{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T19:15:54Z","timestamp":1783538154373,"version":"3.55.0"},"reference-count":32,"publisher":"Royal Society of Chemistry (RSC)","issue":"45","license":[{"start":{"date-parts":[[2021,11,3]],"date-time":"2021-11-03T00:00:00Z","timestamp":1635897600000},"content-version":"vor","delay-in-days":306,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100004837","name":"Ministerio de Ciencia e Innovaci\u00f3n","doi-asserted-by":"publisher","award":["PGC2018-096444-B-100"],"award-info":[{"award-number":["PGC2018-096444-B-100"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    The nonadiabatic photodissociation dynamics of the CH\n                    <jats:sub>3<\/jats:sub>\n                    (and CD\n                    <jats:sub>3<\/jats:sub>\n                    ) radical from the 3p\n                    <jats:sub>\n                      <jats:italic>z<\/jats:italic>\n                    <\/jats:sub>\n                    and 3s Rydberg states is investigated by applying a one-dimensional (1D) wave packet model that uses recently calculated\n                    <jats:italic>ab initio<\/jats:italic>\n                    1D electronic potential-energy curves and nonadiabatic couplings.\n                  <\/jats:p>","DOI":"10.1039\/d1cp03293c","type":"journal-article","created":{"date-parts":[[2021,11,3]],"date-time":"2021-11-03T11:41:38Z","timestamp":1635939698000},"page":"25911-25924","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Photodissociation of the methyl radical: the role of nonadiabatic couplings in enhancing the variety of dissociation mechanisms"],"prefix":"10.1039","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1214-2132","authenticated-orcid":false,"given":"A.","family":"Garc\u00eda-Vela","sequence":"first","affiliation":[{"name":"Instituto de F\u00edsica Fundamental, Consejo Superior de Investigaciones Cient\u00edficas, Serrano 123, 28006 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2021]]},"reference":[{"key":"D1CP03293C\/cit1","volume-title":"Chemistry of Atmospheres","author":"Wayne","year":"2000","unstructured":"R. F.Wayne ,  Chemistry of Atmospheres ,  Oxford University Press ,  Oxford ,  2000"},{"key":"D1CP03293C\/cit2","doi-asserted-by":"crossref","first-page":"L111","DOI":"10.1086\/312711","volume":"535","author":"Feuchtgruber","year":"2000","journal-title":"Astrophys. J., Lett."},{"key":"D1CP03293C\/cit3","doi-asserted-by":"crossref","first-page":"518","DOI":"10.1016\/0009-2614(85)87257-2","volume":"122","author":"Smyth","year":"1985","journal-title":"Chem. Phys. Lett."},{"key":"D1CP03293C\/cit4","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1139\/p56-059","volume":"34","author":"Herzberg","year":"1956","journal-title":"Can. J. Phys."},{"key":"D1CP03293C\/cit5","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1098\/rspa.1961.0120","volume":"262","author":"Herzberg","year":"1961","journal-title":"Proc. R. Soc. Lond., Ser. A"},{"key":"D1CP03293C\/cit6","doi-asserted-by":"crossref","first-page":"571","DOI":"10.1063\/1.445857","volume":"79","author":"Hudgens","year":"1983","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit7","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1146\/annurev.pc.38.100187.000545","volume":"38","author":"Jasinski","year":"1987","journal-title":"Annu. Rev. Phys. Chem."},{"key":"D1CP03293C\/cit8","doi-asserted-by":"crossref","first-page":"13133","DOI":"10.1021\/jp902969v","volume":"113","author":"Zhang","year":"2009","journal-title":"J. Phys. Chem. A"},{"key":"D1CP03293C\/cit9","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1016\/0009-2614(94)00859-0","volume":"227","author":"Wilson","year":"1994","journal-title":"Chem. Phys. Lett."},{"key":"D1CP03293C\/cit10","doi-asserted-by":"crossref","first-page":"792","DOI":"10.1063\/1.469193","volume":"102","author":"North","year":"1995","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit11","doi-asserted-by":"crossref","first-page":"2193","DOI":"10.1063\/1.1635363","volume":"120","author":"Wu","year":"2004","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit12","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1360\/cjcp2006.19(2).109.8","volume":"19","author":"Wu","year":"2006","journal-title":"Chin. J. Chem. Phys."