Congcong","family":"Xia","sequence":"first","affiliation":[{"name":"Jiangxi Transportation Institute China"},{"name":"330038 Nanchang"},{"name":"China"},{"name":"School of Energy & Environmental Engineering"},{"name":"University of Science and Technology Beijing"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huanhuan","family":"Geng","sequence":"additional","affiliation":[{"name":"School of Energy & Environmental Engineering"},{"name":"University of Science and Technology Beijing"},{"name":"100083 Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaobao","family":"Li","sequence":"additional","affiliation":[{"name":"Jiangxi Transportation Institute China"},{"name":"330038 Nanchang"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiyue","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Energy & Environmental Engineering"},{"name":"University of Science and Technology Beijing"},{"name":"100083 Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2143-9421","authenticated-orcid":false,"given":"Fei","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Energy & Environmental Engineering"},{"name":"University of Science and Technology Beijing"},{"name":"100083 Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaowen","family":"Tang","sequence":"additional","affiliation":[{"name":"School of Pharmaceutical Sciences"},{"name":"Sun Yet-sen University"},{"name":"510006 Guangzhou"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"R. E.","family":"Blake","sequence":"additional","affiliation":[{"name":"School of Energy & Environmental Engineering"},{"name":"University of Science and Technology Beijing"},{"name":"100083 Beijing"},{"name":"China"},{"name":"Department of Geology and Geophysics"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Geology and Geophysics"},{"name":"Yale University"},{"name":"New Haven"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sae Jung","family":"Chang","sequence":"additional","affiliation":[{"name":"Department of Geology and Geophysics"},{"name":"Yale University"},{"name":"New Haven"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chan","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Energy & Environmental Engineering"},{"name":"University of Science and Technology Beijing"},{"name":"100083 Beijing"},{"name":"China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2019]]},"reference":[{"key":"C9RA05169D-(cit1)\/*[position()=1]","first-page":"184","volume":"67","author":"Kononova","year":"2002","journal-title":"Biochemistry"},{"key":"C9RA05169D-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1002\/jms.2038","volume":"47","author":"Wagner","year":"2012","journal-title":"J. Mass Spectrom."},{"issue":"25","key":"C9RA05169D-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14016","DOI":"10.1039\/C9RA01385G","volume":"9","author":"Zhang","year":"2019","journal-title":"RSC Adv."},{"key":"C9RA05169D-(cit4)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10912","DOI":"10.1021\/es502981y","volume":"48","author":"Ruth","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"C9RA05169D-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1016\/j.chroma.2017.04.024","volume":"1501","author":"Seto","year":"2017","journal-title":"J. Chromatogr. A"},{"key":"C9RA05169D-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"194","DOI":"10.1016\/j.jhazmat.2016.10.049","volume":"324","author":"Zhao","year":"2016","journal-title":"J. Hazard. Mater."},{"key":"C9RA05169D-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3038","DOI":"10.1039\/C7TA10794C","volume":"6","author":"Gallis","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"C9RA05169D-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1104","DOI":"10.1126\/science.1219875","volume":"337","author":"Metcalf","year":"2012","journal-title":"Science"},{"key":"C9RA05169D-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/s10337-015-2862-6","volume":"78","author":"Rodin","year":"2015","journal-title":"Chromatographia"},{"key":"C9RA05169D-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"93","DOI":"10.3354\/ame01714","volume":"73","author":"Del Valle","year":"2014","journal-title":"Aquat. Microb. Ecol."},{"key":"C9RA05169D-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1038\/ngeo234","volume":"1","author":"Karl","year":"2008","journal-title":"Nat. Geosci."