{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T22:00:32Z","timestamp":1782943232078,"version":"3.54.5"},"reference-count":30,"publisher":"Royal Society of Chemistry (RSC)","issue":"87","license":[{"start":{"date-parts":[[2020,10,1]],"date-time":"2020-10-01T00:00:00Z","timestamp":1601510400000},"content-version":"vor","delay-in-days":274,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"crossref","award":["EP\/L016443\/1"],"award-info":[{"award-number":["EP\/L016443\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100000288","name":"Royal Society","doi-asserted-by":"crossref","award":["URF\\R1\\191066"],"award-info":[{"award-number":["URF\\R1\\191066"]}],"id":[{"id":"10.13039\/501100000288","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<p>\n                    The first copper(\n                    <sc>i<\/sc>\n                    ) phosphides supported by ring-expanded N-heterocyclic carbenes have been synthesised and react readily with heterocumulenes. These copper(\n                    <sc>i<\/sc>\n                    ) phosphides are highly active and selective in the hydrophosphination of isocyanates.\n                  <\/p>","DOI":"10.1039\/d0cc05694d","type":"journal-article","created":{"date-parts":[[2020,10,1]],"date-time":"2020-10-01T04:53:13Z","timestamp":1601527993000},"page":"13359-13362","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["The first ring-expanded NHC\u2013copper(\n                    <scp>i<\/scp>\n                    ) phosphides as catalysts in the highly selective hydrophosphination of isocyanates"],"prefix":"10.1039","volume":"56","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5027-450X","authenticated-orcid":false,"given":"Thomas M.","family":"Horsley Downie","sequence":"first","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan W.","family":"Hall","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas P.","family":"Collier Finn","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8574-3812","authenticated-orcid":false,"given":"David J.","family":"Liptrot","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4820-251X","authenticated-orcid":false,"given":"John P.","family":"Lowe","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mary F.","family":"Mahon","sequence":"additional","affiliation":[{"name":"X-Ray Crystallography Suite"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4924-2890","authenticated-orcid":false,"given":"Claire L.","family":"McMullin","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5082-3203","authenticated-orcid":false,"given":"Michael K.","family":"Whittlesey","sequence":"additional","affiliation":[{"name":"Department of Chemistry"},{"name":"University of Bath"},{"name":"Claverton Down"},{"name":"Bath"},{"name":"UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2020]]},"reference":[{"key":"D0CC05694D-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1482","DOI":"10.1039\/b612306f","volume":"37","author":"Greenberg","year":"2008","journal-title":"Chem. Soc. Rev."},{"key":"D0CC05694D-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2845","DOI":"10.1021\/cs400685c","volume":"3","author":"Rosenberg","year":"2013","journal-title":"ACS Catal."},{"key":"D0CC05694D-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.ccr.2014.01.006","volume":"265","author":"Koshti","year":"2014","journal-title":"Coord. Chem. Rev."},{"key":"D0CC05694D-(cit4)\/*[position()=1]","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c00667","author":"Glueck","year":"2020","journal-title":"J. Org. Chem."},{"key":"D0CC05694D-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15960","DOI":"10.1002\/chem.201503399","volume":"21","author":"King","year":"2015","journal-title":"Chem. \u2013 Eur. J."},{"key":"D0CC05694D-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4845","DOI":"10.1002\/anie.201701051","volume":"56","author":"Sharpe","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D0CC05694D-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2297","DOI":"10.1021\/acs.organomet.8b00281","volume":"37","author":"Rajpurohit","year":"2018","journal-title":"Organometallics"},{"key":"D0CC05694D-(cit8)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"516","DOI":"10.1002\/cber.19781110210","volume":"111","author":"Greiser","year":"1978","journal-title":"Chem. Ber."},{"key":"D0CC05694D-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1016\/S0022-328X(00)92229-0","volume":"159","author":"van Koten","year":"1978","journal-title":"J. Organomet. Chem."},{"key":"D0CC05694D-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"446","DOI":"10.1039\/C39880000446","author":"Annan","year":"1988","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D0CC05694D-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"208","DOI":"10.1039\/c39880000208","author":"Cowley","year":"1988","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D0CC05694D-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2370","DOI":"10.1021\/ic00337a034","volume":"29","author":"Brauer","year":"1990","journal-title":"Inorg. Chem."