{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T03:45:52Z","timestamp":1790826352245,"version":"4.1.0"},"reference-count":38,"publisher":"Royal Society of Chemistry (RSC)","issue":"40","license":[{"start":{"date-parts":[[2021,9,15]],"date-time":"2021-09-15T00:00:00Z","timestamp":1631664000000},"content-version":"vor","delay-in-days":257,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001711","name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung","doi-asserted-by":"publisher","award":["200020_184606"],"award-info":[{"award-number":["200020_184606"]}],"id":[{"id":"10.13039\/501100001711","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    Easily accessible, highly modular and novel Mn(\n                    <jats:sc>i<\/jats:sc>\n                    ) P\u2032ON(H)P pincer complexes for highly enantioselective (up to 98%) transfer hydrogenation of aryl-alkyl ketones have been developed.\n                  <\/jats:p>","DOI":"10.1039\/d1dt02257a","type":"journal-article","created":{"date-parts":[[2021,9,15]],"date-time":"2021-09-15T05:21:14Z","timestamp":1631683274000},"page":"14115-14119","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Mn(\n                    <scp>i<\/scp>\n                    ) phosphine-amino-phosphinites: a highly modular class of pincer complexes for enantioselective transfer hydrogenation of aryl-alkyl ketones"],"prefix":"10.1039","volume":"50","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4176-8510","authenticated-orcid":false,"given":"Harikrishnan","family":"Jayaprakash","sequence":"first","affiliation":[{"name":"Department of Chemistry and Applied Biosciences, ETH Z\u00fcrich, Wolfgang-Pauli-Str. 10, CH-8093 Z\u00fcrich, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2021]]},"reference":[{"key":"D1DT02257A\/cit1","doi-asserted-by":"crossref","first-page":"416","DOI":"10.1039\/C5DT03778F","volume":"45","author":"Murugesan","year":"2016","journal-title":"Dalton Trans."},{"key":"D1DT02257A\/cit2","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1021\/ar700129q","volume":"41","author":"Benito-Garagorri","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"D1DT02257A\/cit3","doi-asserted-by":"crossref","first-page":"2159","DOI":"10.1021\/acs.organomet.8b00284","volume":"37","author":"Gibbons","year":"2018","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit4","doi-asserted-by":"crossref","first-page":"3136","DOI":"10.1002\/cctc.201702019","volume":"10","author":"Vald\u00e9s","year":"2018","journal-title":"ChemCatChem"},{"key":"D1DT02257A\/cit5","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1002\/chem.201803016","volume":"25","author":"Junge","year":"2019","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02257A\/cit6","doi-asserted-by":"crossref","first-page":"741","DOI":"10.1039\/C5QI00262A","volume":"3","author":"Bauer","year":"2016","journal-title":"Inorg. Chem. Front."},{"key":"D1DT02257A\/cit7","doi-asserted-by":"crossref","first-page":"9563","DOI":"10.1039\/D0RA00377H","volume":"10","author":"Xiang","year":"2020","journal-title":"RSC Adv."},{"key":"D1DT02257A\/cit8","doi-asserted-by":"crossref","first-page":"3889","DOI":"10.3390\/molecules25173889","volume":"25","author":"Casnati","year":"2020","journal-title":"Molecules"},{"key":"D1DT02257A\/cit9","doi-asserted-by":"crossref","first-page":"1913","DOI":"10.1002\/adsc.201801511","volume":"361","author":"Garbe","year":"2019","journal-title":"Adv. Synth. Catal."},{"key":"D1DT02257A\/cit10a","doi-asserted-by":"crossref","first-page":"213523","DOI":"10.1016\/j.ccr.2020.213523","volume":"425","author":"Agbossou-Niedercorn","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"D1DT02257A\/cit10b","doi-asserted-by":"crossref","first-page":"3211","DOI":"10.1039\/D0CS00082E","volume":"50","author":"Wen","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"D1DT02257A\/cit10c","doi-asserted-by":"crossref","first-page":"1180","DOI":"10.1016\/j.chempr.2020.11.013","volume":"7","author":"Wang","year":"2021","journal-title":"Chem"},{"key":"D1DT02257A\/cit11","doi-asserted-by":"crossref","first-page":"4691","DOI":"10.1002\/adsc.201900671","volume":"361","author":"Passera","year":"2019","journal-title":"Adv. Synth. Catal."},{"key":"D1DT02257A\/cit12","doi-asserted-by":"crossref","first-page":"6452","DOI":"10.1021\/om5008083","volume":"33","author":"Sonnenberg","year":"2014","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit13","doi-asserted-by":"crossref","first-page":"3781","DOI":"10.1021\/acs.organomet.6b00711","volume":"35","author":"Zirakzadeh","year":"2016","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit14","doi-asserted-by":"crossref","first-page":"7212","DOI":"10.1002\/chem.201701254","volume":"23","author":"Smith","year":"2017","journal-title":"Chem. \u2013 Eur. J."