},{"key":"C9RA05169D-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"610","DOI":"10.1002\/2014GB005011","volume":"29","author":"Burwicz","year":"2015","journal-title":"Global Biogeochem. Cycles"},{"key":"C9RA05169D-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1038\/416389a","volume":"416","author":"Gian-Reto","year":"2002","journal-title":"Nature"},{"key":"C9RA05169D-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1258","DOI":"10.3390\/ijerph8041258","volume":"8","author":"Xu","year":"2011","journal-title":"Int. J. Environ. Res. Public Health"},{"key":"C9RA05169D-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"563","DOI":"10.1021\/cr0503613","volume":"107","author":"Paytan","year":"2007","journal-title":"Chem. Rev."},{"key":"C9RA05169D-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"12292","DOI":"10.1021\/jp002560q","volume":"104","author":"Rusu","year":"2000","journal-title":"J. Phys. Chem. B"},{"key":"C9RA05169D-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"467","DOI":"10.1039\/C6PP00313C","volume":"16","author":"Liu","year":"2017","journal-title":"Photochem. Photobiol. Sci."},{"key":"C9RA05169D-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"345","DOI":"10.1016\/j.watres.2017.06.009","volume":"122","author":"Rott","year":"2017","journal-title":"Water Res."},{"key":"C9RA05169D-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3135","DOI":"10.1016\/S0016-7037(02)00970-5","volume":"67","author":"O'neil","year":"2003","journal-title":"Geochim. Cosmochim. Acta"},{"key":"C9RA05169D-(cit20)\/*[position()=1]","volume-title":"Advances in Agronomy","author":"Jaisi","year":"2014","unstructured":"D. P. Jaisi   and  R. E.Blake ,  Chapter One \u2013 Advances in Using Oxygen Isotope Ratios of Phosphate to Understand Phosphorus Cycling in the Environment ,  Advances in Agronomy ,  Academic Press ,  2014 ,  pp. 1\u201353"},{"key":"C9RA05169D-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5887","DOI":"10.1021\/es5059617","volume":"49","author":"Joshi","year":"2015","journal-title":"Environ. Sci. Technol."},{"key":"C9RA05169D-(cit22)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1516","DOI":"10.2138\/am-1998-11-1240","volume":"83","author":"Blake","year":"1998","journal-title":"Am. Mineral."},{"key":"C9RA05169D-(cit23)\/*[position()=1]","first-page":"3212","volume":"74","author":"Jaisi","year":"2010","journal-title":"Geochim. Cosmochim. Acta"},{"key":"C9RA05169D-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3782","DOI":"10.1016\/j.gca.2009.01.038","volume":"73","author":"Liang","year":"2009","journal-title":"Geochim. Cosmochim. Acta"},{"key":"C9RA05169D-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"947","DOI":"10.1016\/j.jhazmat.2013.06.057","volume":"260","author":"Sandy","year":"2013","journal-title":"J. Hazard. Mater."},{"key":"C9RA05169D-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"8474","DOI":"10.1021\/acs.jafc.6b02608","volume":"64","author":"Jaisi","year":"2016","journal-title":"J. Agric. Food Chem."},{"key":"C9RA05169D-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"529","DOI":"10.1021\/acs.jafc.5b04838","volume":"64","author":"Li","year":"2015","journal-title":"J. Agric. Food Chem."},{"key":"C9RA05169D-(cit28)\/*[position()=1]","doi-asserted-by":"publisher","DOI":"10.1039\/C8NJ05020A","volume":"43","author":"Salimi","year":"2018","journal-title":"New J. Chem."},{"key":"C9RA05169D-(cit29)\/*[position()=1]","first-page":"1","author":"Heo","year":"2015","journal-title":"Desalin. Water Treat."},{"key":"C9RA05169D-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1016\/j.watres.2012.09.045","volume":"47","author":"Lei","year":"2013","journal-title":"Water Res."},{"key":"C9RA05169D-(cit31)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/j.jphotochem.2007.12.007","volume":"197","author":"Chen","year":"2008","journal-title":"J. Photochem. Photobiol., A"},{"key":"C9RA05169D-(cit32)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3784","DOI":"10.1021\/acs.est.7b00205","volume":"51","author":"Han","year":"2017","journal-title":"Environ. Sci. Technol."