{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T06:10:47Z","timestamp":1782972647001,"version":"3.54.5"},"reference-count":34,"publisher":"Royal Society of Chemistry (RSC)","issue":"25","license":[{"start":{"date-parts":[[2021,6,5]],"date-time":"2021-06-05T00:00:00Z","timestamp":1622851200000},"content-version":"am","delay-in-days":521,"URL":"http:\/\/rsc.li\/journals-terms-of-use#chorus"}],"funder":[{"name":"National Science Foundation","award":["CHE-1465104"],"award-info":[{"award-number":["CHE-1465104"]}]},{"DOI":"10.13039\/100000138","name":"U.S. Department of Education","doi-asserted-by":"crossref","award":["P200A1320203-14"],"award-info":[{"award-number":["P200A1320203-14"]}],"id":[{"id":"10.13039\/100000138","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100008109","name":"University of Notre Dame","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100008109","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<p>Amidophenoxide-to-osmium \u03c0 donation is sensitive to the co-ligands; it engenders significant anisotropy in the bonding with an oxo group.<\/p>","DOI":"10.1039\/d0dt01735c","type":"journal-article","created":{"date-parts":[[2020,6,5]],"date-time":"2020-06-05T13:23:42Z","timestamp":1591363422000},"page":"8504-8515","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["High-valent osmium iminoxolene complexes"],"prefix":"10.1039","volume":"49","author":[{"given":"Jacqueline","family":"Gianino","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry"},{"name":"251 Nieuwland Science Hall"},{"name":"University of Notre Dame"},{"name":"Notre Dame"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander N.","family":"Erickson","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry"},{"name":"251 Nieuwland Science Hall"},{"name":"University of Notre Dame"},{"name":"Notre Dame"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sean J.","family":"Markovitz","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry"},{"name":"251 Nieuwland Science Hall"},{"name":"University of Notre Dame"},{"name":"Notre Dame"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8414-2396","authenticated-orcid":false,"given":"Seth N.","family":"Brown","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry"},{"name":"251 Nieuwland Science Hall"},{"name":"University of Notre Dame"},{"name":"Notre Dame"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2020]]},"reference":[{"key":"D0DT01735C-(cit1)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/j.ccr.2008.02.004","volume":"253","author":"Poddel'sky","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"D0DT01735C-(cit2)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"677","DOI":"10.1039\/C4DT02936D","volume":"44","author":"Marshall-Roth","year":"2015","journal-title":"Dalton Trans."},{"key":"D0DT01735C-(cit3)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3751","DOI":"10.1039\/c2dt32063k","volume":"42","author":"Munh\u00e1","year":"2013","journal-title":"Dalton Trans."},{"key":"D0DT01735C-(cit4)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4295","DOI":"10.1021\/ic011297k","volume":"41","author":"Sun","year":"2002","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit5)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"7015","DOI":"10.1039\/D0DT01287D","volume":"49","author":"Gianino","year":"2020","journal-title":"Dalton Trans."},{"key":"D0DT01735C-(cit6)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1239","DOI":"10.1021\/ic201736h","volume":"51","author":"Kopec","year":"2012","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit7)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9864","DOI":"10.1021\/ic200923q","volume":"50","author":"Lippert","year":"2011","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit9)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"399","DOI":"10.1023\/A:1027395627461","volume":"37","author":"Shadyro","year":"2003","journal-title":"Pharm. Chem. J."},{"key":"D0DT01735C-(cit10)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"10712","DOI":"10.1002\/anie.201605132","volume":"55","author":"Jacquet","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D0DT01735C-(cit11)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1094","DOI":"10.1039\/dt9740001094","author":"Collin","year":"1974","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D0DT01735C-(cit12)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1214","DOI":"10.1021\/jo01091a013","volume":"24","author":"Staiger","year":"1959","journal-title":"J. Org. Chem."},{"key":"D0DT01735C-(cit13)\/*[position()=1]","first-page":"1305","volume":"206","author":"Jacquemain","year":"1938","journal-title":"Compt. Rend."},{"key":"D0DT01735C-(cit14)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"877","DOI":"10.1021\/cr940053x","volume":"96","author":"Connelly","year":"1996","journal-title":"Chem. Rev."},{"key":"D0DT01735C-(cit15)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4687","DOI":"10.1021\/ic100347h","volume":"49","author":"Lionetti","year":"2010","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit17)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr., Sect. A: Found. Crystallogr."