},{"key":"D0CC05694D-(cit13)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1039\/dt9910000011","author":"Annan","year":"1991","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D0CC05694D-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"242","DOI":"10.1002\/anie.199302421","volume":"32","author":"Eichh\u00f6fer","year":"1993","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D0CC05694D-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2471","DOI":"10.1002\/anie.199724711","volume":"36","author":"Meyer","year":"1997","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"D0CC05694D-(cit16)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1199","DOI":"10.1002\/zaac.200700098","volume":"633","author":"Scholz","year":"2007","journal-title":"Z. Anorg. Allg. Chem."},{"key":"D0CC05694D-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6148","DOI":"10.1039\/c2dt12415g","volume":"41","author":"Harford","year":"2012","journal-title":"Dalton Trans."},{"key":"D0CC05694D-(cit18)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"14235","DOI":"10.1039\/C5DT02040A","volume":"44","author":"Khalili Najafabadi","year":"2015","journal-title":"Dalton Trans."},{"key":"D0CC05694D-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1021\/acs.organomet.6b00854","volume":"36","author":"Yuan","year":"2017","journal-title":"Organometallics"},{"key":"D0CC05694D-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1039\/C9CC08329D","volume":"56","author":"Itazaki","year":"2020","journal-title":"Chem. Commun."},{"key":"D0CC05694D-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2557","DOI":"10.1021\/om100216f","volume":"29","author":"Roering","year":"2010","journal-title":"Organometallics"},{"key":"D0CC05694D-(cit22)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"5809","DOI":"10.1021\/om2006722","volume":"30","author":"Yi","year":"2011","journal-title":"Organometallics"},{"key":"D0CC05694D-(cit23)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2068","DOI":"10.1039\/C7DT00226B","volume":"46","author":"Schwamm","year":"2017","journal-title":"Dalton Trans."},{"key":"D0CC05694D-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2879","DOI":"10.2174\/138527212804546859","volume":"16","author":"Li","year":"2012","journal-title":"Curr. Org. Chem."},{"key":"D0CC05694D-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2158","DOI":"10.1002\/chem.201202950","volume":"19","author":"Page","year":"2013","journal-title":"Chem. \u2013 Eur. J."},{"key":"D0CC05694D-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"13640","DOI":"10.1021\/ja407004y","volume":"135","author":"Poulten","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D0CC05694D-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2410","DOI":"10.1021\/ja1112518","volume":"133","author":"Park","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D0CC05694D-(cit28)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3102","DOI":"10.1021\/acs.organomet.8b00467","volume":"37","author":"Hall","year":"2018","journal-title":"Organometallics"},{"key":"D0CC05694D-(cit29)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2041","DOI":"10.1002\/cctc.201701992","volume":"10","author":"Sebest","year":"2018","journal-title":"ChemCatChem"},{"key":"D0CC05694D-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3966","DOI":"10.1021\/om100733n","volume":"29","author":"Fortman","year":"2010","journal-title":"Organometallics"}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2020\/CC\/D0CC05694D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T21:29:49Z","timestamp":1782941389000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/56\/87\/13359-13362\/676513"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020]]},"references-count":30,"journal-issue":{"issue":"87","published-print":{"date-parts":[[2020,11,3]]}},"URL":"https:\/\/doi.org\/10.1039\/d0cc05694d","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/D0CC05694D","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=D0CC05694D","name":"related_data"},{"value":"Thomas M. Horsley Downie (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-5027-450X","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"David J. Liptrot (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-8574-3812","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"John P. Lowe (ORCID)","URL":"http:\/\/orcid.org\/0000-0003-4820-251X","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Claire L. McMullin (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-4924-2890","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Michael K. Whittlesey (ORCID)","URL":"http:\/\/orcid.org\/0000-0002-5082-3203","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Authors can choose between single-blind and double-blind peer review","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 21 August 2020; Accepted 30 September 2020;  Accepted Manuscript published 1 October 2020;  Advance Article published 8 October 2020;  Version of Record published 3 November 2020","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}