{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T21:07:47Z","timestamp":1782853667894,"version":"3.54.5"},"reference-count":21,"publisher":"Royal Society of Chemistry (RSC)","issue":"9","license":[{"start":{"date-parts":[[2020,1,31]],"date-time":"2020-01-31T00:00:00Z","timestamp":1580428800000},"content-version":"vor","delay-in-days":30,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<p>\n                    Mn\n                    <sup>2+<\/sup>\n                    prefers the Cd-sites having larger number of tightly bounded Cl-ligands. Pure Cd\n                    <sub>7<\/sub>\n                    P\n                    <sub>4<\/sub>\n                    Cl\n                    <sub>6<\/sub>\n                    exhibits n-type conductivity whereas Cd\n                    <sub>5.8<\/sub>\n                    Mn\n                    <sub>1.2<\/sub>\n                    P\n                    <sub>4<\/sub>\n                    Cl\n                    <sub>6<\/sub>\n                    exhibits p-type conductivity. The HER activity of Cd\n                    <sub>7\u2212y<\/sub>\n                    Mn\n                    <sub>y<\/sub>\n                    P\n                    <sub>4<\/sub>\n                    Cl\n                    <sub>6<\/sub>\n                    is superior to that of pristine Cd\n                    <sub>7<\/sub>\n                    P\n                    <sub>4<\/sub>\n                    Cl\n                    <sub>6<\/sub>\n                    .\n                  <\/p>","DOI":"10.1039\/c9ra10711h","type":"journal-article","created":{"date-parts":[[2020,1,31]],"date-time":"2020-01-31T04:33:34Z","timestamp":1580445214000},"page":"5134-5145","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Effect of Mn\n                    <sup>2+<\/sup>\n                    substitution on the structure, properties and HER activity of cadmium phosphochlorides"],"prefix":"10.1039","volume":"10","author":[{"given":"Anand","family":"Roy","sequence":"first","affiliation":[{"name":"New Chemistry Unit"},{"name":"Sheikh Saqr Laboratory"},{"name":"School of Advance Materials"},{"name":"Theoretical Science Unit"},{"name":"Jawaharlal Nehru Centre for Advanced Scientific Research"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anjali","family":"Singh","sequence":"additional","affiliation":[{"name":"New Chemistry Unit"},{"name":"Sheikh Saqr Laboratory"},{"name":"School of Advance Materials"},{"name":"Theoretical Science Unit"},{"name":"Jawaharlal Nehru Centre for Advanced Scientific Research"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S. Assa","family":"Aravindh","sequence":"additional","affiliation":[{"name":"New Chemistry Unit"},{"name":"Sheikh Saqr Laboratory"},{"name":"School of Advance Materials"},{"name":"Theoretical Science Unit"},{"name":"Jawaharlal Nehru Centre for Advanced Scientific Research"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Swaraj","family":"Servottam","sequence":"additional","affiliation":[{"name":"New Chemistry Unit"},{"name":"Sheikh Saqr Laboratory"},{"name":"School of Advance Materials"},{"name":"Theoretical Science Unit"},{"name":"Jawaharlal Nehru Centre for Advanced Scientific Research"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Umesh V.","family":"Waghmare","sequence":"additional","affiliation":[{"name":"New Chemistry Unit"},{"name":"Sheikh Saqr Laboratory"},{"name":"School of Advance Materials"},{"name":"Theoretical Science Unit"},{"name":"Jawaharlal Nehru Centre for Advanced Scientific Research"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4088-0615","authenticated-orcid":false,"given":"C. N. R.","family":"Rao","sequence":"additional","affiliation":[{"name":"New Chemistry Unit"},{"name":"Sheikh Saqr Laboratory"},{"name":"School of Advance Materials"},{"name":"Theoretical Science Unit"},{"name":"Jawaharlal Nehru Centre for Advanced Scientific Research"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2020]]},"reference":[{"key":"C9RA10711H-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6926","DOI":"10.1002\/anie.201900936","volume":"58","author":"Roy","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"C9RA10711H-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1006\/jssc.1994.1333","volume":"113","author":"Rebbah","year":"1994","journal-title":"J. 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N. R. Rao (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-4088-0615","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 19 December 2019; Accepted 22 January 2020;  Version of Record published 31 January 2020","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}