},{"key":"D0DT01735C-(cit18)\/*[position()=1]","volume-title":"International Tables for Crystallography","volume":"C","year":"1992","unstructured":"International Tables for Crystallography , ed.  A. J. C. Wilson ,  Kluwer Academic Publishers ,  Dordrecht, The Netherlands ,  1992 , vol  C"},{"key":"D0DT01735C-(cit19)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1251","DOI":"10.1021\/ic202764j","author":"Brown","year":"2012","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit20)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D0DT01735C-(cit21)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"15583","DOI":"10.1039\/C8DT03392G","volume":"47","author":"Erickson","year":"2018","journal-title":"Dalton Trans."},{"key":"D0DT01735C-(cit22a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6411","DOI":"10.1021\/ja00773a026","volume":"94","author":"Eaton","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"D0DT01735C-(cit22b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3061","DOI":"10.1021\/ic00291a001","volume":"27","author":"Rodger","year":"1988","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit23a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"1991","DOI":"10.1021\/jo00060a004","volume":"58","author":"Hanessian","year":"1993","journal-title":"J. Org. Chem."},{"key":"D0DT01735C-(cit23b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"4481","DOI":"10.1021\/jo060301c","volume":"71","author":"Donohoe","year":"2006","journal-title":"J. Org. Chem."},{"key":"D0DT01735C-(cit24)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2922","DOI":"10.1021\/ic0302480","volume":"43","author":"Min","year":"2004","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit25)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"9049","DOI":"10.1039\/C7DT01945A","volume":"46","author":"Swanson","year":"2017","journal-title":"Dalton Trans."},{"key":"D0DT01735C-(cit26)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11620","DOI":"10.1021\/ic8011734","volume":"47","author":"Mukherjee","year":"2008","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit27)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"3272","DOI":"10.1021\/acs.inorgchem.8b00062","volume":"57","author":"Conner","year":"2018","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit28a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6371","DOI":"10.1021\/jm060590x","volume":"49","author":"Allison","year":"2006","journal-title":"J. Med. Chem."},{"key":"D0DT01735C-(cit28b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2100","DOI":"10.1016\/j.tetasy.2010.07.001","volume":"21","author":"Kurkin","year":"2010","journal-title":"Tetrahedron: Asymmetry"},{"key":"D0DT01735C-(cit29a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"642","DOI":"10.1007\/s11172-015-0912-8","volume":"64","author":"Piskunov","year":"2015","journal-title":"Russ. Chem. Bull., Int. Ed."},{"key":"D0DT01735C-(cit29b)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"286","DOI":"10.1016\/j.poly.2016.08.033","volume":"119","author":"Piskunov","year":"2016","journal-title":"Polyhedron"},{"key":"D0DT01735C-(cit30)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"987","DOI":"10.1016\/0584-8539(76)80283-8","volume":"32A","author":"Boerio","year":"1976","journal-title":"Spectrochim. Acta"},{"key":"D0DT01735C-(cit31)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"11062","DOI":"10.1021\/ic801352d","volume":"47","author":"Samanta","year":"2008","journal-title":"Inorg. Chem."},{"key":"D0DT01735C-(cit32)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"2977","DOI":"10.1021\/ja00008a028","volume":"113","author":"Karpishin","year":"1991","journal-title":"J. Am. Chem. Soc."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2020\/DT\/D0DT01735C","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2020\/DT\/D0DT01735C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T04:49:41Z","timestamp":1782967781000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/49\/25\/8504-8515\/683922"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020]]},"references-count":34,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2020,6,29]]}},"URL":"https:\/\/doi.org\/10.1039\/d0dt01735c","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020]]},"assertion":[{"value":"This document is Similarity Check deposited","name":"similarity_check","explanation":{"URL":"https:\/\/www.crossref.org\/services\/similarity-check\/"},"group":{"name":"similarity_check","label":"SIMILARITY CHECK"}},{"value":"Supplementary Information","URL":"https:\/\/doi.org\/10.1039\/D0DT01735C","name":"related_data","group":{"name":"related_data","label":"RELATED DATA"}},{"value":"Crystal Structure Data","URL":"http:\/\/xlink.rsc.org?ccdc=true&msid=D0DT01735C","name":"related_data"},{"value":"Seth N. Brown (ORCID)","URL":"http:\/\/orcid.org\/0000-0001-8414-2396","name":"identifier","group":{"name":"author_identifiers","label":"IDENTIFIERS"}},{"value":"Single-blind","order":2,"name":"peer_review_method","group":{"name":"peer_review_method","label":"PEER REVIEW METHOD"}},{"value":"Received 13 May 2020; Accepted 5 June 2020;  Accepted Manuscript published 5 June 2020;  Advance Article published 11 June 2020;  Version of Record published 29 June 2020","order":1,"name":"history","group":{"name":"publication_history","label":"PUBLICATION HISTORY"}}]}}