},{"key":"C9RA05169D-(cit33)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/S0003-2670(00)88444-5","volume":"27","author":"Murphy","year":"1962","journal-title":"Anal. Chim. Acta"},{"key":"C9RA05169D-(cit34)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6254","DOI":"10.1021\/es200456e","volume":"45","author":"Jaisi","year":"2011","journal-title":"Environ. Sci. Technol."},{"key":"C9RA05169D-(cit35)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3957","DOI":"10.1016\/j.gca.2006.04.036","volume":"70","author":"Liang","year":"2006","journal-title":"Geochim. Cosmochim. Acta"},{"key":"C9RA05169D-(cit36)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"340","DOI":"10.3389\/fmicb.2013.00340","volume":"4","author":"Mart\u00ednez","year":"2013","journal-title":"Front. Microbiol."},{"key":"C9RA05169D-(cit37)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.jphotochem.2011.01.021","volume":"219","author":"Pajares","year":"2011","journal-title":"J. Photochem. Photobiol., A"},{"key":"C9RA05169D-(cit38)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"700","DOI":"10.1104\/pp.58.5.700","volume":"58","author":"Biddle","year":"1976","journal-title":"Plant Physiol."},{"key":"C9RA05169D-(cit39)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1016\/j.cej.2016.05.014","volume":"310","author":"Gmurek","year":"2017","journal-title":"Chem. Eng. J."},{"key":"C9RA05169D-(cit40)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1063","DOI":"10.1016\/S0032-9592(03)00231-0","volume":"39","author":"Matys","year":"2004","journal-title":"Process Biochem."},{"key":"C9RA05169D-(cit41)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"747","DOI":"10.1016\/j.scitotenv.2018.06.382","volume":"644","author":"Chan","year":"2018","journal-title":"Sci. Total Environ."},{"key":"C9RA05169D-(cit42)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1080\/03067318608078395","volume":"27","author":"Braun","year":"1986","journal-title":"Int. J. Environ. Anal. Chem."},{"key":"C9RA05169D-(cit43)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9332","DOI":"10.1038\/srep09332","volume":"5","author":"Attri","year":"2015","journal-title":"Sci.\nRep."},{"key":"C9RA05169D-(cit44)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"479","DOI":"10.1007\/s00128-015-1494-8","volume":"94","author":"Hua","year":"2015","journal-title":"Bull. Environ. Contam. Toxicol."},{"key":"C9RA05169D-(cit45)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.jphotochem.2014.06.006","volume":"290","author":"Batista","year":"2014","journal-title":"J. Photochem. Photobiol., A"},{"key":"C9RA05169D-(cit46)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"254","DOI":"10.1016\/j.chemosphere.2013.10.093","volume":"99","author":"Du","year":"2014","journal-title":"Chemosphere"},{"key":"C9RA05169D-(cit47)\/*[position()=1]","first-page":"1","volume":"2017","author":"Guo","year":"2017","journal-title":"J. Chem."},{"key":"C9RA05169D-(cit48)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1007\/s11771-013-1511-1","volume":"20","author":"Song","year":"2013","journal-title":"J. Cent. South Univ."},{"key":"C9RA05169D-(cit49)\/*[position()=1]","first-page":"7b","volume":"51","author":"Li","year":"2017","journal-title":"Environ. Sci. Technol."},{"key":"C9RA05169D-(cit50)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1016\/S0010-8545(02)00034-6","volume":"233","author":"Derosa","year":"2002","journal-title":"Coord. Chem. Rev."}],"container-title":["RSC Advances"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2019\/RA\/C9RA05169D","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2019\/RA\/C9RA05169D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:52:43Z","timestamp":1782881563000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ra\/article\/9\/54\/31325-31332\/660300"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019]]},"references-count":50,"journal-issue":{"issue":"54","published-print":{"date-parts":[[2019,10,2]]}},"URL":"https:\/\/doi.org\/10.1039\/c9ra05169d","relation":{},"ISSN":["2046-2069"],"issn-type":[{"value":"2046-2069","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/C9RA05169D","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Fei Wang (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-2143-9421","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 8 July 2019; Accepted 6 September 2019;  Version of Record published 2 October 2019","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}