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Herein, we present a frustrated Lewis pair system derived from a water stable carbon-based Lewis acid, trioxatriangulene (TOTA\n                    <sup>+<\/sup>\n                    ), and a variety of Lewis bases, which successfully promotes bond cleavage and molecule fixation.\n                  <\/p>","DOI":"10.1039\/d0sc05893a","type":"journal-article","created":{"date-parts":[[2021,2,8]],"date-time":"2021-02-08T09:13:51Z","timestamp":1612775631000},"page":"4841-4849","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Trioxatriangulenium (TOTA\n                    <sup>+<\/sup>\n                    ) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry"],"prefix":"10.1039","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8818-2344","authenticated-orcid":false,"given":"Aslam C.","family":"Shaikh","sequence":"first","affiliation":[{"name":"University of Arizona"},{"name":"Department of Chemistry and Biochemistry"},{"name":"Tucson"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5272-2131","authenticated-orcid":false,"given":"Jos\u00e9 M.","family":"Veleta","sequence":"additional","affiliation":[{"name":"University of Arizona"},{"name":"Department of Chemistry and Biochemistry"},{"name":"Tucson"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4390-4769","authenticated-orcid":false,"given":"Jules","family":"Moutet","sequence":"additional","affiliation":[{"name":"University of Arizona"},{"name":"Department of Chemistry and Biochemistry"},{"name":"Tucson"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3892-3893","authenticated-orcid":false,"given":"Thomas L.","family":"Gianetti","sequence":"additional","affiliation":[{"name":"University of Arizona"},{"name":"Department of Chemistry and Biochemistry"},{"name":"Tucson"},{"name":"USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2021]]},"reference":[{"key":"D0SC05893A-(cit1a)\/*[position()=1]","doi-asserted-by":"crossref","first-page":"6400","DOI":"10.1002\/anie.201409800","volume":"54","author":"Stephan","year":"2015","journal-title":"Angew. 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