},{"key":"D1CP03293C\/cit13","doi-asserted-by":"crossref","first-page":"3986","DOI":"10.1063\/1.454832","volume":"89","author":"Black","year":"1988","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit14","doi-asserted-by":"crossref","first-page":"270","DOI":"10.1063\/1.460394","volume":"94","author":"Westre","year":"1991","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit15","doi-asserted-by":"crossref","first-page":"3610","DOI":"10.1021\/j100188a012","volume":"96","author":"Westre","year":"1992","journal-title":"J. Phys. Chem."},{"key":"D1CP03293C\/cit16","doi-asserted-by":"crossref","first-page":"2049","DOI":"10.1063\/1.446969","volume":"80","author":"Yu","year":"1984","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit17","doi-asserted-by":"crossref","first-page":"9215","DOI":"10.1063\/1.464430","volume":"98","author":"Botschwina","year":"1993","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit18","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/S0301-0104(96)00363-1","volume":"215","author":"Mebel","year":"1997","journal-title":"Chem. Phys."},{"key":"D1CP03293C\/cit19","doi-asserted-by":"crossref","first-page":"110","DOI":"10.1039\/C5CP05710H","volume":"18","author":"Balerdi","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D1CP03293C\/cit20","doi-asserted-by":"crossref","first-page":"17054","DOI":"10.1039\/C6CP01558A","volume":"18","author":"Marggi Poullain","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D1CP03293C\/cit21","doi-asserted-by":"crossref","first-page":"33195","DOI":"10.1039\/C6CP05960K","volume":"18","author":"Zanchet","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D1CP03293C\/cit22","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/j.cplett.2018.09.053","volume":"712","author":"Rodr\u00edguez-Fern\u00e1ndez","year":"2018","journal-title":"Chem. Phys. Lett."},{"key":"D1CP03293C\/cit23","doi-asserted-by":"crossref","first-page":"3967","DOI":"10.1063\/1.448136","volume":"81","author":"tal-Ezer","year":"1984","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit24","doi-asserted-by":"crossref","first-page":"4983","DOI":"10.1063\/1.481053","volume":"112","author":"Juanes-Marcos","year":"2000","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit25","doi-asserted-by":"crossref","first-page":"208","DOI":"10.1002\/jcc.540070214","volume":"7","author":"Delgado-Barrio","year":"1986","journal-title":"J. Comput. Chem."},{"key":"D1CP03293C\/cit26","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/0021-9991(72)90094-0","volume":"10","author":"Truhlar","year":"1972","journal-title":"J. Comput. Phys."},{"key":"D1CP03293C\/cit27","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1063\/1.1671699","volume":"51","author":"Gordon","year":"1969","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit28","doi-asserted-by":"crossref","first-page":"614","DOI":"10.1088\/0022-3700\/6\/4\/016","volume":"6","author":"Norcross","year":"1973","journal-title":"J. Phys. B: At. Mol. Phys."},{"key":"D1CP03293C\/cit29","first-page":"363","volume":"15","author":"Cooley","year":"1961","journal-title":"Math. Commun."},{"key":"D1CP03293C\/cit30","doi-asserted-by":"crossref","first-page":"1872","DOI":"10.1063\/1.1734545","volume":"39","author":"Cashion","year":"1963","journal-title":"J. Chem. Phys."},{"key":"D1CP03293C\/cit31","doi-asserted-by":"crossref","first-page":"824","DOI":"10.1021\/acs.jpclett.5b00129","volume":"6","author":"Garc\u00eda-Vela","year":"2015","journal-title":"J. Phys. Chem. Lett."},{"key":"D1CP03293C\/cit32","doi-asserted-by":"crossref","first-page":"153204","DOI":"10.1103\/PhysRevLett.121.153204","volume":"121","author":"Garc\u00eda-Vela","year":"2018","journal-title":"Phys. Rev. Lett."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2021\/CP\/D1CP03293C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T17:50:34Z","timestamp":1783533034000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cp\/article\/23\/45\/25911-25924\/721974"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021]]},"references-count":32,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2021,11,24]]}},"URL":"https:\/\/doi.org\/10.1039\/d1cp03293c","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021]]}}}