},{"key":"D1DT02257A\/cit15","doi-asserted-by":"crossref","first-page":"396","DOI":"10.1021\/acs.organomet.7b00816","volume":"37","author":"Huber","year":"2018","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit16","doi-asserted-by":"crossref","first-page":"1367","DOI":"10.1021\/ja4082233","volume":"136","author":"Lagaditis","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02257A\/cit17","doi-asserted-by":"crossref","first-page":"9251","DOI":"10.1039\/C9CC03910D","volume":"55","author":"Huber","year":"2019","journal-title":"Chem. Commun."},{"key":"D1DT02257A\/cit18","doi-asserted-by":"crossref","first-page":"1744","DOI":"10.1002\/cctc.201700042","volume":"9","author":"Zirakzadeh","year":"2017","journal-title":"ChemCatChem"},{"key":"D1DT02257A\/cit19","doi-asserted-by":"crossref","first-page":"4608","DOI":"10.1021\/acs.organomet.8b00625","volume":"37","author":"Demmans","year":"2018","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit20","doi-asserted-by":"crossref","first-page":"3153","DOI":"10.1039\/D1CY00446H","author":"Seo","year":"2021","journal-title":"Catal. Sci. Technol."},{"key":"D1DT02257A\/cit21","doi-asserted-by":"crossref","first-page":"106040","DOI":"10.1016\/j.catcom.2020.106040","volume":"142","author":"Azouzi","year":"2020","journal-title":"Catal. Commun."},{"key":"D1DT02257A\/cit22","doi-asserted-by":"crossref","first-page":"3187","DOI":"10.1021\/acs.organomet.9b00457","volume":"38","author":"Van Putten","year":"2019","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit23","first-page":"503","author":"Schneek\u00f6nig","year":"2019","journal-title":"Synlett"},{"key":"D1DT02257A\/cit24","doi-asserted-by":"crossref","first-page":"5825","DOI":"10.1002\/anie.201702406","volume":"56","author":"Widegren","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02257A\/cit25","doi-asserted-by":"crossref","first-page":"6047","DOI":"10.1039\/C9CY01601E","volume":"9","author":"Widegren","year":"2019","journal-title":"Catal. Sci. Technol."},{"key":"D1DT02257A\/cit26","doi-asserted-by":"crossref","first-page":"4973","DOI":"10.1002\/anie.201814751","volume":"58","author":"Zhang","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02257A\/cit27a","doi-asserted-by":"crossref","first-page":"11237","DOI":"10.1002\/anie.201705471","volume":"56","author":"Garbe","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02257A\/cit27b","doi-asserted-by":"crossref","first-page":"3937","DOI":"10.1021\/acs.orglett.9b01056","volume":"21","author":"Ling","year":"2019","journal-title":"Org. Lett."},{"key":"D1DT02257A\/cit28","doi-asserted-by":"crossref","first-page":"13794","DOI":"10.1021\/acscatal.0c04206","volume":"10","author":"Zeng","year":"2020","journal-title":"ACS Catal."},{"key":"D1DT02257A\/cit29","doi-asserted-by":"crossref","first-page":"1271","DOI":"10.1021\/acs.organomet.8b00020","volume":"37","author":"Li","year":"2018","journal-title":"Organometallics"},{"key":"D1DT02257A\/cit30","doi-asserted-by":"crossref","first-page":"11941","DOI":"10.1021\/jacs.7b05939","volume":"139","author":"Fu","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02257A\/cit32","doi-asserted-by":"crossref","first-page":"4229","DOI":"10.1002\/anie.201700681","volume":"56","author":"Chakraborty","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D1DT02257A\/cit33","doi-asserted-by":"crossref","first-page":"1536","DOI":"10.1021\/cr2002905","volume":"112","author":"Crabtree","year":"2012","journal-title":"Chem. Rev."},{"key":"D1DT02257A\/cit34","doi-asserted-by":"crossref","first-page":"4031","DOI":"10.1021\/ja5003636","volume":"136","author":"Li","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D1DT02257A\/cit35a","doi-asserted-by":"crossref","first-page":"432","DOI":"10.1021\/jo991271z","volume":"65","author":"Tanaka","year":"2000","journal-title":"J. Org. Chem."},{"key":"D1DT02257A\/cit35b","doi-asserted-by":"crossref","first-page":"2129","DOI":"10.1021\/ja027458g","volume":"125","author":"Brands","year":"2003","journal-title":"J. Am. Chem. Soc."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2021\/DT\/D1DT02257A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:47:49Z","timestamp":1783450069000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/50\/40\/14115-14119\/725550"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021]]},"references-count":38,"journal-issue":{"issue":"40","published-print":{"date-parts":[[2021,10,19]]}},"URL":"https:\/\/doi.org\/10.1039\/d1dt02257a","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021]]}}}